Synthesis, spectroscopic, thermal, and structural properties of cyanobridged metal complexes containing tetracyanonickelate(II) building blocks with 4-aminomethylpyridine

Year 2019, Volume: 6 Issue: 3, 395 - 402, 20.10.2019

Dursun Karaağaç

https://doi.org/10.18596/jotcsa.453521

Cited By: 1

Abstract

New cyano-bridged metal complexes with chemical formulas [Fe(NH3)2(ampy)Ni(CN)4]n, [Co(H2O)2(ampy)Ni(CN)4]n and [Ni(NH3)2(ampy)Ni(CN)4]n (ampy = 4-aminomethylpyridine, hereafter abbreviated as Fe–Ni–ampy, Co–Ni–ampy and Ni–Ni–ampy) were obtained in the form of powders and examined by vibrational (infrared and Raman) spectroscopy, thermal (TG, DTG and DTA), and elemental analysis techniques. The infrared and Raman spectra of the complexes were performed in the range of 4000–400 cm-1 and 4000–250 cm-1, respectively. General information about the structural features of synthesized complexes was obtained by considering the changes in the cyano group and characteristic peaks of ampy. The cleavage of the (CN) stretching bands in the infrared spectrum of the complexes shows that the terminal and bridge cyano groups are in the structure. Considering the variations in the vibrational frequencies of the cyano group and ampy ligand in the spectrum of the complexes, the Ni atom is in a square plane geometry with four cyano groups and two of these cyano groups are the bridge and the other two are terminal. In addition, the metal atoms [Fe(II), Co(II) or Ni(II)]  are linked to the ring and amino nitrogen atoms of two symmetric ampy ligands, the two ammonia (two aqua ligands for Co–Ni–ampy) ligands and the two bridging cyano groups, and show a distorted octahedral geometry. The thermal degradation of the complexes was also studied between 30 and 950 ºC using TG, DTG, and DTA techniques.

Keywords

Tetracyanonickelate(II), 4-aminomethylpyridine, Cyano-bridged complex, Vibration spectra

