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Hdtma-Bentonitinin Sentez Ve Karakterizasyonu

Yıl 2006, Cilt: 19 Sayı: 2, 21 - 34, 31.12.2006

Nuray Yıldız , Fatmanur Köroğlu Ayla Çalımlı

Öz

Bu çalışmada, Ordu bentonitinden hekzadesiltrimetilamonyum bromür (HDTMA-Br), kullanılarak  HDTMA organobentoniti (HDTMA-B) sentezlenmiştir. Orijinal bentonit ve sentezlenen organobentonit,  toplam organik karbon içeriği, X-ışınları difraktogramı, yüzey alanı ve tanecik boyut dağılımı  analizleri ile karakterize edilmiştir. Analiz sonuçlarından orijinal ve organobentonit örneklerinin, toplam organik karbon içeriği, tanecik boyutu, yüzey alanı gibi  özelikleri  arasında farklılıklar olduğu saptanmıştır.

Anahtar Kelimeler

Bentonit organobentonit sentez ve karakterizasyon.

Kaynakça

  • [1] R.S. Juang, S.H. Lin and K.H. Tsao, “Sorption of phenols from water in column systems using surfactant-modified montmorillonite”, Journal of Colloid and Interface Science, 269, 46-52, 2004.
  • [2] S. Al-Asheh, F. Banat, L. Abu-Aitah, L.”Adsorption of phenol using different types of activated bentonites”, Separation and Purification Technology 33, 1-10, 2003.
  • [3] G.,Chen, B.W. Dussert., I.H., Suffet, “Evulation of granular activated carbons for removal of methylisoberneol to below odor threshold concentration in drinking” Water. Wat. Res., 31 (5); 1155-1163, 1997.
  • [4] J.Ellis and W.Korth. “Removal water by adsorption on ultrastable zeolite Y”. Wat. Res., 27 (4); 535-539,1993..
  • 5] J.D. Seader and E.J.Henley, “Separation Process Principles”,2nd Ed. 1998.
  • [6] A. Çelik, N.Yıldız and A Çalımlı. “Sorption characteristic of organic compounds on three hexadecyl-trimethylammonium-semectits having different cation exchange capacities”, Reviews in Chemical Engineering, 15(4); 349-362, 1999.
  • [7] W.F Jaynes and S.A Boyd, “Trimethylphenylammonium-smectite as an effective adsorbent of water soluble aromatic hydrocarbons”, Journal Air Waste Management Assoc, 40; 1649-1653, 1990.
  • [8] W. F. Jaynes, and S.A Boyd, “Clay mineral type and organic compounds sorption by hexadecyltrimethylammonium-exchanged clays”, Soil Sci. and Am. J, 55; 43-48, 1991.
  • [9] W. F. Jaynes, and G. F. Vance, “BTEX sorption by organo-clays: cosorptive. enhancement and equivalence of interlayer complexes”, Soil. Sci. Soc. Am. J., 60; 1742-1749, 1996.
  • [10] W.F. Jaynes, and G. F Vance ,” Sorption of benzene, toluene, ethylbenzene and xylene(BTEX) compounds by hectorite clays exchanged with aromatic organic cations”, Clays and Clay Minerals, 47(3); 358-365, 1999.
  • [11] S. M. Koh, J. B. Dixon,“Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene”, Applied Clay Science 18; 111- 122, 2001.
  • [12] J.F.Lee, M. M.Mortland, C. T.Chiou, D.E. Kile, S. A. Boyd, “Adsorption of benzene, toluene, xylene by two tetramethylammonium-smectites having different charge densities”, Clay and Clays Minerals, 38; 113-120, 1990.
