Bitkisel Yağ Sanayii Atıksularının Koagülasyon- Flokülasyon Yöntemleriyle Arıtılması

Yıl 2024, , 533 - 540, 30.06.2024

Talip Turna , Yalçın Yıldız

https://doi.org/10.24012/dumf.1472338

Öz

This study was conducted to investigate potential use of environment-friendly treatment technologies in treatment of vegetable oil industry wastewaters containing various pollutants at high concentrations and compounds resistant to biodegradation. Within the scope of the study, coagulation-flocculation processes were experimented. Various configurations were tried to achieve optimum removal efficiencies. In coagulation-flocculation experiments with Al2(SO4)3.18H2O coagulant, the highest COD (92%) and Oil-Grease (89%) removal efficiencies were achieved at 800 mg Al+3/L coagulant dose. In experiments with FeCl3.6H2O coagulant, the highest COD (88%) and Oil-Grease (89%) removal efficiencies were achieved at 600 mg Fe+3/L coagulant dose.

Anahtar Kelimeler

Atıksu arıtımı, bitkisel yağ sanayii atıksuları, koagulasyon-flokülasyon

Etik Beyan

“Hazırlanan makalede etik kurul izni alınmasına gerek yoktur” “Hazırlanan makalede herhangi bir kişi/kurum ile çıkar çatışması bulunmamaktadır”

Destekleyen Kurum

Erciyes Üniversitesi

Proje Numarası

FDK-2017-7392

Teşekkür

Bu çalışma Erciyes Üniversitesi Bilimsel Araştırma Projeleri Bölümü tarafından FDK-2017-7392 numaralı “Bitkisel Yağ Endüstrisi Atıksularının Elektrokimyasal Yöntemlerle Arıtılması” projesi kapsamında desteklenmiştir.

Treatment of Vegetable Oil Industry Wastewaters with Coagulation-flocculation Methods

Öz

This study was conducted to investigate potential use of environment-friendly treatment technologies in treatment of vegetable oil industry wastewaters containing various pollutants at high concentrations and compounds resistant to biodegradation. Within the scope of the study, coagulation-flocculation processes were experimented. Various configurations were tried to achieve optimum removal efficiencies. In coagulation-flocculation experiments with Al2(SO4)3.18H2O coagulant, the highest COD (92%) and Oil-Grease (89%) removal efficiencies were achieved at 800 mg Al+3/L coagulant dose. In experiments with FeCl3.6H2O coagulant, the highest COD (88%) and Oil-Grease (89%) removal efficiencies were achieved at 600 mg Fe+3/L coagulant dose.

Anahtar Kelimeler

Wastewater treatment, vegetable oil industry wastewaters, coagulation-flocculation

Etik Beyan

"There is no need to obtain permission from the ethics committee for the article prepared" "There is no conflict of interest with any person / institution in the article prepared"

Destekleyen Kurum

Erciyes University

Proje Numarası

FDK-2017-7392

Teşekkür

This study was supported by Scientific Research Projects Department of Erciyes University within the scope of FDK-2017-7392 numbered project entitled as “Treatment of Vegetable Oil Industry Wastewaters with Electrochemical Methods”.

