Kırmızılahananın Farklı pH ve Mordanlama Koşullarında Pamuklu Kumaşları Boyama Özelliklerinin Araştırılması

Yıl 2020, Cilt: 24 Sayı: 2, 244 - 255, 26.08.2020

Buket Arık , Ezgi Canitez Arzu Kirtak

https://doi.org/10.19113/sdufenbed.639829

Cited By: 1

Öz

Bu çalışmada, doğal boya kaynağı olarak kırmızılahana ekstraktı ve potasyumalüminyumsülfat ve tannik asit olmak üzere iki çeşit mordan maddesi ile pamuklu kumaşların boyanma özellikleri araştırılmıştır. Mordan maddelerinin pamuklu kumaşlara aktarılmasında ön mordanlama, birlikte mordanlama ve sonradan mordanlama yöntemleri kullanılmış ve doğal boyama işlemleri çektirme yöntemine göre gerçekleştirilmiştir. Ayrıca kırmızılahananın indikatör özelliği sayesinde farklı pH koşullarında farklı renkler verdiği de bilindiğinden denemeler asidik, bazik ve nötr olmak üzere üç farklı pH koşulunda da tekrarlanmıştır. Boyama işlemlerinin ardından numunelere renk ölçümü, sürtme ve yıkama haslığı testleri uygulanmıştır. Çalışma sonucunda, kırmızılahana ekstraktının pamuklu kumaşların renklendirilmesinde kullanılabileceği ve en kalıcı renk tonlarının nötr pH koşullarında elde edilebileceği görülmüştür. Mordanlama yöntemleri ve mordan maddeleri birbiri ile kıyaslandığında ise mordan maddelerine ve yöntemlerine göre pamuklu kumaşların farklı renk tonları verdiği belirlenmiştir. Genel olarak bakıldığında, ön mordanlama yöntemi ve tannik asit mordanı ile daha yüksek renk verimine sahip düzgün boyamaların yapılabildiği ve koyu renk tonları elde etmek için yüksek mordan konsantrasyonu kullanılması gerektiği sonucuna varılmıştır. Ayrıca, yıkama ve sürtme haslığı değerlerinin de doğal boyamalar açısından kabul edilebilir seviyede olduğu belirlenmiştir.

Anahtar Kelimeler

Kırmızılahana, Potasyumalüminyumsülfat, Tannik asit, Doğal boyama, Mordanlama, Pamuk

Investigation of Dyeing Properties of Red Cabbage to Cotton Fabrics in Different pH and Mordanting Conditions

Öz

In this study, dyeing properties of cotton fabrics with red cabbage extract as a natural colorant and by mordanting materials like potassium aluminumsulphate and tannic acid were investigated. Pre-mordanting, simultaneous mordanting and post-mordanting methods were used for mordanting of cotton fabric and natural dyeing process was carried out by exhaustion method. Moreover, since it is known that red cabbage presents different colors in different pH values due to its indicator property, the trials were renewed for three pH conditions as acidic, basic and neutral. After dyeing processes, color measurement, washing and rubbing fastness tests were applied to the samples. As a result of the study, it was observed that red cabbage extract can be used to dye cotton fabrics and the most permanent colors can be obtained in neutral pH conditions. When mordanting methods and mordanting materials were compared to each other, it was determined that various color shades were provided according to the mordanting materials and methods. In terms of general, it was concluded that uniform dyeings with high color yield can be obtained by tannic acid mordant and pre-mordanting method and high mordant concentration should be used to get dark color shades. In addition, washing and rubbing fastness values were determined to be in acceptable limits for natural dyeing.    

Anahtar Kelimeler

Red cabbage, Potassiumaluminumsulphate, Tannic acid, Natural dyeing, Mordanting, Cotton

