The Synthesis of Novel Heterocyclic Schiff Bases Microwave Assisted and Investigation of Saldeta/Salpyr Metal Complexes

Yıl 2024, , 592 - 598, 31.12.2024

Ziya Erdem Koç

https://doi.org/10.47112/neufmbd.2024.68

Öz

2-(4-aminophenyl)-1H-benzimidazole obtained from literature studies was used as the outlet agent. The resulting compound reacted with Gentisaldehyde to get 2-(((4-(1H-benzoimidazoleyl)phenyl)imino)methyl)benzene-1,4-diol (25SAPBZ). Oxygen-bridging complexes were obtained by adding the [Fe(saldeta/salpyr)Cl] complex dissolved in ethanol to the (25SAPBZ) ligand. FTIR, elemental analyses, 1H/13C-NMR and FTIR of complex structures, elemental analyses, and magnetic susceptibility measurements of the obtained ligands were elucidated.

Anahtar Kelimeler

Heterocyclic, Benzimidazole, Schiff base, Metal Complexes

Mikrodalga Destekli Yeni Heterosiklik Schiff Bazlarının Sentezi ve Saldeta/Salpyr Metal Komplekslerinin İncelenmesi

Öz

Literatür çalışmalarından elde edilen 2-(4-aminofenil)-1H-benzimidazol çıkış maddesi olarak kullanıldı. Elde edilen bileşik Gentisaldehyde reaksiyona girerek, 2-(((4-(1H-benzimidazolyl)phenyl)imino)methyl)benzene-1,4-diol (25SAPBZ) elde edildi. (25SAPBZ) ligandına etanolde çözülmüş [Fe(saldeta/salpyr)Cl] kompleksi ilave edilerek oksijen köprülü kompleksler elde edildi. Elde edilen ligandların FTIR, elementel analizleri, 1H/13C-NMR ve kompleks yapıların FTIR, elementel analizleri, manyetik süssebtibilite ölçümleri ile yapılar aydınlatıldı.

Anahtar Kelimeler

Heterosiklik, Benzimidazol, Schiff baz, Metal Kompleks

Kaynakça

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