Kaynakça

• [1] S. Di Fraia, N. Massarotti, M. V. Prati, and L. Vanoli, “A new example of circular economy: Waste vegetable oil for cogeneration in wastewater treatment plants,” Energy Convers Manag, vol. 211, p. 112763, May 2020, doi: 10.1016/J.ENCONMAN.2020.112763.
• [2] Z. S. Lee, S. Y. Chin, J. W. Lim, T. Witoon, and C. K. Cheng, “Treatment technologies of palm oil mill effluent (POME)and olive mill wastewater (OMW): A brief review,” Environ Technol Innov, vol. 15, p. 100377, Aug. 2019, doi: 10.1016/j.eti.2019.100377.
• [3] W. I. Ngoie, O. O. Oyekola, D. Ikhu-Omoregbe, and P. J. Welz, “Valorisation of Edible Oil Wastewater Sludge: Bioethanol and Biodiesel Production,” Waste Biomass Valorization, vol. 11, no. 6, pp. 2431–2440, Jun. 2020, doi: 10.1007/s12649-019-00633-w.
• [4] A. Hussein Falamarz Tahir, K. Nagham Obeid, and S. Abduljabbar Ibrahim, “COD Removal of Edible Oil Content in Wastewater by Advanced Oxidation Process,” Environment and Natural Resources Research, vol. 6, no. 2, 2016, doi: 10.5539/enrr.v6n2p57.
• [5] Z. Šereš et al., “Treatment of vegetable oil refinery wastewater using alumina ceramic membrane: Optimization using response surface methodology,” J Clean Prod, vol. 112, pp. 3132–3137, Jan. 2016, doi: 10.1016/j.jclepro.2015.10.070.
• [6] P. Dhanke and S. Wagh, “Treatment of vegetable oil refinery wastewater with biodegradability index improvement,” Mater Today Proc, vol. 27, pp. 181–187, Jan. 2020, doi: 10.1016/J.MATPR.2019.10.004.
• [7] M. C. Cammarota and D. M. G. Freire, “A review on hydrolytic enzymes in the treatment of wastewater with high oil and grease content,” Bioresour Technol, vol. 97, no. 17, pp. 2195–2210, Nov. 2006, doi: 10.1016/j.biortech.2006.02.030.
• [8] Y. Ahmed, Z. Yaakob, P. Akhtar, and K. Sopian, “Production of biogas and performance evaluation of existing treatment processes in palm oil mill effluent (POME),” Renewable and Sustainable Energy Reviews, vol. 42, pp. 1260–1278, Feb. 2015, doi: 10.1016/j.rser.2014.10.073.
• [9] N. Yu et al., “Electricity and methane production from soybean edible oil refinery wastewater using microbial electrochemical systems,” Int J Hydrogen Energy, vol. 42, no. 1, pp. 96–102, Jan. 2017, doi: 10.1016/j.ijhydene.2016.11.116.
• [10] C. N. Nweke, J. T. Nwabanne, and P. K. Igbokwe, “Kinetics of Batch Anaerobic Digestion of Vegetable Oil Wastewater,” Open Journal of Water Pollution and Treatment, vol. 1, no. 2, pp. 1–10, 2014, doi: 10.15764/WPT.2014.02001.
• [11] C. C. Mar, Y. Fan, F. L. Li, and G. R. Hu, “Bioremediation of wastewater from edible oil refinery factory using oleaginous microalga Desmodesmus sp. S1,” Int J Phytoremediation, vol. 18, no. 12, pp. 1195–1201, Dec. 2016, doi: 10.1080/15226514.2016.1193466.
• [12] S. Sharma, A. Aygun, and H. Simsek, “Electrochemical treatment of sunflower oil refinery wastewater and optimization of the parameters using response surface methodology,” Chemosphere, vol. 249, p. 126511, Jun. 2020, doi: 10.1016/j.chemosphere.2020.126511.
• [13] A. M. A. Pintor, V. J. P. Vilar, C. M. S. Botelho, and R. A. R. Boaventura, “Optimization of a primary gravity separation treatment for vegetable oil refinery wastewaters,” Clean Technol Environ Policy, vol. 16, no. 8, pp. 1725–1734, Apr. 2014, doi: 10.1007/s10098-014-0754-3.
• [14] Elham Abdollahzadeh Sharghi, Azadeh Shorgashti, and B. Bonakdarpour, “The Study of Organic Removal Efficiency and Membrane Fouling in a Submerged Membrane Bioreactor Treating Vegetable Oil Wastewater,” International Journal of Engineering, vol. 29, pp. 1642–1649, 2016.
• [15] U. Tezcan Un, A. S. Koparal, and U. Bakir Ogutveren, “Electrocoagulation of vegetable oil refinery wastewater using aluminum electrodes,” J Environ Manage, vol. 90, no. 1, pp. 428–433, Jan. 2009, doi: 10.1016/j.jenvman.2007.11.007.
• [16] O. F. Saeed, K. W. Hameed, and A. H. Abbar, “Treatment of vegetable oil refinery wastewater by sequential electrocoagulation-electrooxidation process,” J Environ Manage, vol. 342, p. 118362, Sep. 2023, doi: 10.1016/j.jenvman.2023.118362.
