Removal of Paracetamol by Powdered Activated Carbon Synthesized From Orange Peels
Yıl 2023,
Cilt: 27 Sayı: 1, 168 - 180, 28.02.2023
İrem Konuk Akça
,
Rabia Köklü
Öz
This study aims to investigate the removal of Paracetamol active ingredient from aqueous solutions with the use of powdered activated carbon obtained by ZnCl2 activation of orange peels. Equilibrium values of initial paracetamol concentration (100-500 mg L-1), pH (2-10), adsorbent dose (10-500 mg) and contact time (5-120 minutes) parameters in the removal of paracetamol from aqueous solutions are evaluated. The adsorption mechanism of paracetamol is explained with the kinetic models. The highest correlation among Langmuir, Freundlich, Temkin, and Dubinin-Radushkevichi isotherms applied to experimental data was determined as Freundlich isotherm with R2 =0.95. Pseudo-first-order and pseudo-second-order kinetic models were applied, and it was found that the latter, whose correlation coefficient is determined as R2 =0.99, is the best model to explain paracetamol adsorption. As a result of this study, it can be seen that powdered activated carbon synthesized from orange peel is an effective adsorbent in the removal of paracetamol and can be easily applied thanks to its low cost.
Teşekkür
We would like to thank Prof. Dr. Mustafa İmamoğlu for his support in the preparation of activated carbon and for sharing his knowledge and experience with us.
Kaynakça
- [1] H. F. D. Almeida, M. C. Neves, T. Trindade, I. M. Marrucho, M. G. Freire, “Supported ionic liquids as efficient materials to removenon-steroidal anti-inflammatory drugs from aqueous media,” Chemical Engineering Journal, vol. 381, Feb. 2020, Art. no. 122616.
[2] Q. Qin, X. Chen, J. Zhuang, “The fate and impact of pharmaceuticals and personal care products in agricultural soils irrigated with reclaimed water,” Critical Reviews in Environmental Science and Technology, vol. 45, no. 13, pp. 1379-1408, Jul. 2015.
- [3] P. H. Roberts, K. V. Thomas, “The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of lower tyne catchment,” Science of The Total Environment, vol. 356, pp. 143-153, Mar. 2006.
- [4] M. Naghdi, M. Taheran, S. K. Brar, A. Kermanshahi-pour, M. P. Verma, R. Y. Surampalli, “Removal of pharmaceutical compounds in water and wastewater using fungal oxidoreductase enzymes,” Environmental pollution, vol. 234, pp. 190-213, Mar. 2018.
- [5] K. Ikehata, N. J. Naghashkar, M. Gamal El-Din, “Degradation of Aqueous Pharmaceuticals by Ozonation and Advanced Oxidation Processes: A review,” Ozone: Science and Engineering, vol. 28, pp. 353-414, Dec. 2006.
- [6] S. Kharel, M. Stapf, U. Miehe, M. Ekblad, M. Cimbritz, P. Falås, J. Nilsson, R. Robert Sehlén, K. Bester, “Ozone dose dependent formation and removal of ozonation products of pharmaceuticals in pilot and full-scale municipal wastewater treatment plants,” Science of The Total Environment, vol. 731, Aug. 2020, Art. no. 139064.
- [7] C. V. Rekhate, J. K. Srivastava, “Recent advances in ozone-based advanced oxidation processes for treatment of wastewater- A review,” Chemical Engineering Journal Advances, vol. 3, pp. 1-85, Nov. 2020.
- [8] C. Femina Carolin, P. Senthil Kumar, G. Janet Joshiba, V. V. Kumar, “Analysis and removal of pharmaceutical residues from wastewater using membrane bioreactors: a review,” Environmental Chemistry Letters, vol. 19, pp. 329–343, Aug. 2020.
- [9] S. Wong, Y. Lim, N. Ngadi, R. Mat, O. Hassan, I. Inuwa, N. Mohamed, J. Low, “Removal of acetaminophen by activated carbon synthesized from spent tea leaves: equilibrium, kinetics and thermodynamics studies,” Powder Technology, vol. 338, pp. 878–886, Oct. 2018.
