Aktif karbon destekli ucuz ve kullanışlı katalizörün amonyak bor hidrolizinde incelenmesi

Yıl 2023, , 59 - 65, 30.06.2023

Hatice Bektaş , Erhan Onat , Ömer Şahin , Sevilay Demirci , Orhan Baytar , Mehmet Sait İzgi

https://doi.org/10.30728/boron.1179156

Cited By: 1

Öz

Bu çalışmada ilk kez kahve çekirdeği atığından (kahve telvesinden) elde edilen aktif karbon kullanılarak CuMoB@AC ilk kez katalizörü sentezlendi. Burada en iyi katalitik performanslarını belirlemek amacıyla; Cu:Mo oranı, Metal/AC oranı, optimum NaOH oranı, katalizör miktarı, en uygun NH 3 BH 3 oranı ve farklı sıcaklıklarda yapılan deneyler sonucunda da reaksiyon kinetiği çıkarılarak reaksiyonun derecesinin n. dereceden (0.9) olduğu ve aktivasyon enerjisinin de 34,89 kJ/mol olduğu belirlendi. Aynı zamanda katalizörümüz karakterizasyonu belirlemek için SEM-EDS, XRD ileri analitiksel yöntemler kullanılarak belirlenmiştir.

Anahtar Kelimeler

Amonyak boran, CuMoB, Hidrojen, Hidroliz

Destekleyen Kurum

Siirt Üniversitesi

Proje Numarası

2019-SİÜFEN-004

Teşekkür

Bu çalışma Siirt Üniversitesi (Proje no: 2019-SİÜFEN-004) tarafından desteklenmiştir.

Investigation of a cheap and useful activated carbon supported catalyst in ammonia boron hydrolysis

Öz

In this study, CuMoB@AC catalyst was synthesized for the first time by using activated carbon obtained from coffee bean waste (coffee grounds). In order to determine the best catalytic performances; Cu:Mo ratio, Metal/AC ratio, optimum NaOH ratio, catalyst amount, optimum NH3BH3 ratio and reaction kinetics were determined as a result of experiments performed at different temperatures. It was determined that the degree of the reaction was n. degree (0.9) and the activation energy was 34.89 kJ/mol. At the same time, our catalyst was determined using SEM-EDS, XRD advanced analytical methods to determine the characterization.

Anahtar Kelimeler

Ammonia borane, CuMoB, Hydrogen, Hydrolysis

Proje Numarası

2019-SİÜFEN-004

Kaynakça

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