Asidik ortamda paslanmaz çeliğin korozyonuna yeşil inhibitör olan Nikotinamidin etkisi

Yıl 2023, Cilt: 38 Sayı: 3, 1431 - 1438, 06.01.2023

Gülden Asan

https://doi.org/10.17341/gazimmfd.1064200

Öz

Paslanmaz çelik tüm dünyada en çok kullanılan metal olarak karşımıza çıkmaktadır. Çeliğin asidik ortamda korozyon direnci düşük olduğu için ve endüstride asit kullanımı çok yaygın olduğundan çeliğin korozyondan korunması önem arz etmektedir. Bu çalışmada inhibitör olarak çevre dostu olan nikotinamid bileşiği çeliğin korozyondan korunmasında kullanıldı. Çalışma da öncelikle çeliğin 0,1 M HCl asit çözeltisinde elektrokimyasal davranışını belirlemek için dönüşümlü voltametri teğniği kullanıldı. Daha sonra 0,1 M HCl asit çözeltisinde Tafel polarizasyon yöntemi nikotinamid inhibitörü olmadığında, 500 ppm, 750 ppm ve 1000 ppm nikotinamid varlığında çeliğin korozyon davranışını tayin etmek için uygulandı. Bu 3 farklı derişimde inhibitör 0, 15, 30, 45 ve 60 dakikalık sürelerde bekletilerek her bir derişim için optimum süre tayini yapıldı. En yüksek inhibitör etkinliği 1000 ppm nikotinamid derişiminde 15 dakikalık bekletme süresinde % 96,8, süre kısıtlaması olmadığında 500 ppm nikotinamid derişiminde 60 dakikalık bekletme süresinde inhibitör etkinliği % 96,6 olarak bulundu. Elde edilen sonuçlar gösterdi ki nikotinamid paslanmaz çeliğin korozyondan korunmasında etkin bir şekilde kullanılabilir ve çevre dostu olması sebebiyle de korozyondan korunma sağlanırken çevreye ve canlılara zarar verilmemiş olur.

Anahtar Kelimeler

Paslanmaz çelik, korozyon, tafel polarizasyonu, nikotinamid, inhibitör.