- [10] D. Nguyen, H. Tran, R. Juang, N. Dat, F. Tomul, A. Ivanets, S. Woo, A. Hosseini-Bandegharaei, V. Nguyen, H. Chao, “Adsorption process and mechanism of acetaminophen onto commercial,” Journal of Environmental Chemical Engineering, vol. 8, no. 6, Dec. 2020, Art. no. 104408.
- [11] Z. Aksu, D. Akpınar, “Competitive biosorpsion of phenol and chromium(VI) from binary mixtures onto dried anaerobic activated sludge,” Biochemical Engineering Journal, vol. 7, no. 3, pp. 183-193, May. 2001.
- [12] M. Zarroug, S. N. Souissi, J. A. Menéndez, E. G. Calvo, A. Quederni, “Fast production of activated carbon from pomegranate peels by combining microwave heating and phosphoric acid activation for paracetamol adsorption,” Environmental Engineering Science, vol. 39, pp. 441-452, May. 2022.
- [13] Z. T. Al- Sharify, L. M. A. Faisal, T. A. Al-Sharif, N. T. Al-Sharify, F. M. A. Faisal, “Removal of analgesic paracetamol from wastewater using dried olive stone,” International Journal of Civil Engineering and Technology, vol. 9, no. 13, pp. 293-299, 2018.
- [14] D. R. Lima, A. Hosseini-Bandegharaei, P. S. Thue, E. C. Lima, Y. R. T. de Albuquerque, G.S. dos Reis, C. S. Umpierres, S. L. P. Dias, H. N. Tran, “Efficient acetaminophen removal from water and hospital effluents treatment by activated carbons derived from Brazil nutshells,” Colloids and Surfaces, vol. 583, Dec. 2019, Art. no. 123966.
- [15] R. C. Ferreira, H. H. C. De Lima, A. A. Cândido, O. M. C. Junior, P. A. Arroyo, K. Q. De Carvalho, “Adsorption of paracetamol using activated carbon of dende and babassu coconut mesocarp,” International Journal of Agricultural and Biological Engineering, vol. 9, pp. 717–722, 2015.
- [16] Ç. Özer, M. Imamoğlu, “Removal of ciprofloxacin from aqueous solutions by pumpkin peel biochar prepared using phosphoric acid,” Biomass Conversion and Biorefinery, 2022.
- [17] Ç. Özer, M. Imamoğlu, “Isolation of nickel(II) and lead(II) from aqueous solution by sulfuric acid prepared pumpkin peel biochar,” Analytical Letters, 2022.
- [18] S. Usanmaz, Ç. Özer, M. Imamoğlu, “Removal of Cu(II), Ni(II) and Co(II) ions from aqueous solutions by hazelnut husks carbon activated with phosphoric acid,” Desalination and Water Treatment, vol. 227, pp. 300–308, Jul. 2021.
- [19] Q. Wei, Z. Chen, Y. Cheng, X. Wang, X. Yang, Z. Wang, “Preparation and electrochemical performance of orange peelbased-activated carbons activated by different activators,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 574, no. 5, pp. 221–227, Aug. 2019.
- [20] O. S. Bello, T. C. Alagbada, O. C. Alao, A. M. Olatunde, “Sequestering a non-steroidal anti-inflammatory drug using modified orange peels,”Applied Water Science, vol. 10, Art. no. 172, Jun. 2020.
- [21] J. K. Bediako, S. Lin, A. K. Sarkar, Y. Zhao, J. W. Choi, M. H. Song, C. W. Cho, Y. S. Yun, “Evaluation of orange peel-derived activated carbons for treatment of dye-contaminated wastewater tailings,” Environmental Science and Pollution Research, vol. 27, pp. 1053–1068, Jan. 2020.