References

• 1.Wong-Ng W, Culp J, Siderius D, Chen Y. Synthesis and synchrotron X-ray characterization of two 2D Hoffman related compounds [Ni(p-Xylylenediamine)nNi(CN)4] and [Ni(p-tetrafluoroxylylenediamine)nNi(CN)4]. Solid State Sci. 2018;81:12-8.
• 2. Wong-Ng W, Williamson I, Lawson M, Siderus D W, Jeffrey T, Culp J F. Electronic structure, pore size distribution, and sorption characterization of an unusual MOF, {[Ni (dpbz)][Ni(CN)4]}n, dpbz=1,4-bis(4-pyridyl)benzene. J. Appl. Phys. 2018;123(24):245105.
• 3.Lu W, Wei Z, Gu Z-Y, Liu T.F, Park J, Park J, Tian J, Zhang M, Zhang Q, Gentle T, Boscha M, Zhou H C. Tuning the structure and function of metal–organic frameworks via linker design. Chem. Soc. Rev. 2014;43(16):5561-93.
• 4.Li Y, Liu Y, Wang Y, Leng Y, Xie L, Li X. Hydrogen storage properties of [M(Py){Ni(CN) 4}] (M=Fe, Co, Ni). Int. J. Hydrogen Energy. 2007;32(15):3411-5.
• 5.Culp JT, Natesakhawat S, Smith MR, Bittner E, Matranga C, Bockrath B. Hydrogen storage properties of rigid three-dimensional hofmann clathrate derivatives: The effects of pore size. J. Phys. Chem. 2008;112(17):7079-83.
• 6.Massasso G, Rodríguez-Castillo M, Long J, Haines J, Devautour-Vinot S, Maurin G, Grandjean A, Onida B, Donnadieu B, Larionova J, Guérina C, Guari Y. Molecular iodine adsorption within Hofmann-type structures M(L)[M′(CN)4](M=Ni, Co; M′=Ni, Pd, Pt): impact of their composition. Dalton Trans. 2015;44(44):19357-69.
• 7.Černák J, Orendáč M, Potočňák I, Chomič J, Orendáčová A, Skoršepa J, Feher A. Cyanocomplexes with one-dimensional structures: preparations, crystal structures and magnetic properties. Coord. Chem. Rev. 2002;224(1-2):51-66.
• 8.Kämper M, Wagner M, Weiß A. Krypton‐und Xenon‐Einschlußverbindungen komplexer Metallcyanide. Angew. Chem. 1979;91(6):517-8.
• 9.Gapud A, Weber A, Alexander J, Pham L, Khan A, Leatherbury R I, Reyes A P, Lumata L L, Kuhns P L, Valente E J, Sykora R E. New quasi-one-dimensional tetracyanidoplatinate, Cs4[Pt(CN)4](CF3SO3)2: Synthesis, structure, and physical characterization. J. Phys. Chem. Solids. 2014;75(3):447-52.
• 10.Çetinkaya F, Kürkçüoğlu G S, Yeşilel O Z, Hökelek T, Dal H. One-dimensional cyano-bridged heterometallic (Cu/Ni and Cu/Pd) complexes with 1-ethylimidazole. Polyhedron 2012;47(1):126-33.
• 11.Potocnak I, Vavra M, Cizmar E, Tibenská K, Orendáčová A, Steinborn D, Wagner C, Dušek M, Fejfarová K, Fejfarová H, Muller C, Orendáč M, Feher A J. Low-dimensional compounds containing cyano groups. XIV. Crystal structure, spectroscopic, thermal and magnetic properties of [CuL2][Pt(CN)4] complexes (L=ethylenediamine or N,N-dimethylethylenediamine). J. Solid State Chem. 2006;179:1965-76.
• 12.Nemec I, Herchel R, Boča R, Svoboda I, Trávníček Z, Dlháň L, Matelková K, Uess H. Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates. Inorg. Chim. Acta. 2011;366(1):366-72.
• 13.Ouyang L. The use of Tetracyanozincate (II) in the preparation of supramolecular coordination polymers: Department of Chemistry-Simon Fraser University; 2007.
• 14.Sayın E, Kürkçüoğlu G S, Yeşilel O Z, Hökelek T. 1D cyanide complexes with 2-pyridinemethanol: Synthesis, crystal structures and spectroscopic properties. J. Mol. Struct. 2015;1101:73-81.
• 15.Karaağaç D, Kürkçüoğlu G S, Yeşilel O Z, Hökelek T, Dal H. Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex. Z. Kristallogr. 2012;227(9):639-45.
• 16.Karaağaç D, Kürkçüoğlu G S. Syntheses, spectroscopic and thermal analyses of the hofmann-type metal(II) tetra-cyanonickelate(II) pyridazine complexes:{[M(pdz)Ni(CN) 4]∙ H2O}n (M=Zn(II) or Cd(II)). Bull. Chem. Soc. Ethiop. 2015;29(3):415-22.
• 17.Kartal Z. Synthesis, spectroscopic, thermal and structural properties of [M(3-aminopyridine)2Ni(μ-CN)2(CN)2]n (M(II)=Co and Cu) heteropolynuclear cyano-bridged complexes. Spectrochim. Acta, Part A. 2016;152:577-83.
