An Investigation on Physical and Rheological properties of Ethylene-Vinyl Acetate (EVA) Polymer Modified Bitumen
Yıl 2021,
Cilt: 3 Sayı: 1, 1 - 20, 15.07.2021
Sajjad Hassanpour Kasanagh
,
Perviz Ahmedzade
,
Taylan Günay
Öz
The effects of Ethylene-Vinyl Acetate (EVA) on physical and high temperature performance of bitumen was investigated in this work. conventional bitumen tests, rotational viscosity tests were conducted within the context of the research, and rheological studies such as dynamic shear rheometer (DSR), multiple stress creep recovery tests (MSCR) were also performed to determine high temperature performance of binders. The results indicated that EVA polymers reduce penetration, increase the softening point and viscosity of the bitumen which in turn indicates bitumen became stiffer after the modification. Besides, %7 EVA modified binder classified as PG 76 in DSR test was graded in MSCR grading system as PG70S which is one level higher compared to that of base bitumen. This result means that EVA modified binders can be used without permanent deformation until 70°C, under 10 million ESAL at 70 km/h traffic speed.
Kaynakça
- AASHTO M332. (2014). Standard Specification for Performance-Graded Asphalt Binder Using Multiple Stress Creep Recovery (MSCR) Test. In American Association of State Highway and Transportation Officials.
- AASHTO T315. (2012). Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR). In American Association of state and highway transportation officials (p. 33). Washington, DC.
- Ahmadinia, E., Zargar, M., Karim, M. R., Abdelaziz, M., and Shafigh, P. (2011). Using waste plastic bottles as additive for stone mastic asphalt. Materials & Design, 32(10), 4844–4849. https://doi.org/10.1016/j.matdes.2011.06.016
- Airey, G. D. (2002). Rheological evaluation of ethylene vinyl acetate polymer modified bitumens. Construction and Building Materials, 16(8), 473–487. https://doi.org/10.1016/S0950-0618(02)00103-4
- Airey, G. D. (2004). Fundamental binder and practical mixture evaluation of polymer modified bituminous materials. International Journal of Pavement Engineering, 5(3), 137–151. https://doi.org/10.1080/10298430412331314146
- Al-Hadidy, A. I., & Yi-Qiu, T. (2009). Mechanistic approach for polypropylene-modified flexible pavements. Materials & Design, 30(4), 1133–1140. https://doi.org/10.1016/j.matdes.2008.06.021
- Almusawi, A., Sengoz, B., and Topal, A. (2020). Investigation of Mixing and Compaction Temperatures of Modified Hot Asphalt and Warm Mix Asphalt. Periodica Polytechnica Civil Engineering. 65(1), 72–83. https://doi.org/10.3311/PPci.15118
- Ameri, M., Mansourian, A., and Sheikhmotevali, A. H. (2012). Investigating effects of ethylene vinyl acetate and gilsonite modifiers upon performance of base bitumen using Superpave tests methodology. Construction and Building Materials, 36, 1001–1007. https://doi.org/10.1016/j.conbuildmat.2012.04.137
- ASTM D2872. (2012). Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). In USA: Annual Book of ASTM Standards.
- ASTM D36/D36M. (2014). Standard Test Method for Softening Point of Bitumen (Ring-and-Ball Apparatus). ASTM International, West Conshohocken, PA.
- ASTM D4402. (2015). Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer. American Society for Testing and Materials.
