Preparation and Characterization of Polymer Supported Lewis Acid-type Calix[4]arene for Transport of Dichromate Anions

Yıl 2019, Cilt: 4 Sayı: 3, 460 - 464, 30.12.2019

Seydahmet Çay , Serkan Sayin , Mehmet Soner Engin , Sait Malkondu

https://doi.org/10.35229/jaes.631189

Öz

The article describes the
fabrication and characterization of a new 25,27-bis[5-(trimethyl ammonium
bromide)pentyloxyl]-26,28-dihydroxyl-5,11,17,23-tetra-tert-butylcalix[4]arene-embedded polymer inclusion membranes (TMAC[4]Bu^t@PI membrane).
TGA, SEM and DSC techniques were performed to determine its structures.
Moreover, the anion transport capacity of TMAC[4]Bu^t@PI
membrane against Cr(VI) anion was investigated.

Anahtar Kelimeler

Calixarene, dichromate, membrane

Destekleyen Kurum

Giresun University Scientific Research Project.

Proje Numarası

FEN-BAP-A-230218-29

Kaynakça

• 1. Bozkurt, S. and M.B. Turkmen, Synthesis of Calix[4]arene-Based Thiourea Derivatives for Extraction of Toxic Dichromate and Arsenate Ions. Polycyclic Aromatic Compounds, 2018. 38(2): p. 157-167.2. Bozkurt, S., et al., Synthesis and dichromate anion sorption of silica gel-immobilized calix[4]arenes. Journal of Hazardous Materials, 2009. 165(1-3): p. 974-979.3. Krishna, P.G., et al., Preconcentrative separation of chromium(VI) species from chromium(III) by coprecipitation of its ethyl xanthate complex onto naphthalene. Talanta, 2004. 63(3): p. 541-546.4. Bayrakci, M., et al., Electrospun Nanofibrous Polyacrylonitrile/calixarene Mats: an Excellent Adsorbent for the Removal of Chromate Ions from Aqueous Solutions. Acta Chimica Slovenica, 2017. 64(3): p. 679-685.5. Kaya, A., et al., Removal of Cr(VI) through calixarene based polymer inclusion membrane from chrome plating bath water. Chemical Engineering Journal, 2016. 283: p. 141-149.6. Sap, A., B. Tabakci, and A. Yilmaz, Calix[4]arene-based Mannich and Schiff bases as versatile receptors for dichromate anion extraction: synthesis and comparative studies. Tetrahedron, 2012. 68(42): p. 8739-8745.7. Hsu, L.C., et al., Cr(VI) Removal on Fungal Biomass of Neurospora crassa: the Importance of Dissolved Organic Carbons Derived from the Biomass to Cr(VI) Reduction. Environmental Science & Technology, 2010. 44(16): p. 6202-6208.8. Engin, M.S., et al., Preparation and characterisation of thiol functionalised p-tert-butylcalix[4]arene-embedded polymer inclusion membranes: performance and selectivity. International Journal of Environmental Analytical Chemistry, 2019. 99(11): p. 1103-1111.9. Nghiem, L.D., et al., Extraction and transport of metal ions and small organic compounds using polymer inclusion membranes (PIMs). Journal of Membrane Science, 2006. 281(1-2): p. 7-41.10. Sayin, S., F. Ozcan, and M. Yilmaz, Preparation and Application of Calix[4]arene Derivatives Bearing Pyridinium Units-Grafted Magnetite Nanoparticles for Removal of Dichromate and Arsenate Anions. Journal of Macromolecular Science Part a-Pure and Applied Chemistry, 2011. 48(5): p. 365-372.11. Liu, Y.N. and Z.M. Zhong, Extraction of Heavy Metals, Dichromate Anions and Rare Metals by New Calixarene-Chitosan Polymers. Journal of Inorganic and Organometallic Polymers and Materials, 2018. 28(3): p. 962-967.12. Tabakci, M. and M. Yilmaz, Synthesis of a chitosan-linked calix[4]arene chelating polymer and its sorption ability toward heavy metals and dichromate anions. Bioresource Technology, 2008. 99(14): p. 6642-6645.13. Gutsche, C.D., Single step synthesis and properties of calixarenes In Calixarenes: A Versatile Class of Macrocyclic Compounds, ed. Vicens, in Topics in Inclusion Science. 1990. p. 3-37.14. Sayin, S. and M. Yilmaz, Synthesis of environmentally friendly, efficient and highly recyclable Lewis acid-type calix[4]arene catalysts containing flexible or bulky groups for the Mannich reaction. Rsc Advances, 2017. 7(18): p. 10748-10756.15. Engin, M.S., S. Sayin, and S. Cay, Utilization of transport efficacy of novel calix[4]arene-embedded polymer inclusion membrane towards trace metals. Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2018. 92(1-2): p. 173-179.16. Zawierucha, I., C. Kozlowski, and G. Malina, Removal of toxic metal ions from landfill leachate by complementary sorption and transport across polymer inclusion membranes. Waste Management, 2013. 33(10): p. 2129-2136.17. Koseoglu, T.S., et al., Preparation and characterization of P2FAn/PVDF composite cation-exchange membranes for the removal of Cr(III) and Cu(II) by Donnan dialysis. Reactive & Functional Polymers, 2010. 70(11): p. 900-907.