  • [13] J.Lee, Song, Dong. and Y.Jeon, “Adsorption of organic phenols onto dual organic cation montmorillonite from water”, Separation Science and Technolgy, 32(12); 1975-1992, 1997.
  • [14] S. H. Lin, and M. J. Cheng, “Phenol and chlorophenol removal from aqueous solution by organobentonites”. Environmental Techonolgy, 21; 475-482, 1999.
  • [15] S.Gitipour , M.T.Bowers, A. Bodocsi, “The use of modified bentonite for removal of aromatic organics from contaminated soil” Journal of Colloid and Interface Science, 196; 191-198, 1997.
  • [16] S.A. Boyd, M.M Mortland and C.T. Chiou,“Sorption Characteristics of organic compounds on HDTMA-B”, Soil.Sci.Soc.Am.J, 52; 652-657, 1988.
  • [17] M. M. Mortland, S. Shaobai and S. A. Boyd, “Clay organic complexes as adsorbents for phenol and chlorophenols”, Clays and Clay Min., 34; 581- 585, 1986.
  • [18] Y. H. Shen, “Removal of phenol from water by adsorption-flocculation using organobentonite”, Water Research, 36; 1107-1111, 2002.
  • [19] Y. H. Shen, “Removal of dissolved organic matter from water by adsorption-flocculation using organobentonite”, Environmental Technology, 23; 553-560, 2002.
  • [20] Y. H. Shen, “Preparations of organobentonite using nonionic surfactants”, Chemosphere, 44; 989-995, 2001.
  • [21] J. A. Smith, P. R.Jaffe,”Effect of Ten Quaternary ammonium cations on tetrachloromethane sorption to clay from water”, Env. Sci. and Tech., 24; 1167 - 1172,1990.
  • [22] J. A. Smith, P. R. Jaffe, “Comparison of tetrachlormethane sorption to an alkilammonium-clay and alkyldiammonium-clay”, Env.Sci. and Tech., 25; 2054-2058, 1991.
  • [23] J.A. Smith, P. R. Jaffe, “Benzene transport through landfill linercontaining organic bentonites”, Journal of Env.Eng., 120; 1559-1577, 1994.
  • [24] J. A. Smith and A.Galan, “Sorption of nonionic organic contaminants to single and dual organic bentonites from water”, Env.Sci. and Tech., 29; 685-692,1995.
  • [25] L.Zhu, Y.Li and J. Zhang,” Sorption of organobentonites to some organic pollutants in water”, Env. Sci. and Tech., 31; 1407-1410, 1997.
  • [26] L.Zhu, X. Ren and S. Yu, “Use of cethyltrimethylammonium bromide- bentonite to remove organic contaminants of varying polar character from water”, Environmental Science Technolgy, 32; 3374-3378, 1998.
  • 27] N.Yıldız, M. Erol, Z.Aktas, and A.Çalımlı, “Adsorption of aromatic hydrocarbons on BTEA-bentonite”, Adsorption Science and Technology, 22 (2); 145-154, 2004.
  • [28] N. Yıldız, R. Gönülşen, H. Koyuncu, A.Çalımlı, “Adsorption of benzoic acid and hydroquinoneby organically modified bentonites”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 260: 87-94, 2005.
  • [29] Z.Lizhong, L.Yımın, J. Juang, “ Sorption of organobentonites to some organic pollutants in water”Environmental Science and Technology, 31: 1407-1410, 1997.
  • [30] U. Salgın, N.Yıldız, A.Çalımlı, Desorption of Salicylic Acid from Modified Bentonite using Supercritical Fluids in Packed Bed Column, Separation Science and Technology, 39(11): 2677-2694, 2004..