• [17] P. Cisterna, “Biological Treatment by Active Sludge with High Biomass Concentration at Laboratory Scale for Mixed Inflow of Sunflower Oil and Saccharose,” Environments 2017, Vol. 4, Page 69, vol. 4, no. 4, p. 69, Sep. 2017, doi: 10.3390/ENVIRONMENTS4040069.
• [18] G. Louhıchı, L. Bousselmı, A. Ghrabı, and I. Khounı, “Process optimization via response surface methodology in the physico-chemical treatment of vegetable oil refinery wastewater,” Environmental Science and Pollution Research, vol. 26, no. 19, pp. 18993–19011, Jul. 2019, doi: 10.1007/S11356-018-2657-Z/FIGURES/16.
• [19] E. I. Ohimain and S. C. Izah, “A review of biogas production from palm oil mill effluents using different configurations of bioreactors,” Renewable and Sustainable Energy Reviews, vol. 70, pp. 242–253, Apr. 2017, doi: 10.1016/J.RSER.2016.11.221.
• [20] J. Coca, G. Gutiérrez, and J. M. Benito, “Treatment of oily wastewater,” Water Purification and Management, vol. 101, pp. 1–55, 2011, doi: 10.1007/978-90-481-9775-0_1.
• [21] V. Eroglu, I. Ozturk, H. A. San, and I. Demir, “Comparative evaluation of treatment alternatives for wastewaters from an edible oil refining industry,” Water Science and Technology, vol. 22, no. 9, pp. 225–234, Sep. 1990, doi: 10.2166/wst.1990.0086.
• [22] J. Zhang et al., “Enhanced Purification and Disinfection of Restaurant Wastewater by Electro-coagulation Coupled with an Electro-oxidation Process: From Lab Scale to Field Scale,” ACS ES&T Engineering, vol. 3, no. 7, pp. 932–943, Jul. 2023, doi: 10.1021/acsestengg.2c00381.
• [23] A. E. Bailey and F. Shahidi, Bailey’s industrial oil & fats products, 6th ed. Memorial University of Newfoundland: John Wiley & Sons, 2005.
• [24] D. Kalat, “Bitkisel Yağ Sanayii Rafinasyon Atıksularının Anaerobik Mezofilik ve Termofilik Şartlarda Arıtılabilirliği,” Çukurova Üniversitesi, Doktora Tezi, Adana, s.181, 2011.
• [25] Y. Bi et al., “Star-shaped quaternary ammonium compounds with terminal amino groups for rapidly breaking oil-in-water emulsions,” Fuel, vol. 304, p. 121366, Nov. 2021, doi: 10.1016/J.FUEL.2021.121366.
• [26] T. Ahmad et al., “Utilization of wastewater from edible oil industry, turning waste into valuable products: A review,” Trends Food Sci Technol, vol. 99, pp. 21–33, May 2020, doi: 10.1016/j.tifs.2020.02.017.
• [27] C. S. Lee, J. Robinson, and M. F. Chong, “A review on application of flocculants in wastewater treatment,” Process Safety and Environmental Protection, vol. 92, no. 6, pp. 489–508, Nov. 2014, doi: 10.1016/J.PSEP.2014.04.010.
• [28] G. Louhıchı, L. Bousselmı, A. Ghrabı, and I. Khounı, “Process optimization via response surface methodology in the physico-chemical treatment of vegetable oil refinery wastewater,” Environmental Science and Pollution Research, vol. 26, no. 19, pp. 18993–19011, Jul. 2019, doi: 10.1007/s11356-018-2657-z.
• [29] O. Hartal et al., “Optimization of coagulation-flocculation process for wastewater treatment from vegetable oil refineries using chitosan as a natural flocculant,” Environ Nanotechnol Monit Manag, vol. 22, p. 100957, Dec. 2024, doi: 10.1016/j.enmm.2024.100957.
• [30] C. Zhao et al., “Application of coagulation/flocculation in oily wastewater treatment: A review,” Science of The Total Environment, vol. 765, p. 142795, Apr. 2021, doi: 10.1016/J.SCITOTENV.2020.142795.
• [31] A. Kayvani Fard et al., “Enhancing oil removal from water using ferric oxide nanoparticles doped carbon nanotubes adsorbents,” Chemical Engineering Journal, vol. 293, pp. 90–101, Jun. 2016, doi: 10.1016/J.CEJ.2016.02.040.
• [32] C. An, G. Huang, Y. Yao, and S. Zhao, “Emerging usage of electrocoagulation technology for oil removal from wastewater: A revie
