Effect of Fe doping on photocatalytic activity of B2O3 processed using polyvinyl borate precursor

Yıl 2019, , 187 - 195, 31.12.2019

Özcan Köysüren

https://doi.org/10.30728/boron.596150

Öz

In this study, boron oxide (B₂O₃) powder has been
synthesized by the pyrolysis of polyvinyl borate precursor in air. For this
purpose, polyvinyl borate precursor was synthesized through the condensation
reaction of polyvinyl alcohol and boric acid, and then the polymeric precursor
was pyrolyzed at 500°C. The as-prepared B₂O₃
particles were doped with iron (Fe) ions using the wet impregnation method. The photocatalytic activity of both undoped B₂O₃
and iron doped B₂O₃ (Fe-B₂O₃)
powders was studied by investigating the degradation of the model dye, methylene
blue, under UV light irradiation. It was pointed out that iron doped B₂O₃
powder exhibited enhanced photocatalytic activity compared to undoped one. In
addition, various techniques of characterization such as FTIR, XRD, FESEM, EDX
and UV–Vis spectroscopy were performed to confirm the synthesis of B₂O₃
particles and the presence of iron ions in the crystal structure of the
prepared photocatalyst. The novelty of this study was to research the
photocatalytic performance of both B₂O₃ and Fe-B₂O₃
photocatalysts.

 

Anahtar Kelimeler

UV light irradiation, B2O3, Fe doping, Photocatalytic activity, Polyvinyl borate

Kaynakça

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