Synthesıze And Characterızatıon Of Hdtma-Bentonıte

Yıl 2006, Cilt: 19 Sayı: 2, 21 - 34, 31.12.2006

Nuray Yıldız , Fatmanur Köroğlu Ayla Çalımlı

Öz

In the present study, organobentonite(HDTMA-B) was synthesized by using hexadecyltrimethylammonium bromide (HDTMA-Br) from bentonite of Ordu city. Synthesized organobentonites were characterized by X-ray diffaraction, total organic carbon (TOC), surface properties and particle size analysis. The difference in  properties such as organic  carbon content, particle size and surface area  between original and organobentonite sample was put forward depending on analysis results.

Anahtar Kelimeler

Bentonites organobentonites synthesize and characterization..

Kaynakça

  • [1] R.S. Juang, S.H. Lin and K.H. Tsao, “Sorption of phenols from water in column systems using surfactant-modified montmorillonite”, Journal of Colloid and Interface Science, 269, 46-52, 2004.
  • [2] S. Al-Asheh, F. Banat, L. Abu-Aitah, L.”Adsorption of phenol using different types of activated bentonites”, Separation and Purification Technology 33, 1-10, 2003.
  • [3] G.,Chen, B.W. Dussert., I.H., Suffet, “Evulation of granular activated carbons for removal of methylisoberneol to below odor threshold concentration in drinking” Water. Wat. Res., 31 (5); 1155-1163, 1997.
  • [4] J.Ellis and W.Korth. “Removal water by adsorption on ultrastable zeolite Y”. Wat. Res., 27 (4); 535-539,1993..
  • 5] J.D. Seader and E.J.Henley, “Separation Process Principles”,2nd Ed. 1998.
  • [6] A. Çelik, N.Yıldız and A Çalımlı. “Sorption characteristic of organic compounds on three hexadecyl-trimethylammonium-semectits having different cation exchange capacities”, Reviews in Chemical Engineering, 15(4); 349-362, 1999.
  • [7] W.F Jaynes and S.A Boyd, “Trimethylphenylammonium-smectite as an effective adsorbent of water soluble aromatic hydrocarbons”, Journal Air Waste Management Assoc, 40; 1649-1653, 1990.
  • [8] W. F. Jaynes, and S.A Boyd, “Clay mineral type and organic compounds sorption by hexadecyltrimethylammonium-exchanged clays”, Soil Sci. and Am. J, 55; 43-48, 1991.
  • [9] W. F. Jaynes, and G. F. Vance, “BTEX sorption by organo-clays: cosorptive. enhancement and equivalence of interlayer complexes”, Soil. Sci. Soc. Am. J., 60; 1742-1749, 1996.
  • [10] W.F. Jaynes, and G. F Vance ,” Sorption of benzene, toluene, ethylbenzene and xylene(BTEX) compounds by hectorite clays exchanged with aromatic organic cations”, Clays and Clay Minerals, 47(3); 358-365, 1999.
  • [11] S. M. Koh, J. B. Dixon,“Preparation and application of organo-minerals as sorbents of phenol, benzene and toluene”, Applied Clay Science 18; 111- 122, 2001.
  • [12] J.F.Lee, M. M.Mortland, C. T.Chiou, D.E. Kile, S. A. Boyd, “Adsorption of benzene, toluene, xylene by two tetramethylammonium-smectites having different charge densities”, Clay and Clays Minerals, 38; 113-120, 1990.
  • [13] J.Lee, Song, Dong. and Y.Jeon, “Adsorption of organic phenols onto dual organic cation montmorillonite from water”, Separation Science and Technolgy, 32(12); 1975-1992, 1997.
  • [14] S. H. Lin, and M. J. Cheng, “Phenol and chlorophenol removal from aqueous solution by organobentonites”. Environmental Techonolgy, 21; 475-482, 1999.
  • [15] S.Gitipour , M.T.Bowers, A. Bodocsi, “The use of modified bentonite for removal of aromatic organics from contaminated soil” Journal of Colloid and Interface Science, 196; 191-198, 1997.
  • [16] S.A. Boyd, M.M Mortland and C.T. Chiou,“Sorption Characteristics of organic compounds on HDTMA-B”, Soil.Sci.Soc.Am.J, 52; 652-657, 1988.
  • [17] M. M. Mortland, S. Shaobai and S. A. Boyd, “Clay organic complexes as adsorbents for phenol and chlorophenols”, Clays and Clay Min., 34; 581- 585, 1986.
  • [18] Y. H. Shen, “Removal of phenol from water by adsorption-flocculation using organobentonite”, Water Research, 36; 1107-1111, 2002.
  • [19] Y. H. Shen, “Removal of dissolved organic matter from water by adsorption-flocculation using organobentonite”, Environmental Technology, 23; 553-560, 2002.
  • [20] Y. H. Shen, “Preparations of organobentonite using nonionic surfactants”, Chemosphere, 44; 989-995, 2001.
  • [21] J. A. Smith, P. R.Jaffe,”Effect of Ten Quaternary ammonium cations on tetrachloromethane sorption to clay from water”, Env. Sci. and Tech., 24; 1167 - 1172,1990.
  • [22] J. A. Smith, P. R. Jaffe, “Comparison of tetrachlormethane sorption to an alkilammonium-clay and alkyldiammonium-clay”, Env.Sci. and Tech., 25; 2054-2058, 1991.
  • [23] J.A. Smith, P. R. Jaffe, “Benzene transport through landfill linercontaining organic bentonites”, Journal of Env.Eng., 120; 1559-1577, 1994.
  • [24] J. A. Smith and A.Galan, “Sorption of nonionic organic contaminants to single and dual organic bentonites from water”, Env.Sci. and Tech., 29; 685-692,1995.
  • [25] L.Zhu, Y.Li and J. Zhang,” Sorption of organobentonites to some organic pollutants in water”, Env. Sci. and Tech., 31; 1407-1410, 1997.
  • [26] L.Zhu, X. Ren and S. Yu, “Use of cethyltrimethylammonium bromide- bentonite to remove organic contaminants of varying polar character from water”, Environmental Science Technolgy, 32; 3374-3378, 1998.
  • 27] N.Yıldız, M. Erol, Z.Aktas, and A.Çalımlı, “Adsorption of aromatic hydrocarbons on BTEA-bentonite”, Adsorption Science and Technology, 22 (2); 145-154, 2004.
  • [28] N. Yıldız, R. Gönülşen, H. Koyuncu, A.Çalımlı, “Adsorption of benzoic acid and hydroquinoneby organically modified bentonites”, Colloids and Surfaces A: Physicochemical and Engineering Aspects 260: 87-94, 2005.
  • [29] Z.Lizhong, L.Yımın, J. Juang, “ Sorption of organobentonites to some organic pollutants in water”Environmental Science and Technology, 31: 1407-1410, 1997.
  • [30] U. Salgın, N.Yıldız, A.Çalımlı, Desorption of Salicylic Acid from Modified Bentonite using Supercritical Fluids in Packed Bed Column, Separation Science and Technology, 39(11): 2677-2694, 2004..
Toplam 30 adet kaynakça vardır.

