MODELLING OF THE SOLAR CELL BASED ON Cu2SnS3 THIN FILM PRODUCED BY SPRAY PYROLYSIS

Yıl 2022, Cilt: 8 Sayı: 1, 64 - 76, 17.06.2022

Serap Yiğit Gezgin , İlhan Candan , Şilan Baturay , Hamdi Şükür Kılıç

https://doi.org/10.51477/mejs.1105297

Cited By: 2

Öz

Cu2SnS3 (CTS) thin film has been produced for 30 ccm sulphur flux rate at 30 minutes annealing durations at 550 oC temperature. CTS thin film’s crystalline structure has been investigated and crystalline size, lattice parameters, dislocation density and microstrain, crystalline number have also been determined. The CTS thin film’s morphological and optical properties have been examined and thoroughly interpreted. Mo/CTS/CdS/AZO solar cell has been modelled based on CTS thin film produced at the present work, using SCAPS-1D simulation programme. Voc, Jsc, FF, conversion efficiency and photovoltaic parameters have been determined depending on neutral defect density at the interface, coefficient of radiative recombination, Auger electron/hole capture’s coefficient and operation temperature of CTS solar cell. As a consequence of simulation study, ideal efficiency of CTS solar cell has been determined to be 3.72 % and all the data obtained in this study have been presented, interpreted and concluded to be original results.

