Electrochemical pesticide sensor based on anthraquinone substituted copper phthalocyanine

Yıl 2017, Cilt: 1 Sayı: 1, 74 - 85, 29.12.2017

Yeliz İpek , M. Kasım Şener Atıf Koca

https://doi.org/10.32571/ijct.342498

Cited By: 1

Öz

In this study, a
biomimetic selective pesticide electrochemical sensor based on copper
phthalocyanine-anthraquinone hybrid (CuPc-AQ) was studied. Electrochemical
activities based on Pc ring and anthraquinone substituent of the CuPc-AQ make
it valuable material for electrochemical sensor studies in detecting of
pesticides. Thin film of CuPc-AQ on ITO electrode (ITO/CuPc-AQ) was exposed to
water samples containing eserine and carbofuran pesticides, separately. Then in
order to observe the sensor behavior of the modified electrode, square wave
voltammetry (SWV), electrochemical impedance spectroscopy (EIS), and double
potential step chronocoulometry (DPSCC) techniques were used. When the
ITO/CuPc-AQ electrode was doped with nano-platinum (nPt) or nano-gold (nAu)
particles, the sensitivity of ITO/CuPc-AQ electrode increased. The lowest
detection limit (DL) (1.23x10-9 mol dm-3) was obtained with ITO/CuPc-AQ-nAu
electrode using electrochemical impedance spectroscopy technique.

