Application of Fourier Transform Infrared (FTIR) Spectroscopy to Analysis of Clays

Yıl 2019, - Cilt:8 - IMSMATEC Özel Sayı, 37 - 46, 15.12.2019

Ceyda Bilgiç , Şafak Bilgiç

https://doi.org/10.17100/nevbiltek.632788

Cited By: 6

Öz

The present paper should be
considered as a study of the application of Fourier Transform Infrared (FTIR)
Spectroscopy for surface clay characterization. The application of surface clay
materials for water treatment, oil adsorption, excipients or as active using in
drugs has largely increased these recent years. The surface clay material
presents hydroxyl groups, which can link very easily water molecules. These
hydroxyl groups can react with organic groups and by their vibration in the
infra-red region, FTIR can be easily used as a technical method for surface
clay characterization. In this paper, the basic clay mineral specimens
(bentonite, sepiolite, kaolinite and perlite) were examined and shows the
chemical compositions of the clay where alumina oxide and silica oxide are
present in major quantity.

Anahtar Kelimeler

Clay Minerals, FTIR Spectroscopy, Characterization

Destekleyen Kurum

Eskişehir Osmangazi Üniversitesi

Proje Numarası

2018-2233

Fourier Dönüşümlü Kızılötesi (FTIR) Spektroskopisinin Killerin Analizlerinde Kullanılması

Öz

Bu
makale, killerin yüzey karakterizasyonu için Fourier Dönüşümlü Kızılötesi (FTIR)
Spektroskopisi uygulamasının bir çalışmasıdır. Killerin su arıtma, yağ
adsorpsiyonu gibi yüzey işlemlerinde ya da yardımcı maddelerde ve ilaçlarda
aktif olarak kullanımı son yıllarda büyük ölçüde artmıştır. Killerin yüzeyinde
bulunan hidroksil grupları, su molekülleri ile kolayca bağlayabilmektedir. Bu
hidroksil gruplar organik gruplarla reaksiyona girerler ve onların kızıl ötesi
bölgedeki titreşimleriyle tespit edilebilirler. Bu nedenle FTIR, killerin yüzey
karakterizasyonunda kolayca kullanılabilen teknik bir yöntemdir. Bu makalede, temel
kil minerali numuneleri (bentonit, sepiyolit, kaolin ve perlit) incelendi ve
kimyasal bileşimlerinin büyük miktarda alüminyum oksit ve silisyum oksit
içerdiği gözlendi.