Anahtar Kelimeler

CTS, solar cell, SCAPS-1D, simulation

Kaynakça

• [1] S. Rahaman, M. K. Singha, M. A. Sunil, and K. Ghosh, "Effect of copper concentration on CTS thin films for solar cell absorber layer and photocatalysis applications," Superlattices and Microstructures, 145, 106589, 2020.
• [2] V. R. M. Reddy et al., "Review on Cu2SnS3, Cu3SnS4, and Cu4SnS4 thin films and their photovoltaic performance," Journal of Industrial and Engineering Chemistry, 76, 39-74, 2019.
• [3] M. Umehara, Y. Takeda, T. Motohiro, T. Sakai, H. Awano, and R. Maekawa, "Cu2Sn1-xGexS3 (x= 0.17) thin-film solar cells with high conversion efficiency of 6.0%," Applied Physics Express, 6(4), 045501, 2013.
• [4] A. Kanai and M. Sugiyama, "Na induction effects for J–V properties of Cu2SnS3 (CTS) solar cells and fabrication of a CTS solar cell over-5.2% efficiency," Solar Energy Materials and Solar Cells, 231, 111315, 2021.
• [5] J. Zhou, L. You, S. Li, and Y. Yang, "Preparation and characterization of Cu2ZnSnS4 microparticles via a facile solution route," Materials Letters, 81, 248-250, 2012.
• [6] Z. Seboui, A. Gassoumi, and N. Kamoun-Turki, "Evolution of sprayed Cu2ZnSnS4," Materials science in semiconductor processing, 26, 360-366, 2014.
• [7] K. Tanaka, Y. Fukui, N. Moritake, and H. Uchiki, "Chemical composition dependence of morphological and optical properties of Cu2ZnSnS4 thin films deposited by sol–gel sulfurization and Cu2ZnSnS4 thin film solar cell efficiency," Solar Energy Materials and Solar Cells, 95(3), 838-842, 2011.
• [8] K. Woo, Y. Kim, and J. Moon, "A non-toxic, solution-processed, earth abundant absorbing layer for thin-film solar cells," Energy & Environmental Science, 5(1), 5340-5345, 2012.
• [9] Y. Wang and H. Gong, "Cu2ZnSnS4 synthesized through a green and economic process," Journal of alloys and compounds, 509(40), 9627-9630, 2011.
• [10] S. Rabaoui, H. Dahman, N. Ben Mansour, and L. El Mir, "Structural, optical and electrical properties of Cu2SnS3 nanoparticles synthesized by simple solvothermal technique," Journal of Materials Science: Materials in Electronics, 26(2), 1119-1124, 2015.
• [11] A. C. Piñón Reyes et al., "Study of a lead-free perovskite solar cell using CZTS as HTL to achieve a 20% PCE by SCAPS-1D simulation," Micromachines, 12(12), 1508, 2021.
• [12] T. AlZoubi, A. Moghrabi, M. Moustafa, and S. Yasin, "Efficiency boost of CZTS solar cells based on double-absorber architecture: Device modeling and analysis," Solar Energy, 225, 44-52, 2021.
• [13] A. Houimi, S. Y. Gezgin, B. Mercimek, and H. Ş. Kılıç, "Numerical analysis of CZTS/n-Si solar cells using SCAPS-1D. A comparative study between experimental and calculated outputs," Optical Materials, 121, 111544, 2021.
• [14] M. Sreejith, D. Deepu, C. S. Kartha, K. Rajeevkumar, and K. Vijayakumar, "Tuning the properties of sprayed CuZnS films for fabrication of solar cell," Applied physics letters, 105(20), 202107, 2014.
• [15] Y. Khaaissa et al., "Experimental and numerical simulation of deposition time effect on ZnS thin films for CZTS-based solar cells," Optical and Quantum Electronics, 53(9), 1-21, 2021.
• [16] M. Burgelman, K. Decock, A. Niemegeers, J. Verschraegen, and S. Degrave, "SCAPS manual," ed: February, 2016.
• [17] P. K. Kalita, B. Sarma, and H. Das, "Structural characterization of vacuum evaporated ZnSe thin films," Bulletin of Materials Science, 23(4), 313-317, 2000.
• [18] S. Prabahar and M. Dhanam, "CdS thin films from two different chemical baths—structural and optical analysis," Journal of Crystal growth, 285(1-2), 41-48, 2005.
• [19] T. Raadik et al., "Temperature dependent photoreflectance study of Cu2SnS3 thin films produced by pulsed laser deposition," Applied Physics Letters, 110(26), 261105, 2017.
• [20] P. Zhao and S. Cheng, "Influence of sulfurization temperature on photoelectric properties Cu2SnS3 thin films deposited by magnetron sputtering," Advances in Materials Science and Engineering, 2013, 2013.
• [21] E. Hossain et al., "Effects of sulfurization temperature on structural, morphological, and optoelectronic properties of CTS thin films solar cells," Chalcogenide Letters, 15(10), 499-507, 2018.
• [22] D. Tiwari, T. K. Chaudhuri, T. Shripathi, U. Deshpande, and R. Rawat, "Non-toxic, earth-abundant 2% efficient Cu2SnS3 solar cell based on tetragonal films direct-coated from single metal-organic precursor solution," Solar Energy Materials and Solar Cells, 113, 165-170, 2013.
• [23] A. D. Adewoyin, M. A. Olopade, O. O. Oyebola, and M. A. Chendo, "Development of CZTGS/CZTS tandem thin film solar cell using SCAPS-1D," Optik, 176, 132-142, 2019.
• [24] B. Barman and P. Kalita, "Influence of back surface field layer on enhancing the efficiency of CIGS solar cell," Solar Energy, 216, 329-337, 2021.
• [25] M. A. Shafi et al., "Optimization of Electrodeposition Time on the Properties of Cu2ZnSnS4 Thin Films for Thin Film Solar Cell Applications," 2021.
• [26] N. Khemiri, S. Chamekh, and M. Kanzari, "Properties of thermally evaporated CZTS thin films and numerical simulation of earth abundant and non toxic CZTS/Zn (S, O) based solar cells," Solar Energy, 207, 496-502, 2020.
• [27] L. Et-taya, T. Ouslimane, and A. Benami, "Numerical analysis of earth-abundant Cu2ZnSn (SxSe1-x) 4 solar cells based on Spectroscopic Ellipsometry results by using SCAPS-1D," Solar Energy, 201, 827-835, 2020.
• [28] A. Srivastava, P. Dua, T. Lenka, and S. Tripathy, "Numerical simulations on CZTS/CZTSe based solar cell with ZnSe as an alternative buffer layer using SCAPS-1D," Materials Today: Proceedings, 43, 3735-3739, 2021.
• [29] S. Meher, L. Balakrishnan, and Z. Alex, "Analysis of Cu2ZnSnS4/CdS based photovoltaic cell: a numerical simulation approach," Superlattices and Microstructures, 100, 703-722, 2016.
• [30] A. Mohandes, M. Moradi, and H. Nadgaran, "Numerical simulation of inorganic Cs2AgBiBr6 as a lead-free perovskite using device simulation SCAPS-1D," Optical and Quantum Electronics, 53(6), 1-22, 2021.
• [31] V. Raj, F. Rougieux, L. Fu, H. H. Tan, and C. Jagadish, "Design of Ultrathin InP Solar Cell Using Carrier Selective Contacts," IEEE Journal of Photovoltaics, 10(6), 1657-1666, 2020.
• [32] H. Fu and Y. Zhao, "Efficiency droop in GaInN/GaN LEDs," in Nitride Semiconductor Light-Emitting Diodes (LEDs): Elsevier, 299-325, 2018.
• [33] F. Staub, U. Rau, and T. Kirchartz, "Statistics of the Auger recombination of electrons and holes via defect levels in the band gap—application to lead-halide perovskites," ACS omega, 3(7), 8009-8016, 2018.
• [34] P. Roy, S. Tiwari, and A. Khare, "An investigation on the influence of temperature variation on the performance of tin (Sn) based perovskite solar cells using various transport layers and absorber layers," Results in Optics, 4, 100083, 2021.
• [35] M. Abderrezek, M. Fathi, and F. Djahli, "Comparative study of temperature effect on thin film solar cells," 2018.
• [36] H. Zhang, S. Cheng, J. Yu, H. Zhou, and H. Jia, "Prospects of Zn (O, S) as an alternative buffer layer for Cu2ZnSnS4 thin-film solar cells from numerical simulation," Micro & Nano Letters, 11(7), 386-390, 2016.