Synthesis and characterization of Cu/KIT-6 silicas for use in CO2 adsorption

Yıl 2022, Cilt: 5 Sayı: 1, 21 - 28, 31.05.2022

Gamze Gündüz Meriç

Öz

KIT-6 is a mesoporous material with cubic la3d symmetry, adjustable porous 3-dimensional (3D) silica structure, advanced wall thickness and excellent thermal stability. KIT-6, with its cubic la3d symmetrical structure, has adjustable pore size and excellent thermal/hydrothermal stability. In this study, characterization studies of Cu/KIT-6 material by preparing different Si/Cu: blank, 1, 3, 5 ratios were performed by SEM, SEM-Mapping, TEM, XRD, N2 adsorption-desorption, FTIR analysis. Cu based la3d mesoporous silica KIT-6 was synthesized by hydrothermal method and different silicon to copper (Cu) ratios nSi/Cu: 1, 3, 5 and blank KIT-6 were investigated for CO2 adsorption capacity at ambient conditions. The highest CO2 adsorption of 1.70 mmol CO2/g at 0°C and 1.2 bar was achieved for nSi/Cu:1 ratio Cu/KIT-6. These materials are thought to be useful for the emission of CO2 that causes global warming.

Anahtar Kelimeler

KIT-6, silicas, mesoporous, Cu (copper), CO2 capture, global warming

Teşekkür

Bilecik Seyh Edebali University, Yıldız Technical University and Eskisehir Osmangazi University Central Research Laboratories are gratefully acknowledged.