• 18.Parlak C, Alver Ö, Şenyel M. Vibrational spectroscopic study on some Hofmann type clathrates: M(1-Phenylpiperazine)2Ni(CN)4·2G (M=Ni, Co and Cd; G=aniline). J. Mol. Struct. 2009;919(1-3):41-6.
• 19.Černák J, Abboud K A. Three different bonding modes of cyano groups in the coordination polymer [Cu(en)2(H2O)][Cu(en)2Ni2Cu2(CN)10]·2H2O (en is 1,2-diaminoethane). Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2002;58(3):m167-m170.
• 20.Karaağaç D, Kürkçüoğlu G S, Hökelek T, Yeşilel O Z, Süzen Y. Two dimensional cyano-bridged heteropolynuclear complex containing Pd···π interactions. Z. Kristallogr. 2013;228(2):100-5.
• 21.Karaağaç D, Kürkçüoğlu G S, Yeşilel O Z, Hökelek T. Two dimensional cyano-bridged hetero-metallic coordination polymers containing metal⋅⋅⋅ π interactions. Spectrochim. Acta, Part A. 2014;121:196-204.
• 22.Karaağaç D, Kürkçüoğlu G S, Yeşilel O Z. Two dimensional heteronuclear complexes with cyanide and 4-aminomethylpyridine ligands. J. Mol. Struct. 2014;1074:339-48.
• 23.Karaağaç D, Kürkçüoğlu G S, Yeşilel O Z, Taş M. Syntheses, thermal analyses, crystal structures, FT-IR and Raman spectra of 2D [Zn(NH3)2(μ–ampy)M′(μ–CN)2(CN)2]n (M′=Ni(II), Pd(II) or Pt(II)) complexes. Polyhedron. 2013;62:286-92.
• 24.Karaağaç D, Kürkçüoğlu G S, Yeşilel O Z, Hökelek T, Süzen Y. Syntheses, crystal structures, spectroscopic and thermal analyses of 3- and 4-aminomethylpyridinium tetracyanometallate (II) complexes. Inorg. Chim. Acta. 2013;406:73-80.
• 25.Karaağaç D, Kürkçüoğlu GS. Syntheses, spectroscopic and thermal analyses of cyanide bridged heteronuclear polymeric complexes:[M(L)2Ni(CN)4]n (L=N-methylethylenediamine or N-ethylethylenediamine; M=Ni(II), Cu(II), Zn(II) or Cd(II)). J. Mol. Struct. 2016;1105:263-72.
• 26.Niven M L, Percy G C. The infrared spectra (3500-140 cm−1) of the 2, 2'-bipyridine, 2-aminomethylpyridine and ethylenediamine adducts and the sodium tris-compounds of cobalt(II), nickel(II) and zinc(II) acetylacetonates. Transit. Metal Chem. 1978;3(1):267-71.
• 27. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, applications in coordination, Wiley and Sons, New York, 2009.
• 28.Cabral O V, Giannerini T, Felcman J. Fourier-transform infrared spectrum of aspartate hydroxo-aqua nickel(II) complex and DFT-B3LYP/3-21G and 6-311G structural and vibrational calculations. J. Spectrochim. Acta, Part A. 2005;61(1-2):337-45.
• 29.Kürkçüoğlu G S, Hökelek T, Aksel M, Yeşilel O Z, Dal H. Cyano-bridged heteropolynuclear Ni(II), Cu(II) and Cd(II) complexes,[M(deten)2Ni(μ-CN)2(CN)2]n. J. Inorg. Organomet. Polym Mater. 2011;21(3):602.
• 30.Akyüz S. An infrared spectroscopic study of dianiline-metal(II) tetracyanometalate complexes. J. Mol. Struct. 1980;68:41-9.
• 31.Akalin E, Akyüz S. Experimental and theoretical vibrational spectroscopic investigation of Zn(II) halide complexes of 3-aminopyridine and 3-chloropyridine. J. Mol. Struct. 2011;993(1-3):390-6.
• 32.McCullough R, Jones L, Crosby G. An analysis of the vibrational spectrum of the tetracyanonickelate(II) ion in a crystal lattice. Spectrochim. Acta 1960;16(8):929-44.
• 33.Smékal Z, Cı́sařová I, Mroziński J. Cyano-bridged bimetallic complexes of copper(II) with tetracyanonickelate(II). Crystal structure of [Cu(dpt)Ni(CN)4]. Polyhedron 2001;20(28):3301-6.
• 34.Černák J, Abboud K, Chomič J, Meisel M W, Orendáč M, Orendáčová A, Feher A. Ni(tn)2Ag2(CN)4 and Cu(tn)2Ag2(CN)4 (tn=1,3-diaminopropane): preparation, crystal structure, magnetic and spectral properties. Inorg. Chim. Acta 2000;311(1):126-32.
• 35.Potočňák I, Vavra M, Čižmár E, Dušek M, Müller T, Steinborn D. Low-dimensional compounds containing cyano groups. XIX. Crystal structure, spectroscopic, thermal and magnetic properties of {[Cu(tn)2]3[Pt(CN)4]2}[Pt(CN)4](tn=1,3-diaminopropane) complex. Inorg. Chim. Acta 2009;362(11):4152-7.