Öz
Immıscible polymethyl methacrylate/polystyrene (PMMA/PS) mixtures with various maleic anhydride-styrene-methyl methacrylate (MAStMMA) compatibilizer ratio (0, 2, 4, 6, 8 and 10) % were obtained by solution casting. The spectral results showed that the optical constants such as refractive index (n), extinction coefficient (k) and absorption coefficient increase with increasing terpolymer compatibilizer ratio. On the other hand, the optical energy gap Eg showed an inverse trend to concerning optical constants. The lowest observed energy gap was between 8 and 10 % compatibilizer ratio.
Anahtar Kelimeler
compatibilization maleic anhydride optical constants polymer blending
Kaynakça
- Abdullah O. Gh., Tahir D. A., Aziz S-A. B., (2010), Optical and Electrical Properties of Polyvinyl-chloride (PVC) Films, Iraqi Journal of Science 51 295-300
- Alias, A. N., Zabidi, Z. M., Ali, A. M. M., Harun, M. K., and Yahya, M. Z. A., (2013), Optical characterization and properties of polymeric materials for optoelectronic and photonic applications. International Journal of Applied Science and Technology, 3 (5), 11-38
- Alwan, T.J., (2012), Gamma irradiation effect on the optical properties and refractive index dispersion of dye doped polystyrene films, Turk. J. Phys., 36, PP. 377-384
- Aly K.A., Abd Elnaeim A. M., Afify N., Abousehly A. M., (2012), Improvement of the electrical properties of Se3Te1 thin films by In additions, J. Non Cryst. Solids 358, 2759.
- Boztug A., Yilmaz E., (2007), Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends, Materials Research Innovations, 11(3) , 158-160
- Imren D., Boztug A., Yilmaz E., Zengin H.B, (2008), Viscometric investigation of compatibilization of the poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends by terpolymer of maleic anhydride-styrene-vinyl acetate, Journal of Molecular Structure, 891, 329-332
- Imren D., (2010), Compatibilization of immiscible poly(vinyl chloride) (PVC)/polystyrene (PS) blends with maleic anhydride-styrene-vinyl acetate terpolymer (MAStVA), Journal of Molecular Structure , 963, 245-249
- Imren Koç D., Koç M. L., (2016), Fuzzy viscometric analysis of polymer-polymer miscibility based on fuzzy regression, Chemometrics and Intelligent Laboratory Systems, 157, 58-66
- Imren Koç D., Özel Ergün N., Koç M. L., (2019), Prediction of miscibility of sodium alginate/poly(ethylene glycol) blends by fuzzy systems, Journal the Faculty of Engineering and Architecture of Gazi University, of 34(2), 635-646
- Jang Yea-Fen, Lin Tzu-Chun , Guo Jhih-Yan , Chiang Chien-Ming F., Wu Ming-Lun, Shen Hsin-Yi, Chen Tsung-Cheng, Yang Zu-Po, Lee Ya-Ju, Su Hai-Ching, Chang Chih-Hao, Liu Shun-Wei, Enhancing extracted electroluminescence from light-emitting electrochemical cells by employing high-refractive-index substrates, Organic Electronics,51, 149-155
- Khan Z., Baloch M.K., (2014), Effect of solvent on the miscibility of polystyrene/poly(styrene-co-acrylonitrile) blends at different temperatures, J. Macromol. Sci., Part B: Phys. 53, 1027–1049
- Kim S., Park H., Nam G., Yoon H., Leem J., (2013), Improved optical and electrical properties of sol–gel-derived boron-doped zinc oxide thin films, Journal of Sol-Gel Science and Technology, 67, 580-591
- Kim, J., Kim, H., Kim, B., Highly tunable refractive index visible-light metasurface from block copolymer self-assembly. Nat. Commun 7, 12911
- Kumar K.K., M. Ravi, Y. Pavani, S. Bhavani, A.K. Sharma, V.V.R. Narasimha Rao, (2011) Investigations on the effect of complexation of NaF salt with polymer blend (PEO/PVP) electrolytes on ionic conductivity and optical energy band gaps, Physica B: Condensed Matter, 406 (9), 1706-1712
- Najeeb H. N., Balakit A. A., Wahab G. A., (2014), Kodeary A. K., Study of the optical properties of poly (methyl methacrylate) (PMMA) doped with a new diarylethen compound, Academic Research International, 5(1), 48-56
- Nawar A. M., Abdel-Aal N., Said N., El-Tantawy F.M., Yakuphanoğlu F.,(2014), Improving the optical and electrical properties of Zinc Oxide thin film by Cupric Oxide dopant, IOSR Journal of Applied Physics, 6, 17-22
- Shahin A., Bachir W., El-Daher M. S., (2019), Polystyrene Microsphere Optical Properties by Kubelka–Munk and Diffusion Approximation with a Single Integrating Sphere System: A Comparative Study", Journal of Spectroscopy, (2019), Article ID3406319, 8 pages
- Soygun K., Şimşek S., Yılmaz E., and Bolayir G., (2013), Investigation of mechanical and structural properties of blend lignin-PMMA. Adv Mater Sci Eng, 2013: 1–6
- Sultanova N., Kasarova S., Nikolov I., (2016), Advanced applications of optical polymers, Bulg. J. Phys., 43, 243-250
- Sultanova, N.G., Kasarova, S.N. & Nikolov, I.D., (2013), Characterization of optical properties of optical polymers. Opt Quant Electron 45, 221–232
- Tauc J., Amorphous and Liquid Semiconductors, Plenum, New York, 1974.