- [22] C. Djilani, R. Zaghdoudi, A. Modarressi, M. Rogalski, D. Faycal, A. Lallam, “Elimination of organic micropollutants by adsorption on activated carbon prepared from agricultural waste,” Chemical Engineering Journal, vol. 189–190, pp. 203–212., May. 2012.
[23] R. Köklü, M. Imamoğlu, “Removal of ciprofloxacin from aqueous solution by activated carbon prepared from orange peel using zinc chloride,” Membrane and Water Treatment, vol. 13, no. 3, pp. 129-137, May. 2022.
- [24] A. Gundogdu, C. Duran, H. B. Senturk, M. Soylak, D. Ozdes, H. Serencam, M. Imamoglu, “Adsorption of phenol from aqueous solution on a low-cost activated carbon produced from tea industry waste: Equilibrium, kinetic, and thermodynamic study,” Journal of Chemical & Engineering Data, vol. 57, no. 10, pp. 2733–2743, Aug. 2012.
- [25] I. Langmuir, “The constitution and fundamental properties of solids and liquids. Part I. Solids,” Journal of the American Chemical Society, vol. 38, pp. 2221-2295, 1916.
- [26] H. M. F. Freundlich, “Over the adsorption in solution,” The Journal of Physical Chemistry, vol. 57, pp. 385-470, 1906.
- [27] M. Temkin, V. Pyzhev, “Recent Modifications to Langmuir isotherms”, Acta Physico-Chimica Sinica, vol. 12, pp. 217–222, 1940.
- [28] M. M. Dubinin, L. V. Radushkevich, “Equation of the characteristic curve of activated charcoal,” Proceedings of the Academy of Sciences of the USSR. Physical chemistry section, vol. 55, pp. 331-333, 1947.
- [29] M. E. Fernández, “Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes,” Industrial Crops and Products, vol. 62, pp. 437-445, Dec. 2014.
- [30] E. T. Özer , “Removal of amoxicillin from aqueous solutions with activated carbon: kinetic and equilibrium studies,” European Journal of Science and Technology, vol. 18, pp. 833-839, 2020.
- [31] P. Iovino, S. Canzano, S. Capasso, A. Erto, D. Musmarra, “A modeling analysis for the assessment of ibuprofen adsorption mechanism onto activated carbons,” Chemical Engineering Journal, vol. 227, pp. 360-367, Oct. 2015.
- [32] G. Moussavi, Z. Hossaini, M. Pourakbar, “High-rate adsorption of acetaminophen from the contaminated water onto double-oxidized graphene oxide,” Chemical Engineering Journal, vol. 287, pp. 665-673, Mar. 2016.
- [33] A. F. Streit, G. C. Collazzo, S. P. Druzian, R. S. Verdi, E. L. Foletto, L. F. Oliveira, G. L. Dotto, “Adsorption of ibuprofen, ketoprofen, and paracetamol onto activated carbon prepared from effluent treatment plant sludge of the beverage industry,” Chemosphere, vol. 262, Jan. 2021, Art. no. 128322.
- [34] J. R. Baseri, P. N. Palanisamy, P. Sivakumar, “Preparation and characterization of activated carbon from Thevetia peruviana for the removal of dyes from textile waste water,” Advances in Applied Science Research, vol. 3, pp. 377-383, 2012.
- [35] Ç. Özer, M. Imamoğlu, “Adsorptive transfer of methylene blue from aqueous solutions to hazelnut husk carbon activated with potassium carbonate,” Desalination and Water Treatment, vol. 94, pp. 236-243, Oct. 2017.
- [36] S. W. Nam, D. J. Choi, S. K Kim, N. Her, K. D. Zoh, “Adsorption characteristics of selected hydrophilic and hydrophobic micropollutants in water using activated carbon,”, Journal of hazardous materials, vol. 270, pp. 144–152, Apr. 2014.
- [37] M. Sajid, S. Bari, M. S. U. Rehman, M. Ashfaq, “Adsorption characteristics of paracetamol removal onto activated carbon prepared from Cannabis sativum Hemp”, AEJ- Alexandria Engineering Journal, vol. 61, no. 1, pp. 7203-7212, Sep. 2022.
