THE PROPERTIES OF CADMIUM OXIDE-CARBON NANOTUBE NANOCOMPOSITE SYNTHESIZED VIA SOL-GEL METHOD

Yıl 2019, , 25 - 36, 30.06.2019

Ömer Güler , Öyküm Başgöz Muhammet Gökhan Albayrak Mehmet Takgün

https://doi.org/10.36222/ejt.487054

Öz

In this study, cadmium oxide based carbon nanotube reinforced material
was produced and the optical and electrical properties of the obtained
composite were investigated. After the carbon nanotubes used as reinforcement
material were synthesized using the chemical vapor deposition method, they were
supplemented at different ratios to the commercially available cadmium oxide
powders. As another group of samples; cadmium oxide powders were synthesized by
the sol-gel method and the carbon nanotubes were again supplemented at
different ratios. Synthesized carbon nanotubes were subjected to Transmission
Electron Microscope examination. Composite materials obtained were examined by Scanning
Electron Microscope. Then, the changes in the electrical conductivity of the
composites obtained by temperature were measured. The optical properties of the
composites were determined by taking UV-vis spectrometers.

Anahtar Kelimeler

Carbon Nanotube, Cadmium Oxide, Sol-Gel, composite

Kaynakça

• [1] Dong, Wenting;Zhu, Congshan. Optical properties of surface-modified CdO nanoparticles. Optical Materials, 2003, 22.3: 227-233.
• [2] LI, Feng; ZHANG, Changwen; ZHAO, Mingwen. Magnetic and optical properties of Cu-doped ZnO nanosheet: First-principles calculations. Physica E: Low-dimensional Systems and Nanostructures, 2013, 53: 101-105.
• [3] GULINO, Antonino; COMPAGNINI, Giuseppe; SCALISI, Alessandro A. Large third-order nonlinear optical properties of cadmium oxide thin films. Chemistry of materials, 2003, 15.17: 3332-3336.
• [4] Farmanzadeh, Davood; Valıpour, Azadeh. Adsorption of benzene and toluene molecules on surface of pure and doped cadmium oxide nanosheets: A computational investigation. Applied Surface Science, 2018.
• [5] C. Aydin, H.M. El-Nasser, F. Yakuphanoglu, I.S. Yahiaa, M. Aksoy, 2011, “Nanopowder Synthesis of Aluminum Doped Cadmium Oxide via Sol–Gel Calcination Processing”, Journal of Alloys and Compounds 509, 854–858.
• [6] Azizar M., M.K.R. Rahman Khan, 2014, “Effect of Annealing Temperature on Structural, Electrical and Optical Properties of Spray Pyrolytic Nanocrystalline CdO Thin Films”, Mater. Sci. Semicond. Process. 24 26–33.
• [7] Yakuphanoglu F., 2011, “Synthesis and Electro-Optic Properties of Nanosized-Boron Doped Cadmium Oxide Thin Films for Solar Cell Applications”, Sol. Energy 85, 2704–2709.
• [8] Balmuri, S. R., Selvaraj, U., Kumar, V. V., Anthony, S. P., Tsatsakis, A. M., Golokhvast, K. S., & Raman, T. (2017). Effect of Surfactant in Mitigating Cadmium Oxide Nanoparticle Toxicity: Implications for Mitigating Cadmium Toxicity İn Environment. Environmental research, 152, 141-149.
• [9] Zheng, B.J., Lian, J.S., Zhao, L., Jiang, Q., 2010. “Optical and Electrical Properties of In- Doped CdO Thin Films Fabricated by Pulse Laser Deposition”, Applied Surface Science 256, 2910–2914.
• [10] Coutts, T.J., Young, D.L., Li, X., Mulligan, W.P., Wu, X., Vac, J., 2000. “Search for Improved Transparent Conducting Oxides: A fundamental investigation of CdO, Cd2SnO4, and Zn2SnO4”. Sci. Technol. A 18, 2646.
• [11] Metz A.W., Ireland J.R., Zheng J.G., Lobo R.P., Yang Y., Ni J., Stern C.L., Dravid V.P., Bontemps N., Kannewurf C.R., Poeppelmeier K.R., Marks T.J., 2004. “Transparent conducting oxides: texture and microstructure effects on charge carrier mobility in MOCVD-derived CdO thin films grown with a thermally stable, low-melting precursor”, J. Am. Chem. Soc. 126, 8477.
