Origin of Barite Mineralization in the Doğanşehir (Malatya): Trace and Rare Earth Element, Isotope and Fluid Inclusion Evidence

Hatice Kara; Dicle Bal Akkoca

doi:10.31202/ecjse.910527

Araştırma Makalesi

Origin of Barite Mineralization in the Doğanşehir (Malatya): Trace and Rare Earth Element, Isotope and Fluid Inclusion Evidence

Yıl 2021, Cilt: 8 Sayı: 2, 1035 - 1050, 31.05.2021

Hatice Kara , Dicle Bal Akkoca

https://doi.org/10.31202/ecjse.910527

Cited By: 1

Öz

This study the main objective presented the geochemical and isotopic characteristics of the barite mineralization at the Doğanşehir (Malatya), located in the Eastern Taurids. These barite mineralizations observed are included in crack zones of metamorphic rocks. Trace element data of barite in the study area show that Ba, Pb and Zn may have been derived from different sources: these elements probably come from recrystallized limestones and siliceous rocks in the study area. The trends of the REE and the plots of the values of barites on the CeN/SmN versus CeN/YbN diagram indicate that seawater dominated the hydrothermal fluid depositing the barite and supplied the barium and sulfate ions, while a fluid mixture of seawater. Pb isotope studies (206Pb/204Pb=17.04-19.2; 207Pb/204Pb=14.33-17.00 and 208Pb/204Pb=34.19-41.66) indicate that the lead in barite was derived from the mantle, orogen, and crust and was slightly contaminated by the basement rocks. Sulfur isotopic studies indicate that the sulfur in barite has been derived from seawater sulfate sources (δ34SVCDT values range from 17.5 ‰ to 30.7 ‰). Microthermometric studies on barite samples range from 85°C to 122°C, with an average of 110°C. Salinities vary from 0.2 to 2.6 NaCl wt%. Homogenization temperatures of the studied fluid inclusions suggest which were probably formed in epithermal conditions.

Anahtar Kelimeler

barite, lead isotope, sulphur isotope, fluid inclusion

Destekleyen Kurum

FUBAP

Proje Numarası

MF.16.63

Teşekkür

This study was supported by the Scientific Research Office of Fırat University (FUBAP), Project No. MF 16.63.

Kaynakça

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Doğanşehir (Malatya)’da ki Barit Cevherleşmelerinin Kökeni: İz ve Nadir Toprak Element, İzotop ve Sıvı Kapanım Bulguları

Yıl 2021, Cilt: 8 Sayı: 2, 1035 - 1050, 31.05.2021

Hatice Kara , Dicle Bal Akkoca

https://doi.org/10.31202/ecjse.910527

Cited By: 1

Öz

Bu çalışmada, Doğu Toroslar'da yer alan Doğanşehir (Malatya) barit cevherleşmesinin jeokimyasal ve izotopik özellikleri ortaya konmuştur. Gözlenen bu barit cevherleşmeleri metamorfik kayaçların çatlak zonları içinde yer almaktadır. Çalışma alanındaki baritlerin eser element verileri, Ba, Pb ve Zn'nin farklı kaynaklardan türetilmiş olabileceğini göstermektedir: bu elementler muhtemelen çalışma alanındaki rekristalize kireçtaşlarından ve silisli kayalardan gelmektedir. REE ve CeN / SmN'ye karşı CeN / YbN diyagramındaki barit değerlerinin grafikleri, deniz suyunun bariti çökelten hidrotermal sıvıya hükmettiğini ve baryum ve sülfat iyonlarını sağlarken, akışkan bir deniz suyu karışımı sağladığını göstermektedir. Pb izotop çalışmaları (206Pb / 204Pb = 17.04-19.2; 207Pb / 204Pb = 14.33-17.00 ve 208Pb / 204Pb = 34.19-41.66), baritteki kurşunun manto, orojen ve kabuktan türetildiğini ve taban kayaları tarafından hafifçe kirlendiğini göstermektedir. Kükürt izotopik çalışmaları, baritteki kükürtün deniz suyu sülfat kaynaklarından türetildiğini göstermektedir (δ34SVCDT değerleri 17,5 ‰ ila 30,7 ‰ arasındadır). Barit örneklerinde yapılan mikrotermometrik çalışmalar, 85 ° C ile 122 ° C arasında değişmekte, ortalama 110 ° C olduğu belirlenmiştir. Tuzluluklar ağırlıkça % 0,2 ila 2,6 NaCl arasında değişmektedir. İncelenen sıvı kapanımlarının homojenleşme sıcaklıkları, muhtemelen epitermal koşullarda oluşmuş olduğunu düşündürmektedir.

Anahtar Kelimeler

barit, Kurşun izotopu, sülfür izotopu, sıvı kapanım

Proje Numarası

MF.16.63

Kaynakça

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[45].Chaussidon, M., Albarède, F., Sheppard, S.M.F., Sulfur isotope variations in the mantle from ion microprobe analyses of micro-sulphide inclusions, Earth Planet. Sci. Lett., 1989, 92,144–156.
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[47].Claypool, G.E., Holser, W.T., Kaplan, I.P., Sakai, H., Zak, I., The age curves of sulfur and oxygen ısotopes in marine sulfate and their mutual ınterpretation, Chemical Geology, 1980, 28, 199-260.
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[51].Hitzman, M.W., Beaty, D.W., The Irish Zn-Pb-(Ba) orefield. In: Sangster, D.F.(Ed), Carbonate-hosted Lead-Zinc Deposits, Society of Economic Geologists Special Publication, 1996, 4,112-143.
[51].Hitzman, M.W., Beaty, D.W., The Irish Zn-Pb-(Ba) orefield. In: Sangster, D.F.(Ed), Carbonate-hosted Lead-Zinc Deposits, Society of Economic Geologists Special Publication, 1996, 4,112-143.
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[52].Kesler, S.E., Appalachian Mississippi Valley-type deposits: paleoaquifers and brine provinces, In: Sangster, D.F. (Ed.), Carbonate Hosted Lead-zinc Deposits. Society of Economic Geologists Special Publication, 1996, 4,29–57.
[52].Kesler, S.E., Appalachian Mississippi Valley-type deposits: paleoaquifers and brine provinces, In: Sangster, D.F. (Ed.), Carbonate Hosted Lead-zinc Deposits. Society of Economic Geologists Special Publication, 1996, 4,29–57.

Toplam 204 adet kaynakça vardır.

Ayrıntılar

Birincil Dil	İngilizce
Konular	Mühendislik
Bölüm	Makaleler
Yazarlar	Hatice Kara 0000-0003-3441-9865 Dicle Bal Akkoca 0000-0003-3279-8443
Proje Numarası	MF.16.63
Yayımlanma Tarihi	31 Mayıs 2021
Gönderilme Tarihi	6 Nisan 2021
Kabul Tarihi	25 Mayıs 2021
Yayımlandığı Sayı	Yıl 2021 Cilt: 8 Sayı: 2

Kaynak Göster

IEEE	H. Kara ve D. Bal Akkoca, “Origin of Barite Mineralization in the Doğanşehir (Malatya): Trace and Rare Earth Element, Isotope and Fluid Inclusion Evidence”, ECJSE, c. 8, sy. 2, ss. 1035–1050, 2021, doi: 10.31202/ecjse.910527.

Cited By

Structural Conditions for Localization of Barite Mineralization in Tectonic Evolution of the Southern Sanandaj Zone, Iran

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