- [38] S. Shrestha, G. Son, S. H. Lee, T. G. Lee, “Isotherm and thermodynamic studies of Zn (II) adsorption on lignite and coconut shell-based activated carbon fiber,” Chemosphere, vol. 92, no. 8, pp. 1053–1061, Aug. 2013.
- [39] S. Banerjee, G. C. Sharma, M .C. Chattopadhyaya, Y. C. Sharma, “Kinetic and equilibrium modeling for the adsorptive removal of methylene blue from aqueous solutions on of activated fly ash (AFSH),” Journal of Environmental Chemical Engineering, vol. 2, no. 3, pp. 1870–1880, Sep. 2014.
- [40] H. Nourmoradi, K. F. Moghadam, A. Jafari, B. Kamarehie, “Removal of acetaminophen and ibuprofen from aqueous solutions by activated carbon derived from Quercus Brantii (Oak) acorn as a low-cost biosorbent,” Journal of Environmental Chemical Engineering, vol. 6, no. 6, pp. 6807-6815, Dec. 2018.
- [41] A. Çiçekçi, B. Dönmez, E. Kavcı, Ö. Laçin, “Adsorption isotherm and thermodynamics for the continuation of malachite green,” Sinop University Journal of Science, vol. 5, no. 2, pp. 103-111, 2020, 10.33484/sinopfbd.701059.
- [42] S. Hashemian, K. Salari, Z. A. Yazdi, “Preparation of activated carbon from agricultural wastes (almond shell and orange peel) for adsorption of 2-pic from aqueous solution,” Journal of Industrial and Engineering Chemistry, vol. 20, no. 4, pp. 1892–1900, Jul. 2014.
- [43] S. Lagergren, “Zur theorie der sogenannten adsorption geloster stoffe,” Kungliga svenska vetenskapsakademiens Handlingar, vol. 24, pp. 1-39, 1898.
- [44] Y. S. Ho, G. McKay, “Sorption of dye from aqueous solution by peat,” Chemical Engineering Journal, vol. 70, pp. 115-124, 1998.
- [45] M. Parades Laverde, M. Salamanca, J. Silva Agredo, L. Manrique Losada, R. A. Torres Palma, “Selective removal of acetaminophen in urine with activated carbons from rice (oryza sativa) and coffee (coffea arabica) husk: Effect of activating agent, activation temperature and analysis of physical-chemical interactions,” Journal of Environmental Chemical Engineering, vol. 7, no. 5, Oct. 2019, Art. No.103318.
Yıl 2023,
Cilt: 27 Sayı: 1, 168 - 180, 28.02.2023
İrem Konuk Akça
,
Rabia Köklü
Kaynakça
- [1] H. F. D. Almeida, M. C. Neves, T. Trindade, I. M. Marrucho, M. G. Freire, “Supported ionic liquids as efficient materials to removenon-steroidal anti-inflammatory drugs from aqueous media,” Chemical Engineering Journal, vol. 381, Feb. 2020, Art. no. 122616.
[2] Q. Qin, X. Chen, J. Zhuang, “The fate and impact of pharmaceuticals and personal care products in agricultural soils irrigated with reclaimed water,” Critical Reviews in Environmental Science and Technology, vol. 45, no. 13, pp. 1379-1408, Jul. 2015.
- [3] P. H. Roberts, K. V. Thomas, “The occurrence of selected pharmaceuticals in wastewater effluent and surface waters of lower tyne catchment,” Science of The Total Environment, vol. 356, pp. 143-153, Mar. 2006.
- [4] M. Naghdi, M. Taheran, S. K. Brar, A. Kermanshahi-pour, M. P. Verma, R. Y. Surampalli, “Removal of pharmaceutical compounds in water and wastewater using fungal oxidoreductase enzymes,” Environmental pollution, vol. 234, pp. 190-213, Mar. 2018.
