PİRİDİN-2,6-DİKARBOKSİLİK ASİTİN PROTON TRANSFER TUZU VE BUNUN Ni(II) VE Cu(II) KOMPLEKSLERİNİN SENTEZİ VE KARAKTERİZASYONU

Nurgün Büyükkıdan; Bülent Büyükkıdan; Nedime Demir; Ceyda Karahan

Araştırma Makalesi

SYNTHESIS AND CHARACTERIZATION OF PROTON TRANSFER SALT OF PYRIDINE-2,6-DICARBOXYLIC ACID AND ITS Ni(II) AND Cu(II) COMPLEXES

Yıl 2018, Sayı: 041, 1 - 12, 16.12.2018

Nurgün Büyükkıdan , Bülent Büyükkıdan , Nedime Demir Ceyda Karahan

Öz

In this study the proton transfer salt (H₂Meppz)(Hdipic)₂ (1) was obtained by the reaction of N-methylpiperazine
(Meppz) with pyridine-2,6-dicarboxylic acid (H₂dipic). The metal
complexes [Ni(H₂O)₆][Ni(dipic)₂].(Meppz).5H₂O
(2) and (H₂Meppz)[Cu(dipic)₂].2H₂O
(3) were synthesized by the reaction
of proton transfer salt (1) with Ni(CH₃COO)₂.4H₂O
and Cu(CH₃COO)₂.2H₂O.
The structure of proton transfer salt (1) was characterized by ¹H and ¹³C
NMR, FT-IR and UV-Vis spectra and elemental analysis techniques. The structures
of the complexes have been suggested according to data obtained from FT-IR,
UV-Vis, ICP-OES, magnetic susceptibility and elemental analysis methods.

Anahtar Kelimeler

Pyrazine, piperazine, dicarboxylicacid, complex, metal

Kaynakça

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