- Behnood, A. (2020). A review of the warm mix asphalt (WMA) technologies: Effects on thermo-mechanical and rheological properties. Journal of Cleaner Production, 120817. https://doi.org/10.1016/j.jclepro.2020.120817
- Behnood, A., and Olek, J. (2017). Rheological properties of asphalt binders modified with styrene-butadiene-styrene (SBS), ground tire rubber (GTR), or polyphosphoric acid (PPA). Construction and Building Materials, 151, 464–478. https://doi.org/10.1016/j.conbuildmat.2017.06.115
- Fernandes, M. R. S., Forte, M. M. C., and Leite, L. F. M. (2008). Rheological evaluation of polymer-modified asphalt binders. Materials Research, 11(3), 381–386. https://doi.org/10.1590/S1516-14392008000300024
- Garcı́a-Morales, M., Partal, P., Navarro, F. J., Martı́nez-Boza, F., Gallegos, C., González, N., González, O., and Muñoz, M. E. (2004). Viscous properties and microstructure of recycled eva modified bitumen. Fuel, 83(1), 31–38. https://doi.org/10.1016/S0016-2361(03)00217-5
- Haddadi, S., Ghorbel, E., and Laradi, N. (2008). Effects of the manufacturing process on the performances of the bituminous binders modified with EVA. Construction and Building Materials, 22(6), 1212–1219. https://doi.org/10.1016/j.conbuildmat.2007.01.026
- Hunter, R. N., Andy Self., and John Read. (2015). The shell bitumen handbook. Thomas Telford.
- Kaya, D., Topal, A., and McNally, T. (2019). Correlation of processing parameters and ageing with the phase morphology of styrene-butadiene-styrene block co-polymer modified bitumen. Materials Research Express, 6(10), 105309.
- Hassanpour Kasanagh, S., (2020). Geri Dönüştürülmüş Polimer ve Atık Lastik Tozu Esaslı Termoplastik Dinamik Vulkanizat (TDV) Katkısının Bitüm ve Bitümlü Sıcak Karışımlar Üzerinde Etkisinin İncelenmesi. Doktora Tezi, Ege Üniversitesi, Fen Bilimleri Enstitüsü, İzmir.
- Król, J., Radziszewski, P., and Kowalski, K. J. (2015). Influence of microstructural behavior on multiple stress creep recovery (MSCR) in modified bitumen. Procedia Engineering, 111, 478–484. https://doi.org/10.1016/j.proeng.2015.07.119
- McGennis, R. B., Anderson, R. M., Kennedy, T. W., and Solaimanian, M. (1995). Background of SUPERPAVE asphalt mixture design and analysis. United States. Federal Highway Administration. Office of Technology Applications.
- Polacco, G., Stastna, J., Vlachovicova, Z., Biondi, D., and Zanzotto, L. (2004). Temporary networks in polymer‐modified asphalts. Polymer Engineering & Science, 44(12), 2185–2193. https://doi.org/10.1002/pen.20246
- Sengoz, B., and Isikyakar, G. (2008). Evaluation of the properties and microstructure of SBS and EVA polymer modified bitumen. Construction and Building Materials, 22(9), 1897–1905. https://doi.org/10.1016/j.conbuildmat.2007.07.013
- Köfteci, S., Gunay, T., and Ahmedzade, P. (2020). Rheological Analysis of Modified Bitumen by PVC Based Various Recycled Plastics. Journal of Transportation Engineering, Part B: Pavements, 146(4), 04020063. https://doi.org/10.1061/JPEODX.0000214
- Stastna, J., Zanzotto, L., and Vacin, O. J. (2003). Viscosity function in polymer-modified asphalts. Journal of Colloid and Interface Science, 259(1), 200–207. https://doi.org/10.1016/S0021-9797(02)00197-2
- Zaniewski, J. P., and Pumphrey, M. E. (2004). Evaluation of performance graded asphalt binder equipment and testing protocol. Asphalt Technology Program, 107, 376-384
Etilen Vinil Asetat (EVA) Polimer Modifiyeli Bitümün Fiziksel ve Reolojik Özelliklerinin Araştırılması
Yıl 2021,
Cilt: 3 Sayı: 1, 1 - 20, 15.07.2021
Sajjad Hassanpour Kasanagh
,