- [5] K. Ikehata, N. J. Naghashkar, M. Gamal El-Din, “Degradation of Aqueous Pharmaceuticals by Ozonation and Advanced Oxidation Processes: A review,” Ozone: Science and Engineering, vol. 28, pp. 353-414, Dec. 2006.
- [6] S. Kharel, M. Stapf, U. Miehe, M. Ekblad, M. Cimbritz, P. Falås, J. Nilsson, R. Robert Sehlén, K. Bester, “Ozone dose dependent formation and removal of ozonation products of pharmaceuticals in pilot and full-scale municipal wastewater treatment plants,” Science of The Total Environment, vol. 731, Aug. 2020, Art. no. 139064.
- [7] C. V. Rekhate, J. K. Srivastava, “Recent advances in ozone-based advanced oxidation processes for treatment of wastewater- A review,” Chemical Engineering Journal Advances, vol. 3, pp. 1-85, Nov. 2020.
- [8] C. Femina Carolin, P. Senthil Kumar, G. Janet Joshiba, V. V. Kumar, “Analysis and removal of pharmaceutical residues from wastewater using membrane bioreactors: a review,” Environmental Chemistry Letters, vol. 19, pp. 329–343, Aug. 2020.
- [9] S. Wong, Y. Lim, N. Ngadi, R. Mat, O. Hassan, I. Inuwa, N. Mohamed, J. Low, “Removal of acetaminophen by activated carbon synthesized from spent tea leaves: equilibrium, kinetics and thermodynamics studies,” Powder Technology, vol. 338, pp. 878–886, Oct. 2018.
- [10] D. Nguyen, H. Tran, R. Juang, N. Dat, F. Tomul, A. Ivanets, S. Woo, A. Hosseini-Bandegharaei, V. Nguyen, H. Chao, “Adsorption process and mechanism of acetaminophen onto commercial,” Journal of Environmental Chemical Engineering, vol. 8, no. 6, Dec. 2020, Art. no. 104408.
- [11] Z. Aksu, D. Akpınar, “Competitive biosorpsion of phenol and chromium(VI) from binary mixtures onto dried anaerobic activated sludge,” Biochemical Engineering Journal, vol. 7, no. 3, pp. 183-193, May. 2001.
- [12] M. Zarroug, S. N. Souissi, J. A. Menéndez, E. G. Calvo, A. Quederni, “Fast production of activated carbon from pomegranate peels by combining microwave heating and phosphoric acid activation for paracetamol adsorption,” Environmental Engineering Science, vol. 39, pp. 441-452, May. 2022.
- [13] Z. T. Al- Sharify, L. M. A. Faisal, T. A. Al-Sharif, N. T. Al-Sharify, F. M. A. Faisal, “Removal of analgesic paracetamol from wastewater using dried olive stone,” International Journal of Civil Engineering and Technology, vol. 9, no. 13, pp. 293-299, 2018.
- [14] D. R. Lima, A. Hosseini-Bandegharaei, P. S. Thue, E. C. Lima, Y. R. T. de Albuquerque, G.S. dos Reis, C. S. Umpierres, S. L. P. Dias, H. N. Tran, “Efficient acetaminophen removal from water and hospital effluents treatment by activated carbons derived from Brazil nutshells,” Colloids and Surfaces, vol. 583, Dec. 2019, Art. no. 123966.
- [15] R. C. Ferreira, H. H. C. De Lima, A. A. Cândido, O. M. C. Junior, P. A. Arroyo, K. Q. De Carvalho, “Adsorption of paracetamol using activated carbon of dende and babassu coconut mesocarp,” International Journal of Agricultural and Biological Engineering, vol. 9, pp. 717–722, 2015.
- [16] Ç. Özer, M. Imamoğlu, “Removal of ciprofloxacin from aqueous solutions by pumpkin peel biochar prepared using phosphoric acid,” Biomass Conversion and Biorefinery, 2022.
- [17] Ç. Özer, M. Imamoğlu, “Isolation of nickel(II) and lead(II) from aqueous solution by sulfuric acid prepared pumpkin peel biochar,” Analytical Letters, 2022.