Kaynakça

• 1. Zhou K, Chaemchuen S, Verpoort F. Alternative materials in technologies for Biogas upgrading via CO2 capture. Renewable and Sustainable Energy Reviews. 2017 Nov;79:1414–41. .
• 2. Lakhi KS, Cha WS, Joseph S, Wood BJ, Aldeyab SS, Lawrence G, et al. Cage type mesoporous carbon nitride with large mesopores for CO2 capture. Catalysis Today. 2015 Apr;243:209–17. .
• 3. Mutyala S, Jonnalagadda M, Mitta H, Gundeboyina R. CO2 capture and adsorption kinetic study of amine-modified MIL-101 (Cr). Chemical Engineering Research and Design. 2019 Mar;143:241–8. .
• 4. Han Y, Hwang G, Kim H, Haznedaroglu BZ, Lee B. Amine-impregnated millimeter-sized spherical silica foams with hierarchical mesoporous–macroporous structure for CO2 capture. Chemical Engineering Journal. 2015 Jan;259:653–62. .
• 5. Yıldız MG, Davran-Candan T, Günay ME, Yıldırım R. CO2 capture over amine-functionalized MCM-41 and SBA-15: Exploratory analysis and decision tree classification of past data. Journal of CO2 Utilization. 2019 May;31:27–42. .
• 6. Gaikwad S, Kim SJ, Han S. CO2 capture using amine-functionalized bimetallic MIL-101 MOFs and their stability on exposure to humid air and acid gases. Microporous and Mesoporous Materials. 2019 Mar;277:253–60. .
• 7. Zhang G, Zhao P, Xu Y. Development of amine-functionalized hierarchically porous silica for CO2 capture. Journal of Industrial and Engineering Chemistry. 2017 Oct;54:59–68. .
• 8. Liu Y, Shi J, Chen J, Ye Q, Pan H, Shao Z, et al. Dynamic performance of CO2 adsorption with tetraethylenepentamine-loaded KIT-6. Microporous and Mesoporous Materials. 2010 Oct;134(1–3):16–21. .
• 9. Peirce S, Russo ME, Perfetto R, Capasso C, Rossi M, Fernandez-Lafuente R, et al. Kinetic characterization of carbonic anhydrase immobilized on magnetic nanoparticles as biocatalyst for CO2 capture. Biochemical Engineering Journal. 2018 Oct;138:1–11. .
• 10. Hussain M, Akhter P, Saracco G, Russo N. Nanostructured TiO2/KIT-6 catalysts for improved photocatalytic reduction of CO2 to tunable energy products. Applied Catalysis B: Environmental. 2015 Jul;170–171:53–65. .
• 11. Hu L, Liu J, Zhu L, Hou X, Huang L, Lin H, et al. Highly permeable mixed matrix materials comprising ZIF-8 nanoparticles in rubbery amorphous poly(ethylene oxide) for CO2 capture. Separation and Purification Technology. 2018 Oct;205:58–65. .
• 12. Wang X, Zhou J, Xing W, Liu B, Zhang J, Lin H, et al. Resorcinol–formaldehyde resin-based porous carbon spheres with high CO2 capture capacities. Journal of Energy Chemistry. 2017 Sep;26(5):1007–13. .
• 13. Sari Yilmaz M. Synthesis of novel amine modified hollow mesoporous silica@Mg-Al layered double hydroxide composite and its application in CO2 adsorption. Microporous and Mesoporous Materials. 2017 Jun;245:109–17. .
• 14. Sun H, Parlett CMA, Isaacs MA, Liu X, Adwek G, Wang J, et al. Development of Ca/KIT-6 adsorbents for high temperature CO2 capture. Fuel. 2019 Jan;235:1070–6. .
• 15. Kishor R, Ghoshal AK. APTES grafted ordered mesoporous silica KIT-6 for CO2 adsorption. Chemical Engineering Journal. 2015 Feb;262:882–90. .
• 16. Huang X, Ding J, Zhong Q. Catalytic decomposition of H2O2 over Fe-based catalysts for simultaneous removal of NOX and SO2. Applied Surface Science. 2015 Jan;326:66–72. .
• 17. Gargiulo N, Pepe F, Caputo D. CO<SUB>2</SUB> Adsorption by Functionalized Nanoporous Materials: A Review. j nanosci nanotech. 2014 Feb 1;14(2):1811–22. .
• 18. Yan B, Yu S, Zeng C, Yu L, Wang C, Zhang L. Binderless zeolite NaX microspheres with enhanced CO2 adsorption selectivity. Microporous and Mesoporous Materials. 2019 Apr;278:267–74. .
• 19. Huang J, Zou J, Ho WSW. Carbon Dioxide Capture Using a CO 2 -Selective Facilitated Transport Membrane. Ind Eng Chem Res. 2008 Feb 1;47(4):1261–7. .
• 20. Heyl D, Rodemerck U, Bentrup U. Mechanistic Study of Low-Temperature CO2 Hydrogenation over Modified Rh/Al2O3 Catalysts. ACS Catal. 2016 Sep 2;6(9):6275–84. .
• 21. Liu J, An T, Li G, Bao N, Sheng G, Fu J. Preparation and characterization of highly active mesoporous TiO2 photocatalysts by hydrothermal synthesis under weak acid conditions. Microporous and Mesoporous Materials. 2009 Aug;124(1–3):197–203. .
• 22. Hiyoshi N, Yogo K, Yashima T. Adsorption characteristics of carbon dioxide on organically functionalized SBA-15. Microporous and Mesoporous Materials. 2005 Sep;84(1–3):357–65. .
• 23. Zhou Y, Lu J, Zhou Y, Liu Y. Recent advances for dyes removal using novel adsorbents: A review. Environmental Pollution. 2019 Sep;252:352–65. .
• 24. Lv Y, Xin Z, Meng X, Tao M, Bian Z, Gu J, et al. Essential role of organic additives in preparation of efficient Ni/KIT-6 catalysts for CO methanation. Applied Catalysis A: General. 2018 May;558:99–108. .
• 25. Wei Y, Cai W, Deng S, Li Z, Yu H, Zhang S, et al. Efficient syngas production via dry reforming of renewable ethanol over Ni/KIT-6 nanocatalysts. Renewable Energy. 2020 Jan;145:1507–16. .
• 26. Ouyang H, Guo L, Li C, Chen X, Jiang B. Fabrication and adsorption performance for CO2 capture of advanced nanoporous microspheres enriched with amino acids. Journal of Colloid and Interface Science. 2018 Dec;532:433–40. .
• 27. Loganathan S, Ghoshal AK. Amine tethered pore-expanded MCM-41: A promising adsorbent for CO 2 capture. Chemical Engineering Journal. 2017 Jan;308:827–39. .
• 28. Cecilia JA, Vilarrasa-García E, García-Sancho C, Saboya RMA, Azevedo DCS, Cavalcante CL, et al. Functionalization of hollow silica microspheres by impregnation or grafted of amine groups for the CO 2 capture. International Journal of Greenhouse Gas Control. 2016 Sep;52:344–56. .
• 29. Wang W, Qi R, Shan W, Wang X, Jia Q, Zhao J, et al. Synthesis of KIT-6 type mesoporous silicas with tunable pore sizes, wall thickness and particle sizes via the partitioned cooperative self-assembly process. Microporous and Mesoporous Materials. 2014 Aug;194:167–73. .
• 30. Mello MR, Phanon D, Silveira GQ, Llewellyn PL, Ronconi CM. Amine-modified MCM-41 mesoporous silica for carbon dioxide capture. Microporous and Mesoporous Materials. 2011 Aug;143(1):174–9. .
• 31. Wang L, Ma L, Wang A, Liu Q, Zhang T. CO2 Adsorption on SBA-15 Modified by Aminosilane. Chinese Journal of Catalysis. 2007 Sep;28(9):805–10. .
• 32. Hu Y, Liu W, Sun J, Yang X, Zhou Z, Zhang Y, et al. High Temperature CO 2 Capture on Novel Yb2O3 -Supported CaO-Based Sorbents. Energy Fuels. 2016 Aug 18;30(8):6606–13. .
• 33. Chi C, Li Y, Ma X, Duan L. CO2 capture performance of CaO modified with by-product of biodiesel at calcium looping conditions. Chemical Engineering Journal. 2017 Oct;326:378–88. .