Perviz Ahmedzade
,
Taylan Günay
Öz
Bu çalışmada, Etilen Vinil Asetat (EVA) polimer katkısının bitümün fiziksel ve yüksek sıcaklık performansı üzerindeki etkisi incelenmiştir. Araştırma kapsamında geleneksel bitüm deneyleri ile birlikte dönel viskozite deneyleri gerçekleştirilmiş ayrıca bağlayıcıların yüksek sıcaklık performansını belirleyen reolojik çalışmalar dinamik kayma reometresi (DSR) ve çoklu gerilmeli sünme geri dönme (MSCR) deneyleri yardımıyla uygulanmıştır. Çalışmanın sonucunda, EVA polimeri saf bitümün penetrasyonu düşürdüğü, yumuşama noktası ve viskozitesini ise arttırdığı tespit edilmiş bu sayede bitümün fiziksel olarak sertleşmesine neden olduğu ortaya konmuştur. Ayrıca, çalışma kapsamında DSR yüksek sıcaklık performans sınıfı (PG) 76 °C olarak tespit edilen %7 EVA katkılı bağlayıcının MSCR deneyine göre performans sınıfı PG70S olarak belirlenmiş ve PG64S olan saf bitüme göre bir sınıf artış sağlandığı belirlenmiştir. Bu sonuç, EVA katkılı bitümün 70°C sıcaklıkta, 70 km/s üzeri araç hızında ve yirmi yıl boyunca trafik tasarım şeridinde beklenen maksimum 10 milyon (eşdeğer standard dingil yükü) ESAL sayısında kalıcı deformasyona maruz kalmadan kullanılabileceğini ifade etmektedir.
Kaynakça
- AASHTO M332. (2014). Standard Specification for Performance-Graded Asphalt Binder Using Multiple Stress Creep Recovery (MSCR) Test. In American Association of State Highway and Transportation Officials.
- AASHTO T315. (2012). Standard method of test for determining the rheological properties of asphalt binder using a dynamic shear rheometer (DSR). In American Association of state and highway transportation officials (p. 33). Washington, DC.
- Ahmadinia, E., Zargar, M., Karim, M. R., Abdelaziz, M., and Shafigh, P. (2011). Using waste plastic bottles as additive for stone mastic asphalt. Materials & Design, 32(10), 4844–4849. https://doi.org/10.1016/j.matdes.2011.06.016
- Airey, G. D. (2002). Rheological evaluation of ethylene vinyl acetate polymer modified bitumens. Construction and Building Materials, 16(8), 473–487. https://doi.org/10.1016/S0950-0618(02)00103-4
- Airey, G. D. (2004). Fundamental binder and practical mixture evaluation of polymer modified bituminous materials. International Journal of Pavement Engineering, 5(3), 137–151. https://doi.org/10.1080/10298430412331314146
- Al-Hadidy, A. I., & Yi-Qiu, T. (2009). Mechanistic approach for polypropylene-modified flexible pavements. Materials & Design, 30(4), 1133–1140. https://doi.org/10.1016/j.matdes.2008.06.021
- Almusawi, A., Sengoz, B., and Topal, A. (2020). Investigation of Mixing and Compaction Temperatures of Modified Hot Asphalt and Warm Mix Asphalt. Periodica Polytechnica Civil Engineering. 65(1), 72–83. https://doi.org/10.3311/PPci.15118
- Ameri, M., Mansourian, A., and Sheikhmotevali, A. H. (2012). Investigating effects of ethylene vinyl acetate and gilsonite modifiers upon performance of base bitumen using Superpave tests methodology. Construction and Building Materials, 36, 1001–1007. https://doi.org/10.1016/j.conbuildmat.2012.04.137
- ASTM D2872. (2012). Standard test method for effect of heat and air on a moving film of asphalt (rolling thin-film oven test). In USA: Annual Book of ASTM Standards.
- ASTM D36/D36M. (2014). Standard Test Method for Softening Point of Bitumen (Ring-and-Ball Apparatus). ASTM International, West Conshohocken, PA.
- ASTM D4402. (2015). Standard test method for viscosity determination of asphalt at elevated temperatures using a rotational viscometer. American Society for Testing and Materials.