- Yilmaz E., (2022), Compatibilization of polyvinyl chloride - polymethyl methacrylate polymer blends with maleic anhydride-styrene-methyl methacrylate terpolymer J. Appl. Polym. Sci. 139(10), 51745
- Doğan A., Kısmet Y. (2021). Gama Işımasının Kolza Takviyeli Polipropilen Kompozit Malzemenin Mekanik Özellikleri Üzerindeki Etkisi. International Journal of Pure and Applied Sciences. doi:10.29132/ijpas.996361
Öz
Karışmayan polimetil metakrilat/polistiren (PMMA/PS) harmanları değişik maleik anhidrit-stiren-metil metakrilat (MAStMMA) uyumlaştırıcı oranı (0, 2, 4, 6, 8 ve 10) eklenerek çözeltiden döküm yoluyla elde edilmiştir. Spektral sonuçlar, kırılma indisi (n), sönüm katsayısı (k) ve absorpsiyon katsayısı (µ) gibi optik sabitlerin terpolimer bazlı uyumlaştırıcı ilavesiyle arttığını göstermiştir. Diğer yandan optik enerji boşluğu Eg, anılan optik sabitlere göre zıt bir eğilim göstermiştir. Gözlenen en düşük enerji boşluğu %8 ila %10 uyumlaştırıcı oranı arasında belirlenmiştir.
Anahtar Kelimeler
uyumlaştırma maleik anhidrit optik sabitler polimer harmanlama
Kaynakça
- Abdullah O. Gh., Tahir D. A., Aziz S-A. B., (2010), Optical and Electrical Properties of Polyvinyl-chloride (PVC) Films, Iraqi Journal of Science 51 295-300
- Alias, A. N., Zabidi, Z. M., Ali, A. M. M., Harun, M. K., and Yahya, M. Z. A., (2013), Optical characterization and properties of polymeric materials for optoelectronic and photonic applications. International Journal of Applied Science and Technology, 3 (5), 11-38
- Alwan, T.J., (2012), Gamma irradiation effect on the optical properties and refractive index dispersion of dye doped polystyrene films, Turk. J. Phys., 36, PP. 377-384
- Aly K.A., Abd Elnaeim A. M., Afify N., Abousehly A. M., (2012), Improvement of the electrical properties of Se3Te1 thin films by In additions, J. Non Cryst. Solids 358, 2759.