• [12] Kumaravela, R., Menakaa, S., Regina, S., Snegaa, M., Ramamurthia, K., Jeganathan, K., 2010. “Electrical optical and structural properties of aluminum doped CdO thin films prepared by spray pyrolysis technique”, Materials Chemistry and Physics 122, 444.
• [13] Bhosale, C.H., Kambale, A.V., Kokate, A.V., Rajpure, K.Y., 2005. Structural, optical and electrical properties of chemically sprayed CdO thin films, Materials Science and Engineering B, 122, 67–71.
• [14] Uplane, M.D., Kshirsagar, P.N., BLokhande, B.J., Bhosale, C.H., 1999. “Stability and Electronic Properties of Znxcd1-Xo Alloys”, Mater. Chem. Phys. 1, 8630.
• [15] Peter, L.M., 1979. “The photoelectrochemical properties of anodic Bi2S3 films, Journal of Electroanalytical Chemistry and Interfacial Electrochemistry”, Volume 98, Issue 1, Pages 49-58.
• [16] Divine Mbom Y. , Josepha Foba T. , Agwara Moise O., Joseph Ketcha M., 2014, “CdO Nanoparticles by Thermal Decomposition of a CadmiumHexamethylenetetramine Complex”, Journal of Materials Science Research; Vol. 3, No. 3.
• [17] Ye, M., Zhong, H., Zheng, W., Li, R., Li, Y., 2007, “Ultralong Cadmium Hydroxide Nanowires: Synthesis, Characterization, and Transformation into CdO Nanostrands. Langmuir, 23(17), 9064-9068.
• [18] Zhang, J., Wang, Y., Lin, Z., Huang, F. 2010, “Formation and Self-Assembly of Cadmium Hydroxide Nanoplates in Molten Composite-Hydroxide Solution”, Crystal Growth & Design, 10(10), 4285-4291.
• [19] Prakash, T., Arunkumar, T., Sathıysa Raj, D., Jayaprakash, R. (2013). “Surfactant-liaised Variation in CdO Nanocomposites Morphology”, Physics Procedia, 49, 36-43.
• [20] Ghoshal, T., Biswas, S., Nambissan, P. M. G., Majumdar, G., De, S. K. (2009). “Cadmium Oxide Octahedrons and Nanowires on the Micro-Octahedrons: A Simple Solvothermal Synthesis”, Crystal Growth & Design, 9(3).
• [21] Tadjarodi, A., Imani, M. (2011). “A novel nanostructure of cadmium oxide synthesized by mechanochemical method”. Materials Research Bulletin, 46(11), 1949-1954.
• [22] Tadjarodi, A., Imani, M. (2011b). “Synthesis and characterization of CdO nanocrystalline structure by mechanochemical method”. Materials Letters, 65(6), 1025-1027.
• [23] Shi, W., Wang, C., Wang, H., Zhang, H. (2006). “Hexagonal Nanodisks of Cadmium Hydroxide and Oxide”, Journal of Materials Science Research Vol. 3, No. 3; 2014 11 with Nanoporous Structure. Crystal Growth & Design, 6(4), 915-918.
• [24] Andeani, J. K., Mohsenzadeh, S. (2013). “Phytosynthesis of Cadmium Oxide Nanoparticles from Achillea wilhelmsii Flowers”. Journal of Chemistry, 2013, 1-4.
• [25] Ramazani, M., Morsali, A. (2011). “Sonochemical syntheses of a new nano-plate cadmium (II) coordination polymer as a precursor for the synthesis of cadmium (II) oxide nanoparticles”, Ultrasonics Sonochemistry, 18(5), 1160-1164.
• [26] Aydın, C., El-Nasser, H.M., Yakuphanoglu, F., Yahia, I.S., Aksoy, M., 2011. “Nanopowder synthesis of aluminum doped cadmium oxide via sol–gel calcination processing”, Journal of Alloys and Compounds 509, 854.
• [27] Duclaux, L. (2002). Review of the doping of carbon nanotubes (multiwalled and single-walled). Carbon, 40(10), 1751-1764.
• [28] Kumar, S. S., Vairam, S., Neelakandeswari, N., & Aruna, S. (2018). Effect of metal oxide charge transfer layers on the photovoltaic performance of carbon nanotube heterojunction solar cells. Materials Letters, 220, 249-252.
• [29] S.P. Yakala, S.S. Yawale, G.T. Lamdhade, Tin oxide and zinc oxide based doped humidity sensors, Sensors and Actuators A: Physical, 135 (2007), pp. 388-393.
• [30] Ates, T.; Tatar, C.; Yakuphanoglu, F. Preparation of semiconductor ZnO powders by sol–gel method: Humidity sensors. Sensors and Actuators A: Physical, 2013, 190: 153-160.
• [31] S.P. Yawale, S.S. Yawale, G.T. Lamdhade, Tin oxide and zinc oxide based doped humidity sensors, Sensors and Actuators A: Physical, 135 (2007), pp. 388-393.