Kaynakça

• 1. Hansson CM., The impact of corrosion on society. Metallurgical and Materials Transactions A: Physical Metallurgy and Materials Science., 42(10):2952–62, 2011.
• 2. Javaherdashti R., How corrosion affects industry and life. Anti-Corrosion Methods and Materials., 47(1):30–4, 2000.
• 3. Kesavan D, Gopiraman M, Sulochana N., Green Inhibitors for Corrosion of Metals : A Review Correspondence : Chemical Science Review and Letters.,1(1):1–8, 2012.
• 4. Kocaman E, Kılınç B, Şen Ş, Şen U., Effect of chromium content on Fe(18-x)CrxB2(X=3,4,5) hardfacing electrode on microstructure, abrasion and corrosion behavior. Journal of the Faculty of Engineering and Architecture of Gazi University., 36(1):177–90, 2020.
• 5. Matik U., Improvement of surface properties of iron based powder metal compacts by electroless NiB coating. Journal of the Faculty of Engineering and Architecture of Gazi University., 33(4):1603–10, 2018.
• 6. Asan G, Asan A., Corrosion protection of AISI 1010 using doped MoS<inf>2</inf> conductive polymers. Journal of the Turkish Chemical Society, Section A: Chemistry., 7(1), 2020.
• 7. Hosseini M, Mertens SFL, Ghorbani M, Arshadi MR., Asymmetrical Schiff bases as inhibitors of mild steel corrosion in sulphuric acid media. Materials Chemistry and Physics., 78(3):800–8, 2003.
• 8. Wang X, Chen JG, Su G feng, Cui C, Li HY., Application of electromagnetism method to characterize the degradation behavior in structural mild steel within the elastic range. Construction and Building Materials, 241:118011, 2020.
• 9. Asan A., Effect of 5-Nitro-2-Furaldehyde on Corrosion of Carbon Steel, JOTCSB., 2(2):137–42, 2019.
• 10. Bjorhovde R., Development and use of high performance steel. Journal of Constructional Steel Research., 60(3–5):393–400, 2004.
• 11. Soltani N, Tavakkoli N, Khayatkashani M, Jalali MR, Mosavizade A., Green approach to corrosion inhibition of 304 stainless steel in hydrochloric acid solution by the extract of Salvia officinalis leaves. Corrosion Science, 62:122–35, 2012.
• 12. Rani BEA, Basu BBJ., Green inhibitors for corrosion protection of metals and alloys: An overview. International Journal of Corrosion., 2012, 1-15, 2012.
• 13. Abboud Y, Abourriche A, Saffaj T, Berrada M, Charrouf M, Bennamara A, et al., The inhibition of mild steel corrosion in acidic medium by 2,2′-bis(benzimidazole). Applied Surface Science., 252(23):8178–84, 2006.
• 14. Chauhan LR, Gunasekaran G., Corrosion inhibition of mild steel by plant extract in dilute HCl medium. Corrosion Science., 49(3):1143–61, 2007.
• 15. Al-Fakih AM, Aziz M, Sirat HM., Turmeric and ginger as green inhibitors of mild steel corrosion in acidic medium. Journal of Materials and Environmental Science., 6(5):1480–7, 2015.
• 16. Chen Y, Jiang YY, Chen H, Zhang Z, Zhang JQ, Cao CN., Corrosion inhibition of mild steel in acidic medium by linseed oil-based imidazoline. JAOCS, Journal of the American Oil Chemists’ Society., 90(9):1387–95, 2013.
• 17. Azzaoui K, Mejdoubi E, Jodeh S, Lamhamdi A, Rodriguez-Castellón E, Algarra M, et al., Eco friendly green inhibitor Gum Arabic (GA) for the corrosion control of mild steel in hydrochloric acid medium. Corrosion Science, 129(September):70–81, 2017.
• 18. Mohana KN, Badiea AM., Effect of sodium nitrite-borax blend on the corrosion rate of low carbon steel in industrial water medium. Corrosion Science, 50(10):2939–47, 2008.
• 19. Deyab MA., Egyptian licorice extract as a green corrosion inhibitor for copper in hydrochloric acid solution. Journal of Industrial and Engineering Chemistry., 22:384–9, 2015.
• 20. Stupnišek-Lisac E, Gazivoda A, Madžarac M., Evaluation of non-toxic corrosion inhibitors for copper in sulphuric acid. Electrochimica Acta., 47(26):4189–94, 2002.
• 21. Asan G., Asan A., Çeliklerin Korozyonuna Boraksın Etkisi. Journal of Boron., 6(3):332–7, 2021.
• 22. Aljourani J, Raeissi K, Golozar MA., Benzimidazole and its derivatives as corrosion inhibitors for mild steel in 1M HCl solution. Corrosion Science, 51(8):1836–43, 2009.
• 23. Verma DK, Dewangan Y, Dewangan AK, Asatker A., Heteroatom-Based Compounds as Sustainable Corrosion Inhibitors: An Overview. Journal of Bio- and Tribo-Corrosion [Internet]., 7(1), 2021.
• 24. Gurudatt DM, Mohana KN, Tandon HC., Adsorption and corrosion inhibition characteristics of some organic molecules containing methoxy phenyl moiety on mild steel in hydrochloric acid solution. Materials Discovery., 2:24–43, 2015.
• 25. Nahlé A, Abu-Abdoun II, Abdel-Rahman I., Inhibition of mild steel corrosion by 3-benzoylmethyl benzimidazolium hexafluoroantimonate in acidic solution. International Journal of Corrosion., 2012:45–7, 2012.
• 26. Moretti G, Quartarone G, Tassan A, Zingales A., 5-Amino- and 5-Chloro-Indole As Mild Steel Corrosion Inhibitors in in Sulphuric Acid. Electrochimica Acta., 41(13):1971–80, 1996.
• 27. Döner A, Solmaz R, Özcan M, Kardaş G., Experimental and theoretical studies of thiazoles as corrosion inhibitors for mild steel in sulphuric acid solution. Corrosion Science., 53(9):2902–13, 2011.
• 28. Bashir S, Sharma V, Kumar S, Ghelichkhah Z, Obot IB, Kumar A., Inhibition performances of nicotinamide against aluminum corrosion in an acidic medium. Portugaliae Electrochimica Acta., 38(2):107–23, 2020.
• 29. Hippolyte CN, Serge BY, Sagne A, Creus J, Albert T., Nicotinamide Inhibition Properties for Copper Corrosion in 3.5% NaCl Solution: Experimental and Theorical Investigations. Journal of Materials Science and Chemical Engineering., 06(03):100–21, 2018.
• 30. Tüken T, Yazici B, Erbil M., The effect of nicotinamide on iron corrosion in chloride solutions. Turkish Journal of Chemistry., 26(5):735–42, 2002.
• 31. Asan G, Asan A., Inhibitor effect of nicotinamide on corrosion of aluminum. Journal of Molecular Structure, 1201:127184, 2020.
• 32. Asan G., Protection of Copper From Corrosion With Nicotinamide Inhibitor. Hittite Journal of Science & Engineering., 8(3):273–7, 2021.
• 33. Karaer E, Köse DA., Novel mixed ligand complexes of alkaline earth metals with coumarilic acid and nicotinamide. Journal of the Turkish Chemical Society, Section A: Chemistry., 8(2):659–76, 2021.