Dispersion of Graphene Using cetyltrimethylammonium bromide (CTAB): Dye Removal and Characterization Studies

Yıl 2021, Cilt: 25 Sayı: 2, 584 - 593, 15.04.2021

Ferda Mindivan , Meryem Göktaş , Ülküye Dudu Gül

https://doi.org/10.16984/saufenbilder.732643

Cited By: 1

Öz

The aim of this study to determine the usability of CTAB-RGO composites in the removal of MB from aqueous solutions and to investigate the stability of composites in the aqueous dispersions. And also, we compared the effects of three different CTAB concentrations on the decolorization of MB. The CTAB-RGO composites performed increasing decolorization activity, decreasing average particle size and resulting individual graphene layers with the increasing CTAB concentration. CTAB-RG0 with 40 and 80 mg/L composites were unstable, RGO and CTAB-RGO with 120 mg/L had good stability in the aqueous solutions. Effective repulsive forces of CTAB-RGO-120 composite prevented to forming graphene aggregates. The highest decolorization rate of CTAB-RGO-120 composite at neutral pH can result from both the electrostatic interaction and π-π interaction.

Anahtar Kelimeler

reduced graphene oxide, cetyltrimethylammonium bromide, decolorization, methylene blue

Kaynakça

• Referans1 Ü.D. Gül, “A green approach for the treatment of dye and surfactant contaminated industrial wastewater,” Brazilian Journal of Biology, Ahead of Print, pp. 1-6, 2019.
• Referans2 H. Liu, S.K. Obendorf, M.J. Leonard, T.J. Young, M.J. Incorvıa, “Adsorption of aroma chemicals on cotton fabric from aqueous systems,” Journal of Surfactants and Detergents, vol.8, 4, pp. 311-317, 2005.
• Referans3 S. Alehyen, F. Bensejjay, M. El Achourı, L. Pérez, M.R., “Infante, Study of the interaction between methyl orange and mono and bis-quaternary ammonium surfactants,” Journal of Surfactants and Detergents, vol. 13, no. 2, pp. 225-231, 2010.
• Referans4 Ü.D. Gül, G. Dönmez, “Influence of surfactants on dye removal and growth of Aspergillus versicolor: an effective way to decolorize textile dye,” Clean Soil Air Water, vol.42, no. 7, pp. 917-922, 2014.
• Referans5 I. Mnif, R. Fendri, D. Ghribi, “Biosorption of Congo Red from aqueous solution by Bacillus weihenstephanensis RI12: effect of SPB1 biosurfactant addition on biodecolorization potency,” Water Science and Technology, vol.72, no. 6, pp. 865-874, 2015.
• Referans6 M.E. Ramírez, Y.H. Vélez, L. Rendón, E. Alzate, “Potential of microalgae in the bioremediation of water with chloride content,” Brazilian Journal of Biology = Revista Brasileira de Biologia, vol. 78, no. 3, pp. 472-476, 2018.
• Referans7 H. Ouni, A. Hafiane, M. Dhahbi, “The effect of surfactant on dye removal by polyelectrolyte enhanced ultrafiltration,” Desalination and Water Treatment, vol.56, no. 6, pp. 1526-1535, 2015.
• Referans8 Ü.D. Gül, S. İlhan, C. Filik İşçen, “Optimization of Biosorption Conditions for Surfactant Induced Decolorization by Anaerobic Sludge Granules,” Tenside Surfactants and Detergents, vol.56, pp. 188- 196, 2019.
• Referans9 M. Poorsargola, M. Alimohammadiana, B. Sohrabia, M. Dehestani, “Dispersion of graphene using surfactant mixtures: Experimental and molecular dynamics simulation studies,” Applied Surface Science, no. 464, pp. 440–450, 2019.
• Referans10 W. Zhang, C. Zhou, W. Zhou, A. Lei, Q. Zhang, Q. Wan, B. Zou, “Fast and Considerable Adsorption of Methylene Blue Dye onto Graphene Oxide,” Bull. Environ. Contam. Toxicol., vol. 87, no. 86, 2011.
• Referans11 P. Sharma, N. Hussain, D.J. Borah, M.R. Das, “Kinetics and Adsorption Behavior of the Methyl Blue at the Graphene Oxide/Reduced Graphene Oxide Nanosheet-Water Interface: A Comparative Study,” J. Chem. Eng. Data., vol. 58, pp. 3477–3488, 2013.
• Referans12 P. Sharma, R. Manash, “Das Removal of a Cationic Dye from Aqueous Solution Using Graphene Oxide Nanosheets: Investigation of Adsorption Parameters,” J. Chem. Eng. Data., vol. 58, pp. 151−158, 2013.
• Referans13 R.K.S. Rathour, J. Bhattacharya, A. Mukherjee, “β-Cyclodextrin Conjugated Graphene Oxide: A Regenerative Adsorbent for Cadmium and Methylene Blue,”J. Mol. Liq., no. 282, pp. 606–616, 2019.
