Tekstil atık sularından C.I. Bazik Mavi 3 boyarmaddesinin elektrokimyasal uygulama ile giderilmesi

Yıl 2016, Cilt: 20 Sayı: 3, 521 - 531, 02.09.2016

Emrah Bulut

https://doi.org/10.16984/saufenbilder.85559

Öz

Tekstil boyama endüstrisinde kullanılan Bazik Mavi 3 boyarmaddesinin alüminyum elektrot kullanılarak elektrokimyasal olarak tekstil atık sularından giderimi üzerinde çalışılmıştır. Kesikli proses ile yapılan deneyler sonrasında 10 dakika sonunda pH8 değerinde %97’den fazla giderim etkinliği hesaplanmıştır. Elektrokimyasal işlemin 6. dakikası sonunda 50-400 mg/L aralığındaki konsantrasyonlardaki boya giderim etkinliği %92-95 arasında değişirken bu oran, 500 ve 600 mg/L için sırasıyla %72 ve %60 olarak hesaplanmıştır. 10. dakika sonunda ise bütün konsantrasyon değerlerindeki boya giderim oranı %96 civarındadır. Akım yoğunluğu değerlendirildiğinde ise boya giderim etkinliği 333 A/m² akım yoğunluğu ile 4. dakikadan sonra (%96) işlem bitene kadar çok fazla bir artış göstermemiş ve 10. dakikada %97 seviyesine ulaşmıştır.

Anahtar Kelimeler

elektrokoagülasyon, tekstil atık suları, bazik mavi 3, alüminyum elektrot

Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment

Öz

The present study investigates the electrochemical treatment of Basic Blue 3 dyestuff from the textile waste waters. We achieved more than 97% color removal with pH8 after 10 minutes. In terms of initial dye concentrations, 92-95%, 72 and 60% dye removal efficiencies were obtained in 6 minutes for 50-400 mg/L, 500 and 600 mg/L initial dye concentrations respectively. In 10 minutes removing efficiencies became 96% for all the concentrations. When we consider the current density parameter, 96% removal efficiency was obtained with 333 A/m² current density in 4 minutes respectively. However the removal efficiency only increases to 97% in 10 minutes.