- Behnood, A. (2020). A review of the warm mix asphalt (WMA) technologies: Effects on thermo-mechanical and rheological properties. Journal of Cleaner Production, 120817. https://doi.org/10.1016/j.jclepro.2020.120817
- Behnood, A., and Olek, J. (2017). Rheological properties of asphalt binders modified with styrene-butadiene-styrene (SBS), ground tire rubber (GTR), or polyphosphoric acid (PPA). Construction and Building Materials, 151, 464–478. https://doi.org/10.1016/j.conbuildmat.2017.06.115
- Fernandes, M. R. S., Forte, M. M. C., and Leite, L. F. M. (2008). Rheological evaluation of polymer-modified asphalt binders. Materials Research, 11(3), 381–386. https://doi.org/10.1590/S1516-14392008000300024
- Garcı́a-Morales, M., Partal, P., Navarro, F. J., Martı́nez-Boza, F., Gallegos, C., González, N., González, O., and Muñoz, M. E. (2004). Viscous properties and microstructure of recycled eva modified bitumen. Fuel, 83(1), 31–38. https://doi.org/10.1016/S0016-2361(03)00217-5
- Haddadi, S., Ghorbel, E., and Laradi, N. (2008). Effects of the manufacturing process on the performances of the bituminous binders modified with EVA. Construction and Building Materials, 22(6), 1212–1219. https://doi.org/10.1016/j.conbuildmat.2007.01.026
- Hunter, R. N., Andy Self., and John Read. (2015). The shell bitumen handbook. Thomas Telford.
- Kaya, D., Topal, A., and McNally, T. (2019). Correlation of processing parameters and ageing with the phase morphology of styrene-butadiene-styrene block co-polymer modified bitumen. Materials Research Express, 6(10), 105309.
- Hassanpour Kasanagh, S., (2020). Geri Dönüştürülmüş Polimer ve Atık Lastik Tozu Esaslı Termoplastik Dinamik Vulkanizat (TDV) Katkısının Bitüm ve Bitümlü Sıcak Karışımlar Üzerinde Etkisinin İncelenmesi. Doktora Tezi, Ege Üniversitesi, Fen Bilimleri Enstitüsü, İzmir.
- Król, J., Radziszewski, P., and Kowalski, K. J. (2015). Influence of microstructural behavior on multiple stress creep recovery (MSCR) in modified bitumen. Procedia Engineering, 111, 478–484. https://doi.org/10.1016/j.proeng.2015.07.119
- McGennis, R. B., Anderson, R. M., Kennedy, T. W., and Solaimanian, M. (1995). Background of SUPERPAVE asphalt mixture design and analysis. United States. Federal Highway Administration. Office of Technology Applications.
- Polacco, G., Stastna, J., Vlachovicova, Z., Biondi, D., and Zanzotto, L. (2004). Temporary networks in polymer‐modified asphalts. Polymer Engineering & Science, 44(12), 2185–2193. https://doi.org/10.1002/pen.20246
- Sengoz, B., and Isikyakar, G. (2008). Evaluation of the properties and microstructure of SBS and EVA polymer modified bitumen. Construction and Building Materials, 22(9), 1897–1905. https://doi.org/10.1016/j.conbuildmat.2007.07.013
- Köfteci, S., Gunay, T., and Ahmedzade, P. (2020). Rheological Analysis of Modified Bitumen by PVC Based Various Recycled Plastics. Journal of Transportation Engineering, Part B: Pavements, 146(4), 04020063. https://doi.org/10.1061/JPEODX.0000214
- Stastna, J., Zanzotto, L., and Vacin, O. J. (2003). Viscosity function in polymer-modified asphalts. Journal of Colloid and Interface Science, 259(1), 200–207. https://doi.org/10.1016/S0021-9797(02)00197-2
- Zaniewski, J. P., and Pumphrey, M. E. (2004). Evaluation of performance graded asphalt binder equipment and testing protocol. Asphalt Technology Program, 107, 376-384