- [18] S. Usanmaz, Ç. Özer, M. Imamoğlu, “Removal of Cu(II), Ni(II) and Co(II) ions from aqueous solutions by hazelnut husks carbon activated with phosphoric acid,” Desalination and Water Treatment, vol. 227, pp. 300–308, Jul. 2021.
- [19] Q. Wei, Z. Chen, Y. Cheng, X. Wang, X. Yang, Z. Wang, “Preparation and electrochemical performance of orange peelbased-activated carbons activated by different activators,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 574, no. 5, pp. 221–227, Aug. 2019.
- [20] O. S. Bello, T. C. Alagbada, O. C. Alao, A. M. Olatunde, “Sequestering a non-steroidal anti-inflammatory drug using modified orange peels,”Applied Water Science, vol. 10, Art. no. 172, Jun. 2020.
- [21] J. K. Bediako, S. Lin, A. K. Sarkar, Y. Zhao, J. W. Choi, M. H. Song, C. W. Cho, Y. S. Yun, “Evaluation of orange peel-derived activated carbons for treatment of dye-contaminated wastewater tailings,” Environmental Science and Pollution Research, vol. 27, pp. 1053–1068, Jan. 2020.
- [22] C. Djilani, R. Zaghdoudi, A. Modarressi, M. Rogalski, D. Faycal, A. Lallam, “Elimination of organic micropollutants by adsorption on activated carbon prepared from agricultural waste,” Chemical Engineering Journal, vol. 189–190, pp. 203–212., May. 2012.
[23] R. Köklü, M. Imamoğlu, “Removal of ciprofloxacin from aqueous solution by activated carbon prepared from orange peel using zinc chloride,” Membrane and Water Treatment, vol. 13, no. 3, pp. 129-137, May. 2022.
- [24] A. Gundogdu, C. Duran, H. B. Senturk, M. Soylak, D. Ozdes, H. Serencam, M. Imamoglu, “Adsorption of phenol from aqueous solution on a low-cost activated carbon produced from tea industry waste: Equilibrium, kinetic, and thermodynamic study,” Journal of Chemical & Engineering Data, vol. 57, no. 10, pp. 2733–2743, Aug. 2012.
- [25] I. Langmuir, “The constitution and fundamental properties of solids and liquids. Part I. Solids,” Journal of the American Chemical Society, vol. 38, pp. 2221-2295, 1916.
- [26] H. M. F. Freundlich, “Over the adsorption in solution,” The Journal of Physical Chemistry, vol. 57, pp. 385-470, 1906.
- [27] M. Temkin, V. Pyzhev, “Recent Modifications to Langmuir isotherms”, Acta Physico-Chimica Sinica, vol. 12, pp. 217–222, 1940.
- [28] M. M. Dubinin, L. V. Radushkevich, “Equation of the characteristic curve of activated charcoal,” Proceedings of the Academy of Sciences of the USSR. Physical chemistry section, vol. 55, pp. 331-333, 1947.
- [29] M. E. Fernández, “Activated carbon developed from orange peels: Batch and dynamic competitive adsorption of basic dyes,” Industrial Crops and Products, vol. 62, pp. 437-445, Dec. 2014.
- [30] E. T. Özer , “Removal of amoxicillin from aqueous solutions with activated carbon: kinetic and equilibrium studies,” European Journal of Science and Technology, vol. 18, pp. 833-839, 2020.
- [31] P. Iovino, S. Canzano, S. Capasso, A. Erto, D. Musmarra, “A modeling analysis for the assessment of ibuprofen adsorption mechanism onto activated carbons,” Chemical Engineering Journal, vol. 227, pp. 360-367, Oct. 2015.
- [32] G. Moussavi, Z. Hossaini, M. Pourakbar, “High-rate adsorption of acetaminophen from the contaminated water onto double-oxidized graphene oxide,” Chemical Engineering Journal, vol. 287, pp. 665-673, Mar. 2016.