Anahtar Kelimeler

electrocoagulation, textile waste waters, basic blue 3, aluminum electrode

Kaynakça

• T. H. Kim, C. Park, J. Yang ve S. Kim, «Comparison of disperse and reactive dye removals by chemical coagulation and Fenton oxidation,» J. Hazard. Mater., cilt 112, pp. 95-103, 2004.
• I. D. Mall, V. C. Srivastava, N. K. Agarwal ve I. M. Mishra, «Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses,» Colloids Surf., A: Physicochem. Eng. Aspects, cilt 264, pp. 17-28, 2005.
• S. Singh, V. C. Srivastava ve I. D. Mall, «Multistep optimization and residue disposal study for electrochemical treatment of textile wastewater using aluminum electrode,» Int. J. Chem. React. Eng., cilt 11, pp. 1-16, 2013.
• L. Szpyrkowicz, C. Juzzolino ve S. N. Kaul, «A comparative study on oxidation of disperses dyes by electrochemical process, ozone, hypochlorite and Fenton Reagent,» Water Res., cilt 35, pp. 2129-2136, 2001.
• C. Wu, Y. Wang, B. Gao, Y. Zhao ve Q. Yue, «Coagulation performance and floc characteristics of aluminum sulfate using sodium alginate as coagulant aid for synthetic dying wastewater treatment,» Sep.Purif. Technol., cilt 95, pp. 180-187, 2012.
• K. Marungrueng ve P. Pavasant, «Removal of basic dye (Astrazon Blue FGRL) using macroalga Caulerpa lentillifera,» J. Environ. Manage, cilt 78, pp. 268-274, 2006.
• C. Hessel, C. Allegre, M. Maisseu, F. Charbit ve P. Moulin, «Guidelines and legislation for dye house effluents,» J. Environ. Manage, cilt 83, pp. 171-180, 2007.
• I. Tan, B. Hameed ve A. Ahmad, «Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon,» Chem. Eng. J., cilt 127, pp. 111-119, 2007.
• H. Chu ve K. Chen, «Reuse of activated sludge biomass: I. Removal of basic dyes from wastewater biomass,» Process Biochem., cilt 37, pp. 595-600, 2002.
• X. J. Zhou, W. Q. Guo, S. S. Yang ve N. Q. Ren, «A Rapid and Low Energy Consumption Method to Decolorize the High Concentration Triphenylmethane Dye Wastewater: Operational Parameters Optimization for the Ultrasonic-Assisted Ozone Oxidation Process,» Biores. Technol., cilt 105, pp. 40-47, 2012.
• M. L. Marin, L. Santos-Juanes, A. Arques, A. M. Amat ve M. A. Miranda, «Organic Photocatalysts for the Oxidation of Pollutants and Model Compounds,» Chem. Rev., cilt 112, pp. 1710-1750, 2012.
• C. Chen ve C. Lu, «Photocatalytic Degradation of Basic Violet 4: Degradation Efficiency, Product Distribution, and Mechanisms,» J. Phys. Chem. C, cilt 111, pp. 13922-13932, 2007.
• S. Huo ve X. −. Yan, «Metal−Organic Frame Work MIL-100 (Fe) for the Adsorption of Malachite Green from Aqueous Solution,» J. Mater. Chem., cilt 2, pp. 7449-7455, 2012.
• I. Ali, «New Generation Adsorbents for Water Treatment,» Chem. Rev., cilt 112, pp. 5073-5091, 2012.
• S. Deng, Q. Zhou, G. Yu, J. Huang ve Q. Fan, «Removal of Perfluorooctanoate from Surface Water by Polyaluminium Chloride Coagulation,» Water Res., cilt 45, pp. 1774-1780, 2011.
• M. Minhalma ve M. N. De Pinho, «Flocculation/Flotation/Ultrafiltration Integrated Process for the Treatment of Cork Processing Wastewaters,» Environ. Sci. Technol., cilt 35, pp. 4916-4921, 2001.
• M. Huan, L. Lian−Tai, Y. Cai−Fang, S. Jin-Jin, H. Q. Yuan−Gao ve L. Shun−Peng, «Biodegradation of Malachite Green by Strain Pseudomonas sp. K9 and Cloning of the tmr2 Gene Associated with an ISPpu12,» World J. Microbiol. Biotechnol., cilt 27, pp. 1323-1329, 2011.
• C. Chen, J. Kuo, C. Chen, Y. Huang, I. Hob ve Y. Chung, «Biological Decolorization of Dye Solution Containing Malachite Green by Pandoraea Pulmonicola YC32 Using a Batch and Continuous System,» J. Hazard. Mater., cilt 172, pp. 1439-1445, 2009.
• J. Gregory ve J. Duan, «Hydrolyzing metal salts as coagulants,» Pure Appl. Chem., cilt 73, pp. 2017-2026, 2001.
• J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts.,» Adv. Colloid Interface Sci., cilt 100, pp. 475-502, 2003.
• P. Can˜izares, F. Martinez, J. Garcia-Gomez, C. Saez ve M. A. Rodrigo, «Combined electrooxidation and assisted electrochemical coagulation of aqueous phenol wastes,» J. Appl. Electrochem., cilt 32, pp. 1241-1246, 2002.
• P. Can˜izares, F. Martinez, M. Diaz, J. Garcia-Gomez ve M. A. Rodrigo, «Electrochemical Oxidation of Aqueous Phenol Wastes Using Active and Nonactive Electrodes,» J. Electrochem. Soc., cilt 149, pp. D118-D124, 2002.
• F. Y. Yu, C. W. Li ve S. F. Kang, «Color, dye and doc removal, and acid generation during fenton oxidation of dyes,» EnViron. Technol., cilt 26, pp. 537-544, 2005.
• B. Mondal, V. C. Srivastava ve I. D. Mall, «lectrochemical treatment of textile printing wastewater by stainless steel electrodes: multiple response optimization and residue analysis,» J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., cilt 47, pp. 2040-2051, 2012.
• S. Singh, V. C. Srivastava ve I. D. Mall, «Mechanistic study of electrochemical treatment of basic green 4 dye with aluminum electrodes through zeta potential, TOC, COD and color measurements, and characterization of residues,» RSC Adv., cilt 3, pp. 16426-16439, 2013.
• M. Panizza ve G. Cerisola, «Direct and Mediated Anodic Oxidation of Organic Pollutants,» Chem. Rev., cilt 109, pp. 6541-6569, 2009.
• S. S. Vaghela, A. D. Jethva, B. B. Mehta, S. P. Dave, S. Adimurthy ve G. Ramachandraiah, «Laboratory Studies of Electrochemical Treatment of Industrial Azo Dye Effluent,» Environ. Sci. Technol., cilt 39, pp. 2848-2855, 2005.
• M. Panizza ve G. Cerisola, «Application of Diamond Electrodes to Electrochemical Processes,» Electrochim. Acta, cilt 51, pp. 191-199, 2005.
• C. A. Martinez−Huitle ve S. Ferro, «Electrochemical Oxidation of Organic Pollutants for the Wastewater Treatment: Direct and Indirect Processes,» Chem. Soc. Rev., cilt 35, pp. 1324-1340, 2006.
• G. B. Raju, M. T. Karuppiah, S. S. Latha, S. Parvathy ve S. Prabhakar, «Treatment of Wastewater from Synthetic Textile Industry by Electrocoagulation−Electrooxidation,» Chem. Eng. J., cilt 144, pp. 51-58, 2008.
• J. P. Kushwaha, V. C. Srivastava ve I. D. Mall, «Studies on Electrochemical Treatment of Dairy Wastewater Using Aluminum Electrode,» AIChE J., cilt 57, pp. 2589-2598, 2011.
• J. D. Rodgers, W. Jedral ve N. J. Bunce, «Electrochemical Oxidation of Chlorinated Phenols,» Environ. Sci. Technol., cilt 33, pp. 1453-1457, 1999.
• B. Mondal, V. C. Srivastava, J. P. Kushwaha, R. Bhatnagar, S. Singh ve I. D. Mall, «Parametric and Multiple Response Optimization for the Electrochemical Treatment of Textile Printing Dye-Bath Effluent,» Sep. Purif. Technol., cilt 109, pp. 135-143, 2013.
• E. Yuksel, M. Eyvaz ve E. Gurbulak, «Electrochemical treatment of colour index reactive orange 84 and textile wastewater by using stainless steel and iron electrodes,» Environ. Prog. Sustainable Energy, cilt 32, pp. 60-68, 2013.
• F. Akbal ve A. Kuleyin, «Decolorization of levafix brilliant blue e-b by electrocoagulation method,» Environ. Prog. Sustainable Energy, cilt 30, pp. 29-36, 2011.
• J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts,» Adv. Colloid Interface Sci., cilt 100, p. 475, 2003.