Zeytinyağı endüstrisi atıksuyunu arıtan mikrofiltrasyon membran sisteminde organik madde gideriminin kinetik değerlendirilmesi

Yıl 2024, Cilt: 39 Sayı: 1, 287 - 298, 21.08.2023

Sevgi Tokgöz Güneş , Ezgi Oktav Akdemir

https://doi.org/10.17341/gazimmfd.1041320

Öz

Bu çalışmada, laboratuvar ölçekli bir mikrofiltrasyon membran sistemi, 100, 150 ve 200 L/sa debilerde, 1 bar basınçta ve 30, 60, 90 ve 120 dakikalık 4 farklı filtrasyon süresinde (MFS) çalıştırılmıştır. Sistem, 120 g/L kimyasal oksijen ihtiyacı (KOİ) konsantrasyonuna sahip zeytinyağı endüstrisi atıksuyu ile beslenmiştir. Mikrofiltrasyon sonrası elde edilen sonuçlar, Modifiye Stover-Kincannon modeli, İkinci Derece Kinetik model, Birinci Derece Kinetik model kullanılarak analiz edilmiş ve uygulanan modellerin deneysel verilere uygun olduğu bulunmuştur. Modifiye Stover-Kincannon model sabitleri olan Umaks ve KB sırasıyla 39,370- 46,948 g/L.dak ve 80,114-96,883 g/L.dak aralığındadır. İkinci Derece Kinetik model sabitleri olan b ve a değerleri sırasıyla 2,0349-2,0807 ve 2,5546-3,0527 1/dak ve ikinci derece KOİ giderme hız sabiti olan k2(C) değerleri ise, 39,3095-46,9741 1/dak aralığında bulunmuştur. Birinci Derece Kinetik modelinde, birinci derece KOİ giderme hız sabiti, k1, 0,8868-0,5286 1/dak aralığındadır. Yüksek korelasyon katsayıları (R2 = %100–97), uygulanan bu modellerin, mikrofiltrasyon sistem tasarımında organik madde giderme kinetiğinde kullanılabileceğini, dolayısıyla zeytinyağı endüstrisi atıksuyunun arıtımında membranın davranışını tahmin edebileceğini göstermektedir.

Anahtar Kelimeler

Kinetik model, organik madde, mikrofiltrasyon, zeytinyağı endüstrisi atıksuyu

Kaynakça

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