Ayrıntılar

Konular Kimya Mühendisliği
Bölüm Araştırma Makaleleri
Yazarlar

Nuray Yıldız

Fatmanur Köroğlu Bu kişi benim

Ayla Çalımlı Bu kişi benim

Yayımlanma Tarihi 31 Aralık 2006
Kabul Tarihi 15 Kasım 2005
Yayımlandığı Sayı Yıl 2006 Cilt: 19 Sayı: 2

Kaynak Göster

APA Yıldız, N., Köroğlu, F., & Çalımlı, A. (2006). Hdtma-Bentonitinin Sentez Ve Karakterizasyonu. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, 19(2), 21-34.
AMA Yıldız N, Köroğlu F, Çalımlı A. Hdtma-Bentonitinin Sentez Ve Karakterizasyonu. ESOGÜ Müh Mim Fak Derg. Aralık 2006;19(2):21-34.
Chicago Yıldız, Nuray, Fatmanur Köroğlu, ve Ayla Çalımlı. “Hdtma-Bentonitinin Sentez Ve Karakterizasyonu”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi 19, sy. 2 (Aralık 2006): 21-34.
EndNote Yıldız N, Köroğlu F, Çalımlı A (01 Aralık 2006) Hdtma-Bentonitinin Sentez Ve Karakterizasyonu. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 19 2 21–34.
IEEE N. Yıldız, F. Köroğlu, ve A. Çalımlı, “Hdtma-Bentonitinin Sentez Ve Karakterizasyonu”, ESOGÜ Müh Mim Fak Derg, c. 19, sy. 2, ss. 21–34, 2006.
ISNAD Yıldız, Nuray vd. “Hdtma-Bentonitinin Sentez Ve Karakterizasyonu”. Eskişehir Osmangazi Üniversitesi Mühendislik ve Mimarlık Fakültesi Dergisi 19/2 (Aralık 2006), 21-34.
JAMA Yıldız N, Köroğlu F, Çalımlı A. Hdtma-Bentonitinin Sentez Ve Karakterizasyonu. ESOGÜ Müh Mim Fak Derg. 2006;19:21–34.
MLA Yıldız, Nuray vd. “Hdtma-Bentonitinin Sentez Ve Karakterizasyonu”. Eskişehir Osmangazi Üniversitesi Mühendislik Ve Mimarlık Fakültesi Dergisi, c. 19, sy. 2, 2006, ss. 21-34.
Vancouver Yıldız N, Köroğlu F, Çalımlı A. Hdtma-Bentonitinin Sentez Ve Karakterizasyonu. ESOGÜ Müh Mim Fak Derg. 2006;19(2):21-34.
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