- [33] A. F. Streit, G. C. Collazzo, S. P. Druzian, R. S. Verdi, E. L. Foletto, L. F. Oliveira, G. L. Dotto, “Adsorption of ibuprofen, ketoprofen, and paracetamol onto activated carbon prepared from effluent treatment plant sludge of the beverage industry,” Chemosphere, vol. 262, Jan. 2021, Art. no. 128322.
- [34] J. R. Baseri, P. N. Palanisamy, P. Sivakumar, “Preparation and characterization of activated carbon from Thevetia peruviana for the removal of dyes from textile waste water,” Advances in Applied Science Research, vol. 3, pp. 377-383, 2012.
- [35] Ç. Özer, M. Imamoğlu, “Adsorptive transfer of methylene blue from aqueous solutions to hazelnut husk carbon activated with potassium carbonate,” Desalination and Water Treatment, vol. 94, pp. 236-243, Oct. 2017.
- [36] S. W. Nam, D. J. Choi, S. K Kim, N. Her, K. D. Zoh, “Adsorption characteristics of selected hydrophilic and hydrophobic micropollutants in water using activated carbon,”, Journal of hazardous materials, vol. 270, pp. 144–152, Apr. 2014.
- [37] M. Sajid, S. Bari, M. S. U. Rehman, M. Ashfaq, “Adsorption characteristics of paracetamol removal onto activated carbon prepared from Cannabis sativum Hemp”, AEJ- Alexandria Engineering Journal, vol. 61, no. 1, pp. 7203-7212, Sep. 2022.
- [38] S. Shrestha, G. Son, S. H. Lee, T. G. Lee, “Isotherm and thermodynamic studies of Zn (II) adsorption on lignite and coconut shell-based activated carbon fiber,” Chemosphere, vol. 92, no. 8, pp. 1053–1061, Aug. 2013.
- [39] S. Banerjee, G. C. Sharma, M .C. Chattopadhyaya, Y. C. Sharma, “Kinetic and equilibrium modeling for the adsorptive removal of methylene blue from aqueous solutions on of activated fly ash (AFSH),” Journal of Environmental Chemical Engineering, vol. 2, no. 3, pp. 1870–1880, Sep. 2014.
- [40] H. Nourmoradi, K. F. Moghadam, A. Jafari, B. Kamarehie, “Removal of acetaminophen and ibuprofen from aqueous solutions by activated carbon derived from Quercus Brantii (Oak) acorn as a low-cost biosorbent,” Journal of Environmental Chemical Engineering, vol. 6, no. 6, pp. 6807-6815, Dec. 2018.
- [41] A. Çiçekçi, B. Dönmez, E. Kavcı, Ö. Laçin, “Adsorption isotherm and thermodynamics for the continuation of malachite green,” Sinop University Journal of Science, vol. 5, no. 2, pp. 103-111, 2020, 10.33484/sinopfbd.701059.
- [42] S. Hashemian, K. Salari, Z. A. Yazdi, “Preparation of activated carbon from agricultural wastes (almond shell and orange peel) for adsorption of 2-pic from aqueous solution,” Journal of Industrial and Engineering Chemistry, vol. 20, no. 4, pp. 1892–1900, Jul. 2014.
- [43] S. Lagergren, “Zur theorie der sogenannten adsorption geloster stoffe,” Kungliga svenska vetenskapsakademiens Handlingar, vol. 24, pp. 1-39, 1898.
- [44] Y. S. Ho, G. McKay, “Sorption of dye from aqueous solution by peat,” Chemical Engineering Journal, vol. 70, pp. 115-124, 1998.
- [45] M. Parades Laverde, M. Salamanca, J. Silva Agredo, L. Manrique Losada, R. A. Torres Palma, “Selective removal of acetaminophen in urine with activated carbons from rice (oryza sativa) and coffee (coffea arabica) husk: Effect of activating agent, activation temperature and analysis of physical-chemical interactions,” Journal of Environmental Chemical Engineering, vol. 7, no. 5, Oct. 2019, Art. No.103318.