Kaynakça

• [1] Kilicarslan, H. 2006. The colors obtained from fir (abies) cone and the fastness values of these colors on wool carpet yarns. Ankara University, MSc. Thesis, 70p, Ankara, Turkey.
• [2] Karadag, R. 2007. Natural Dyeing. 1st, Republic of Turkey Ministry of Culture and Tourism, Ankara, Turkey, 129p.
• [3] Onem, E. 2009. A research on applicability of madder in the leather dyeing. Ege University, MSc. Thesis, 60p, Izmir, Turkey.
• [4] Benli, H. 2012. Wool yarns dyed with madder red and buckthorn used in turkish carpets and improvement of fastness. Arış, 7(7), 18-25.
• [5] Krizova, H. 2015. Natural dyes: their past, present, future and sustainability. pp 59-71. Křemenáková, D., Militký, J., Mishra, R., ed. 2015. Recent Developments in Fibrous Material Science, Kanina Publishing, Liberec, Czech Republic.
• [6] Kaya, U., Sanli, H. S. 2017. Dying of cotton, wool and silk clothes with woad plants’ coloring agent and analysing some purity ratings. Idil, 6(37), 2581-2594.
• [7] Yilmaz, F., Bahtiyari, M. I. 2017. Coloration of wool fabrics with various plantal sources. Journal of Textiles and Engineer, 24(106), 62-71.
• [8] Cakir, U. 2015. Investigation of usage of the plant of red cabbage (Brassica oleracea L. Var. capitata L. rubra (L.) Thell) as cellulosic and protein fiber dyestuff. Gaziosmanpasa University, PhD. Thesis, 116p, Tokat, Turkey.
• [9] Akbay, N. S. 2015. Dyeing properties of varium fabrics with the extract of red cabbage (Brassica oleracea var. capitata f. rubra) and onion shell (Allium cepa). Gaziosmanpasa University, MSc. Thesis, 117p, Tokat, Turkey.
• [10] Gokhale, S. B., Tatiya, A. U., Bakliwal, S. R., Fursule, R. A. 2004. Natural dye yielding plants in India. Natural Product Radiance, 3(4), 228-234.
• [11] Geetha, B., Sumathy, V. J. H. 2013. Extraction of natural dyes from plants. International Journal of Chemistry and Pharmaceutical Sciences, 1(8), 502-509.
• [12] Onal, A., Subasar, F. D. 2012. Cotton, wool and linen fabrics dyeing with natural dye extracted from red cabbage (Brassica oleracea var.capitata f.rubra). Gaziosmanpasa Journal of Scientific Research, 1(4), 35-41.
• [13] Ben Ticha, M., Haddar, W., Meksi, N., Guesmi, A., Mhenni, M. F. 2016. Improving dyeability of modified cotton fabrics by the natural aqueous extract from red cabbage using ultrasonic energy. Carbohydrate Polymers, 154(32), 287–295.
• [14] Benli, H. 2017. An investigation of dyeability of wool fabric with red cabbage (Brassica oleracea L. var.) extract. Industria Textila, 68(2), 108-115.
• [15] Haddar, W., Ben Ticha, M., Meksi, N., Guesmi, A. 2018. Application of anthocyanins as natural dye extracted from Brassica oleracea L. var. capitata f. rubra: Dyeing studies of wool and silk fibres. Natural Product Research, 32(2), 141-148.
• [16] Kahkonen, M. P., Heinamaki, J., Ollilainen, V., Heinonen, M. 2003. Berry anthocyanins: isolation, identification and antioxidant activities. Journal of the Science of Food and Agriculture, 83(14), 1403–1411.
• [17] Morgil, I., Karatas, F. 2009. Chemistry education and chemistry education seminar 1 course notes. http://www.kimyaegitimi.org/sites/default/files/kimya_egitimi_ogrenci_deneyleri/kirmizi_lahana_deneyi.pdf (Access Date: 26.07.2019).
• [18] Sarigul, T. 2015. Chemistry of red cabbage. http://www.bilimgenc.tubitak.gov.tr/makale/kirmizi-lahananin-kimyasi (Access Date: 15.04.2019).
• [19] Yilmaz, B. 2019. Home experiment with magic colors - Red cabbage experiment. https://www.kidsgourmet.com.tr/sihirli-renkler-ile-evde-deney (Access Date: 24.07.2019).
• [20] Tutak, M., Benli, H. 2008. Investigation of dyeing properties of natural dyes obtained from some plants on wool. Journal of Balikesir University Institute of Science and Technology, 10(2), 53-59.
• [21] Rungruangkitkrai, N., Mongkholrattanasit, R. 2012. Eco-friendly of textiles dyeing and printing with natural dyes. RMUTP International Conference: Textiles & Fashion, 3-4 July, Bangkok, Thailand, 1-17.
• [22] Ismal, O. E. 2016. Patterns from nature: contact printing. Journal of the Textile Association, 77(2), 81-91.
• [23] Moniruzzaman, M., Mondal, M. S., Hossain, M. N. 2018. The influence of mordant and mordanting techniques on ecofriendly dyeing of cotton fabric by extracted used tea. Journal of Engineering Science, 9(1), 111-117.
• [24] Karabulut, K. 2015. Giving color, UV protection and antibacterial activity in a single step to knitted cotton fabrics via dyeing with natural dyes. Namık Kemal University, MSc. Thesis, 69p, Tekirdag, Turkey.
• [25] Gawish, S. M., Mashaly, H. M., Helmy, H. M., Ramadan, A. M., Farouk, R. 2017. Effect of mordant on UV protection and antimicrobial activity of cotton, wool, silk and nylon fabrics dyed with some natural dyes. Journal of Nanomedicine & Nanotechnology, 8(1), 1-9.
• [26] Aydin, S. A., Ustun, F. 2007. Tannins 1, Chemical structure, pharmacological effects, analysis methods. Journal of the Faculty of Veterinary Medicine Istanbul University, 33(1), 21-31.
• [27] Colak, S. M., Dandar, U., Kilic, E. 2014. Antioxidant effect of tannic acid on formation of formaldehyde and hexavalent chromium compounds in leather. Tekstil ve Konfeksiyon, 24(1), 105-110.
• [28] Ismal, O. E. 2017. Greener natural dyeing pathway using a by-product of olive oil; prina and biomordants. Fibers and Polymers, 18(4), 773-785.
• [29] Wikipedia. Tannic Acid. https://en.wikipedia.org/wiki/Tannic_acid (Access Date: 24.07.2019).
• [30] X-rite. 2016. A Guide to Understanding Color. https://www.xrite.com/-/media/xrite/files/whitepaper_pdfs/l10-001_a_guide_to_understanding_color_communication/l10-001_understand_color_en.pdf (Access Date: 22.10.2019).