Anahtar Kelimeler

Kil Mineralleri, FTIR Spektroskopisi

Proje Numarası

2018-2233

Kaynakça

• [1] Ajbary M., Santos A., Morales-Florez V., Esquivias R., “Removal of basic yellow cationic dye by an aqueous dispersion of Moroccan stevensite” Applied Clay Science, 80-81, 46-51, 2013.
• [2] Li M., Yao J., Lin B., Yang X., Zhang L., Lei L., “Pentachlorophenol sorption in the cetyltrimethylammonium bromide/bentonite one-step process in single and multiple solute systems” Journal of Chemical Engineering Data, 58, 2610-2615, 2013.
• [3] Savic I., Gajic D., Stojiljkovic S., Savic I., di Gennaro S., “Modelling and optimization of methylene blue adsorption from aqueous solution using bentonite clay” Computer Aided Chemical Engineering, 33, 1417-1422, 2014.
• [4] Shichi T., Takaqi K., “Clay minerals as photochemical reaction fields” Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 1, 113-130, 2000.
• [5] Eren E., “Adsorption performance and mechanism in binding of azo dye by raw bentonite” Clean Soil Air Water, 38, 758-763, 2010.
• [6] Liang X., Xu Y., Tan X., Wang L., Sun Y., Lin D., Sun Y., Qin X., Wang Q., “Heavy metal adsorbents mercapto and amino functionalized palygorskite: preparation and characterization” Colloids and Surface A: Physicochemical and Engineering Aspects, 426, 98-105, 2013.
• [7] Ross C.S., “The mineralogy of clays” Transactions of the 1st International Congress of Soil Science, 4, 555–561, Washington D.C., 1999.
• [8] Hendricks S.B., Fry W.H., “The results of X-ray and microscopical examinations of soil colloids” Soil Science, 29, 457–478, 1930.
• [9] Pauling L., “Structure of the chlorites” Proceedings of the National Academy of Sciences of United States of America, 16(9), 578–582, 1930.
• [10] Elmoubarki R., Mahjoubi F.Z., Tounsadi H., Moustadraf J., Abdennouri M., Zouhri A., ElAlban A., Barka N., “Adsorption of textile dyes on raw and decanted Moroccan clays: kinetics, equilibrium and thermodynamics” Water Resource Industry, 9, 16-29, 2015.
• [11] Yan L., Qin L., Yu H., Li S., Shan R., Du B., “Adsorption of acid dyes from aqueous solution by CTMAB modified bentonite: kinetic and isotherm modelling” Journal of Molecular Liquit, 21, 1074-1081, 2015.
• [12] Huang R., Wang B., Yang B., Zheng D., Zhang Z., “Equilibrium, kinetic and thermodynamic studies of adsorption of Cd (II) from aqueous solution onto HACC-bentonite” Desalination, 280, 297-304, 2011.
• [13] Masindi V., Gitari W.M., Ngulube T., “Defluoridation of drinking water using Al3+ -modified bentonite clay: optimization of fluoride adsorption conditions” Toxicological Environmental Chemistry, 96 (9), 1294-1309, 2014.
• [14] Adeyemo A.A., Adeoye I.O., Bello O.S., “Adsorption of dyes using different types of clay: a review” Applied Water Science, 20, 1-26, 2015.
• [15] Alkan A., Demirbas Ö., Doğan, M., “Electrokinetic properties of kaolinite in mono and multivalent electrolyte solutions” Microporous Mesoporous Materials, 83, 51-59, 2005.
• [16] Ruiz-Hitzky E., “Molecular access to intracrystalline tunnels of sepiolite” Journal Material Chemistry, 11, 86–91, 2001.
• [17] Santaren J., Sanz J., Ruiz-Hitzky E., “Structural fluorine in sepiolite” Clays and Clay Minerals, 38, 63-68, 1990.
• [18] Casal B., Merino J., Serratosa J.M., Ruiz-Hitzky E., “Sepiolite-based materials for the photo- and thermal-stabilization of pesticides” Applied Clay Science, 18, 245-254, 2001.
• [19] Ming H., “Modification of kaolinite by controlled hydrothermal deuteration-a DRIFT spectroscopic study” Clay Minerals, 39, 349–362, 2004.
• [20] Frost R.L., Mako E., Kristof J., Kloprogge J.T., “Modification of kaolinite surfaces through mechanochemical treatment--a mid-IR and near-IR spectroscopic study” Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 58, 2849-2859, 2002.
• [21] Saad Z., Al-Mashaikie A.K., Al-Hawbanie A.M., “Petrography and geochemical study of the perlite rocks from Bait Al-Qeyarie, Kawlan Area, Yemen” JAKU: Earth Science, 21, 195–217, 2010.
• [22] Keller W.D. Picket E.E., “The absorption of infrared radiation in clay minerals” Am. Journal Science, 248, 264-273, 1950.
• [23] Sambridge M., FitzGerald J., Kovács I., O’Neill H.St.C., Hermann J., “Quantitative IR spectroscopy with unpolarized light Part I: Physical and mathematical development” American Mineralogist, 93, 751-764, 2008.
• [24] Anderson R.L., Ratsliffe I., Greenwell H.C., Williams P.A., Cliffe S., Coveney P.V., “Clay swelling, A challenge in the oil field” Earth-Science Reviews, 98, 201-216, 2010.
• [25] Tabak A., Afsin B., Çağlar B., Koksal E., “Characterization and pillaring of a Turkish bentonite (Resadiye)” Journal of Colloid and Interface Science, 313, 5–11, 2007.
• [26] Doğan M., Alkan M., “Some Physicochemical Properties of Perlite as an Adsorbent” Fresenius Environmental Bulletin, 13, 252–257, 2004.
• [27] Innocenzi P., “Infrared spectroscopy of sol–gel derived silica-based films: a spectra-microstructure overview” Journal of Non-Crystalline Solids, 316, 309–319, 2003.
• [28] Sabah E., Çelik M.S., “Interaction of pyridine derivatives with sepiolite” Journal of Colloid and Interface Science, 251, 33–38, 2002.
• [29] Önal M., “Examination of some commercial sorptive organo bentonites” Turkish Journal of Chemistry, 31, 579-588, 2007.
• [30] Tunç S., Duman O., Kancı B., “Rheological Measurements of Na-Bentonite and Sepiolite Particles in the Presence of Tetradecyltrimethylammonium Bromide, Sodium Tetradecyl Sulfonate and Brij 30 Surfactants” Colloids and Surfaces A: Physicochemical and Engineering Aspects, 398, 37–47, 2012.
• [31] Roulia M., Chassapis K., Kapoutsis J.A., Kamitsos E.I., Savvidis T., “Influence of Thermal Treatment on the Water Release and the Glassy Structure of Perlite” Journal Materials Science, 41, 5870-5881, 2006.