- Boztug A., Yilmaz E., (2007), Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends, Materials Research Innovations, 11(3) , 158-160
- Imren D., Boztug A., Yilmaz E., Zengin H.B, (2008), Viscometric investigation of compatibilization of the poly(vinyl chloride)/poly(ethylene-co-vinyl acetate) blends by terpolymer of maleic anhydride-styrene-vinyl acetate, Journal of Molecular Structure, 891, 329-332
- Imren D., (2010), Compatibilization of immiscible poly(vinyl chloride) (PVC)/polystyrene (PS) blends with maleic anhydride-styrene-vinyl acetate terpolymer (MAStVA), Journal of Molecular Structure , 963, 245-249
- Imren Koç D., Koç M. L., (2016), Fuzzy viscometric analysis of polymer-polymer miscibility based on fuzzy regression, Chemometrics and Intelligent Laboratory Systems, 157, 58-66
- Imren Koç D., Özel Ergün N., Koç M. L., (2019), Prediction of miscibility of sodium alginate/poly(ethylene glycol) blends by fuzzy systems, Journal the Faculty of Engineering and Architecture of Gazi University, of 34(2), 635-646
- Jang Yea-Fen, Lin Tzu-Chun , Guo Jhih-Yan , Chiang Chien-Ming F., Wu Ming-Lun, Shen Hsin-Yi, Chen Tsung-Cheng, Yang Zu-Po, Lee Ya-Ju, Su Hai-Ching, Chang Chih-Hao, Liu Shun-Wei, Enhancing extracted electroluminescence from light-emitting electrochemical cells by employing high-refractive-index substrates, Organic Electronics,51, 149-155
- Khan Z., Baloch M.K., (2014), Effect of solvent on the miscibility of polystyrene/poly(styrene-co-acrylonitrile) blends at different temperatures, J. Macromol. Sci., Part B: Phys. 53, 1027–1049
- Kim S., Park H., Nam G., Yoon H., Leem J., (2013), Improved optical and electrical properties of sol–gel-derived boron-doped zinc oxide thin films, Journal of Sol-Gel Science and Technology, 67, 580-591
- Kim, J., Kim, H., Kim, B., Highly tunable refractive index visible-light metasurface from block copolymer self-assembly. Nat. Commun 7, 12911
- Kumar K.K., M. Ravi, Y. Pavani, S. Bhavani, A.K. Sharma, V.V.R. Narasimha Rao, (2011) Investigations on the effect of complexation of NaF salt with polymer blend (PEO/PVP) electrolytes on ionic conductivity and optical energy band gaps, Physica B: Condensed Matter, 406 (9), 1706-1712
- Najeeb H. N., Balakit A. A., Wahab G. A., (2014), Kodeary A. K., Study of the optical properties of poly (methyl methacrylate) (PMMA) doped with a new diarylethen compound, Academic Research International, 5(1), 48-56
- Nawar A. M., Abdel-Aal N., Said N., El-Tantawy F.M., Yakuphanoğlu F.,(2014), Improving the optical and electrical properties of Zinc Oxide thin film by Cupric Oxide dopant, IOSR Journal of Applied Physics, 6, 17-22
- Shahin A., Bachir W., El-Daher M. S., (2019), Polystyrene Microsphere Optical Properties by Kubelka–Munk and Diffusion Approximation with a Single Integrating Sphere System: A Comparative Study", Journal of Spectroscopy, (2019), Article ID3406319, 8 pages
- Soygun K., Şimşek S., Yılmaz E., and Bolayir G., (2013), Investigation of mechanical and structural properties of blend lignin-PMMA. Adv Mater Sci Eng, 2013: 1–6
- Sultanova N., Kasarova S., Nikolov I., (2016), Advanced applications of optical polymers, Bulg. J. Phys., 43, 243-250
- Sultanova, N.G., Kasarova, S.N. & Nikolov, I.D., (2013), Characterization of optical properties of optical polymers. Opt Quant Electron 45, 221–232
- Tauc J., Amorphous and Liquid Semiconductors, Plenum, New York, 1974.
- Yilmaz E., (2022), Compatibilization of polyvinyl chloride - polymethyl methacrylate polymer blends with maleic anhydride-styrene-methyl methacrylate terpolymer J. Appl. Polym. Sci. 139(10), 51745
- Doğan A., Kısmet Y. (2021). Gama Işımasının Kolza Takviyeli Polipropilen Kompozit Malzemenin Mekanik Özellikleri Üzerindeki Etkisi. International Journal of Pure and Applied Sciences. doi:10.29132/ijpas.996361
Ayrıntılar
| Birincil Dil | İngilizce |
|---|---|
| Konular | Mühendislik |
| Bölüm | Makaleler |
| Yazarlar | |
| Yayımlanma Tarihi | 30 Haziran 2022 |
| Gönderilme Tarihi | 7 Ocak 2022 |
| Kabul Tarihi | 16 Şubat 2022 |
| Yayımlandığı Sayı | Yıl 2022 |