Anahtar Kelimeler

Electrochemistry, Phthalocyanine, Pesticide sensor, Langmuir-Blodgett

Kaynakça

• 1. Samanta, S. Aquat. Ecosyst. Health Manag. 2013, 16 (4), 454-464.
• 2. Hami, H.A., Azzaoui, F.Z.; Idrissi, M.; Ouammi, L.; Mokhtari, A.; Soulaymani-Bencheikh, R.; Soulaymani, A.. Am. J. Epidemiol. 2012, 175 (11 Supl):S1-S145.
• 3. Hoai, P.M.; Sebesvari, Z.; Minh, T.B.; Viet, P.H.; Renaud, F.G. Environ. Pollut. 2011, 159 (2), 3344-3350.
• 4. Rodriguez-Liebana, J.A.; Mingorance, M.D.; Pena, A. Colloid Surface. A 2013, 435, 71-77.
• 5. Singh, N.K.; Chhillar, N.; Banerjee, B.D.; Bala, K.; Basu, M.; Mustafa, M. Hum. Exp. Toxicol. 2013, 32 (1), 24-30.
• 6. Sapbamrer, R.; Nata, S. Environ. Health Prev. 2014, 19 (1), 12-20.
• 7. Lee, K.G.; Jo, E.K. Food Chem. 2012, 134 (4), 2497-2503.
• 8. Gaffney, S.H.; Curriero, F.C.; Strickland, P.T.; Glass, G.E.; Helzlsouer, K.J.; Breysse, P.N. Environ. Health Perspect. 2005, 113 (12), 1712-1716.
• 9. Xu, M.L.; Liu, J.B.; Lu, J. Appl. Spectrosc. Rev. 2014, 49 (2), 97-120.
• 10. Fatoki, O.S.; Awofolu, R.O. J. Chromatogr A 2003, 983 (1-2), 225-236.
• 11. Luo, F.F.; Liao, S.Z.; Zhang, R.L.; Wu, Z.Y.; Yu, R.Q.; Shen, G.L. Chinese J. Anal. Chem. 2013, 41 (10), 1549-1554.
• 12. Tran, H.V.; Reisberg, S.; Piro, B.; Nguyen, T.D.; Pham, M.C. Electroanal. 2013, 25 (3), 664-670.
• 13. Chen, H.D.; Zuo, X.L.; Su, S.; Tang, Z.Z.; Wu, A.B.; Song, S.P.; Zhang, D.B.; Fan, C.H. Analyst 2008, 133 (9), 1182-1186.
• 14. Svorc, L.; Rievaj, M.; Bustin, D. Sens. Actuators B: Chem. 2013, 181, 294-300.
• 15. Eggins, B.R. Chem. Sens. Biosens. UK, 2002.
• 16. Wong, A.; Sotomayor, M.D.T. Sens. Actuators B: Chem. 2013, 181, 332-339.
• 17. Boni, A.C.; Wong., A.; Dutra, R.A.F.; Sotomayor, M.D.P.T. Talanta 2011, 85 (4), 2067-2073.
• 18. Shahrokhian, S.; Amini, M.K.; Mohammadpoor-Baltork, I.; Tangestaninejad, S. Electroanal. 2000, 12 (11), 863-867.
• 19. Rahim, A.; Barros, S.B.A.; Kubota, L.T.; Gushikem, Y. Electrochim. Acta 2011, 56 (27), 10116-10121.
• 20. Wujcik, E.K.; Londono, N.J.; Duirk, S.E.; Monty, C.N.; Masel, R.I. Chemosphere 2013, 91 (8), 1176-1182.
• 21. Lin, T.; Lin, J.; Huang, X.; Liu, J. Comm. Comp. Interface Sci. 2011, 214, 257-262.
• 22. Vial, L.; Dumy, P. New J. Chem. 2009, .33 (5), 939-946.
• 23. Bhattachayay, D.; Pal, P.; Banerjee, S.; Sanyal, S.K.; Turner, A.P.F.; Sarkar, P. Anal. Lett. 2008, 41 (8), 1387-1397.
• 24. Erbahar, D.D.; Gurol, I.; Gumus, G.; Musluoglu, E.; Ozturk, Z.Z.; Ahsen, V.; Harbeck, M. Sens. Actuators B: Chem. 2012, 173, 562-568.
• 25. Wang, P.H.; Yu, J.H.; Li, Z.J.; Ding, Z.J.; Guo, L.; Du, B. Sens. Actuators B: Chem. 2013, 188, 1306-1311.
• 26. Ipek, Y.; Dincer, H.; Koca, A. Sens. Actuators B: Chem. 2014, 193, 830-837.
• 27. Sezer, B.; Sener, M.K.; Koca, A.; Erdogmus, A.; Avciata, U. Synth. Met. 2010, 160 (19-20), 2155-2166.
• 28. Wiederkehr, N.A. Phys. Chem. Glasses: B 2008, 49 (6), 326-333.
• 29. Valli, L. Adv. Colloid Interface. 2005, 116 (1-3), 13-44.
• 30. Mahmoudian, M.R.; Alias, Y.; Basirun, W.J.; MengWoi, P.; Jamali-Sheini, F.; Sookhakian, M..; Silakhori, M. J. Electroanal. Chem. 2015, 751, 30-36.
• 31. İpek, Y.; Şener, M.K.; Koca, A.. J. Porphyrins Phthalocyanines 2015, 19, 708-718.
• 32. Wang, M.; Huang, J.; Wang, M.; Zhang, D. Chen, J. Food Chem. 2014, 151, 191-197.
• 33. Yin, H.; Ai., S.; Xu, J.; Shi, W.; Zhu, L. J. Electroanal. Chem. 2009, 637(1-2), 21-27.
• 34. Sun, X.; Zhu, Y.; Wang, X. Food Control 2012, 28, 184-191.
• 35. Zamfir, L.G.; Rotariu, L.; Bala, C. Biosens. Bioelectron. 2013, 46, 61-67.
• 36. Snejdarkova, M.; Svobodova, L.; Evtugyn, G.; Budnikov, H.; Karyakin, A.; Nikolelis, D.P.; Hianik, T. Anal. Chim. Acta 2004, 514, 79-88.
• 37. Snejdarkova, M.; Svobodova, L.; Nikolelis, D.P.; Wang, J.; Hianik, T. Electroanalysis 2003, 15(14), 1185-1191.