• [33] F. El-Gohary, A. Tawfik, and U. Mahmoud, “Comparative study between chemical coagulation/precipitation (C/P) versus coagulation/dissolved air flotation (C/DAF) for pre-treatment of personal care products (PCPs) wastewater,” Desalination, vol. 252, no. 1–3, pp. 106–112, Mar. 2010, doi: 10.1016/j.desal.2009.10.016.
• [34] Ş. ve İ. D. B. Çevre, “Su Kirliliği Kontrolü Yönetmeliği,” Ankara, 2022.
• [35] APHA/AWWA/WEF, Standard Methods for the Examination of Water and Wastewater. 2012. doi: ISBN 9780875532356.
• [36] R. Jamwal et al., “Attenuated total Reflectance–Fourier transform infrared (ATR–FTIR) spectroscopy coupled with chemometrics for rapid detection of argemone oil adulteration in mustard oil,” LWT, vol. 120, p. 108945, Feb. 2020, doi: 10.1016/J.LWT.2019.108945.
• [37] R. Jamwal et al., “Recent trends in the use of FTIR spectroscopy integrated with chemometrics for the detection of edible oil adulteration,” Vib Spectrosc, vol. 113, p. 103222, Mar. 2021, doi: 10.1016/J.VIBSPEC.2021.103222.
• [38] P. Scardina, G. Copeta, and P. Teragni, “Analysis of oil in water using the agilent cary 630 FTIR,” USA, 2014.
• [39] T. Turna, “Treatment of vegetable oil industry wastewaters by electrochemical methods,” Doctoral Thesis, Erciyes University,135 p., 2020.
• [40] H. YANG, J. IRUDAYARAJ, and M. PARADKAR, “Discriminant analysis of edible oils and fats by FTIR, FT-NIR and FT-Raman spectroscopy,” Food Chem, vol. 93, no. 1, pp. 25–32, Nov. 2005, doi: 10.1016/j.foodchem.2004.08.039.
• [41] A. A. Al-Shamrani, A. James, and H. Xiao, “Destabilisation of oil–water emulsions and separation by dissolved air flotation,” Water Res, vol. 36, no. 6, pp. 1503–1512, Mar. 2002, doi: 10.1016/S0043-1354(01)00347-5.
• [42] F. Özyonar and B. Karagözoğlu, “Removal Of Turbıdıty From Drınkıng Water By Electrocoagulatıon And Chemical Coagulation,” Journal of the Faculty of Engineering and Architecture of Gazi University, vol. 27, no. 1, pp. 81–89, 2012.
• [43] O. S. Amuda, I. A. Amoo, and O. O. Ajayi, “Performance optimization of coagulant/flocculant in the treatment of wastewater from a beverage industry,” J Hazard Mater, vol. 129, no. 1–3, pp. 69–72, Feb. 2006, doi: 10.1016/j.jhazmat.2005.07.078.
• [44] E. K. Tetteh, S. Rathilal, and K. Robinson, “Treatment of industrial mineral oil wastewater – effects of coagulant type and dosage,” Water Pract Technol, vol. 12, no. 1, pp. 139–145, Mar. 2017, doi: 10.2166/wpt.2017.021.
• [45] F. Özyonar and B. Karagözlüoğlu, “Mezbahane atıksularından KOI, yağ-gres ve bulanıklık giderimi üzerine bir çalışma: kimyasal koagülasyon prosesiyle ön arıtımı,” Fen Bilimleri Dergisi, vol. 32, no. 1, 2011.
• [46] M. Chatoui, S. Lahsaini, A. Aguelmous, S. Souabi, M. A. Bahlaoui, and A. Jada, “Moroccan Journal of Chemistry Removal of oil and grease from vegetable oil refinery wastewaters by coagulation-flocculation process,” Moroccan Journal of Chemistry, vol. 5, no. 4, pp. 683–690, Jul. 2017.
• [47] I. Khouni, G. Louhichi, A. Ghrabi, and P. Moulin, “Efficiency of a coagulation/flocculation–membrane filtration hybrid process for the treatment of vegetable oil refinery wastewater for safe reuse and recovery,” Process Safety and Environmental Protection, vol. 135, pp. 323–341, Mar. 2020, doi: 10.1016/j.psep.2020.01.004.
• [48] M. Basibuyuk and D. G. Kalat, “The use of waterworks sludge for the treatment of vegetable oil refinery industry wastewater,” Environmental Technology (United Kingdom), vol. 25, no. 3, pp. 373–380, 2004, doi: 10.1080/09593330409355471.
• [49] C. Haddaji, K. Ennaciri, A. Driouich, K. Digua, and S. Souabi, “Optimization of the coagulation-flocculation process for vegetable oil refinery wastewater using a full factorial design,” Process Safety and Environmental Protection, vol. 160, pp. 803–816, Apr. 2022, doi: 10.1016/j.psep.2022.02.068.
• [50] A. Almojjly, D. Johnson, D. L. Oatley-Radcliffe, and N. Hilal, “Removal of oil from oil-water emulsion by hybrid coagulation/sand filter as pre-treatment,” Journal of Water Process Engineering, vol. 26, pp. 17–27, Dec. 2018, doi: 10.1016/j.jwpe.2018.09.004.