Li+ doped chitosan-based solid polymer electrolyte incorporated with PEDOT:PSS for electrochromic device

Year 2018, Volume: 5 Issue: 3, 1413 - 1422, 01.09.2018

Esin Eren

https://doi.org/10.18596/jotcsa.433901

Cited By: 4

Abstract

In this study, solid polymer electrolyte (SPE)
based on chitosan (Ch) was prepared with addition of poly(3,4-ethylenedioxythiophene):polystyrene
sulfonate (PEDOT:PSS), lithium trifluro methane sulfonate (LiTRIF),  propylene carbonate (PC) by solvent casting
technique. The chitosan-based polymer electrolyte was characterized using electrochemical impedance spectroscopy (EIS). The ionic
conductivity value was calculated as 4.2 x 10^-4 S/cm. The SPE having
good ionic conductivity was used to fabricate electrochromic device with
glass/ITO/WO₃׀PEDOT:PSS-Ch-LiTRIF-PC׀ITO/glass whose
performance was evaluated via cyclic voltammetry, transmittance, repeating
chronoamperometry. The optical contrast of ECD was attained as 22% at 800 nm,
which resulting in coloration efficiency of 67 cm²/C. The ECD displays fast
response time for coloration (t_c ) is 0.29 s. Upon reversal of
potential bleaching (t_b ) forms within 3 s. The findings
demonstrated that this SPE electrolyte has promising candidate for use in
optoelectronic applications. 

Keywords

Chitosan, Electrolyte, Electrochromic Device, PEDOT:PSS

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