• Referans14 N.H. Othman, N.H. Alias, M.Z. Shahruddinn, N.F. Abu Bakar, N.R.N. Him, W.J. Lau, “Adsorption Kinetics of Methylene Blue Dyes onto Magnetic Graphene Oxide,” J. Environ. Chem. Eng., vol. 6, pp. 2803–2811, 2018.
• Referans15 N.M. Mahmoodi, M. Maroofi Seyyed, M. Mazarji, G. Nabi-Bidhendi, “Preparation of modified reduced graphene oxide nanosheet with cationic surfactant and its dye adsorption ability from colored wastewater,” J. Sufactants Deterg., vol. 20, pp. 1085–1093, 2017.
• Referans16 M. Yusuf, M.A. Khan, M. Otero, E.C. Abdullah, M. Hosomi, A. Terada, S. Riya, “Synthesis of CTAB intercalated graphene and its application for the adsorption of AR265 and AO7 dyes from water,” J. Colloid Interface Sci., no. 493 pp. 51–61, 2017.
• Referans17 K.N. Amba Sankar, C. Sathish Kumar, K. Mohanta, “Highly Stable Aqueous Dispersion of CTAB- Intercalated Reduced Graphene Oxide,” Materials Today: Proceedings, vol. 18, no. 3, pp. 759–764, 2019.
• Referans18 F. Mindivan, “Effect of various initial concentrations of CTAB on the noncovalent modified graphene oxide (MGNO) structure and thermal stability,” Materials Testing, vol. 59, no. 9, 729-734, 2017.
• Referans19 F. Mindivan, M. Göktaş, “Effects of various vitamin C amounts on the green synthesis of reduced graphene oxide,” Materials Testing, vol.61, no.10, 2019.
• Referans20 F. Mindivan, M. Göktas, “Green synthesis of Reduced Graphene Oxide (RGNO) /Polyvinylchloride (PVC) composites and their structural Characterization,” Materials Research Proceedings, (Powder Metallurgy and Advanced Materials– RoPM&AM 2017), vol. 8, pp. 143-151, 2018.
• Referans21 Y. Hu, M. Su, X. Xie, C. Sun, J. Kou, “Few-layer graphene oxide with high yield via efficient surfactant-assisted exfoliation of mildly-oxidized graphite,” Applied Surface Science, vol. 494, pp. 1100–1108, 2019.
• Referans22 B. White, S. Banerjee, S. O’Brien, J.N. Turro, I.P. Herman, “Zeta-Potential Measurements of Surfactant-Wrapped Individual Single-Walled Carbon Nanotubes,” J. Phys. Chem C., no. 111, pp. 13684-13690, 2007.
• Referans23 W.S. Sarsam, A. Amiri, S.N. Kazi, A. Badarudin, “Stability and thermophysical properties of non-covalently functionalized graphene nanoplatelets nanofluids,” Energy Conversion and Management, no. 116, pp. 101–111, 2016.
• Referans24 B. Nazaria, Z. Ranjbara, R.R. Hashjina, A.R. Moghaddama, G. Momenc, B. Ranjbard, “Dispersing graphene in aqueous media: Investigating the effect of different Surfactants,” Colloids and Surfaces A, vol.58, no.123870, 2019.
• Referans25 Y. Wu, H. Luo, H. Wang, C. Wang, J. Zhang, Z. Zhang, “Adsorption of hexavalent chromium from aqueous solutions by graphene modified with cetyltrimethylammonium bromide,” Journal of Colloid and Interface Science, no. 394, pp. 183–191, 2013.
• Referans26 Ü.D. Gül and G. Dönmez, “Effects of Dodecyl Trimethyl Ammonium Bromide Surfactant on Decolorization of Remazol Blue by a Living Aspergillus versicolor Strain,” J Surfact Deterg, vol.15, pp. 797-803, 2012.
• Referans27 G.M. Nabil, N.M. El-Mallah, M.E. Mahmoud, “Enhanced decolorization of reactive black 5 dye by active carbon sorbent-immobilized-cationic surfactant (AC-CS),” Journal of Industrial and Engineering Chemistry, vol.20, no.3, pp. 994-1002, 2014.
• Referans28 R.S.S. Siddhardha, V.L. Kumar, A. Kaniyoor, V.S. Muthukumar, S. Ramaprabhu, R. Podila, A.M. Rao, S.S. Ramamurthy, “Synthesis and characterization of gold graphene composite with dyes as model substrates for decolorization: A surfactant free laser ablation approach,” Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, no. 133, pp. 365-371, 2014.
• Referans29 C.-J. Shih, S. Lin, R. Sharma, M.S. Strano, D. Blankschtein, “Understanding the pH-Dependent Behavior of Graphene Oxide Aqueous Solutions: A Comparative Experimental and Molecular Dynamics Simulation Study,” Langmuir, vol. 28, no. 1, pp. 235-241, 2012.
• Referans30 J. Su, S. He, Z. Zhao, X. Liu, H. Li “Efficient preparation of cetyltrimethylammonium bromide-graphene oxide composite and its adsorption of Congo red from aqueous solutions,” Colloids and Surfaces A, no. 554, pp. 227–236, 2018.
• Referans31 A.Y.W. Sham, S.M. Notley, “Adsorption of organic dyes from aqueous solutions using surfactant exfoliated graphene,” Journal of Environmental Chemical Engineering, no. 6, pp. 495–504, 2018.