EFFECTS OF NOVEL ANTIBACTERIAL CHEMICALS ON LOW TEMPERATURE PLASMA FUNCTIONALIZED COTTON SURFACE

Yıl 2011, Cilt: 21 Sayı: 4, 356 - 363, 30.12.2011

Buket Arık , Aslı Demir , Esen Özdoğan , Tülay Gülümser

Öz

Since natural fibers are very susceptible to bacterial attacks, various antibacterial finishes have been developed to control the
bacterial growth. Metal and metal salts, quaternary ammonium compounds, N-halamines, chitosan, polybiguanids and halogenated
phenols can be used for antibacterial finishes. On the other hand, plasma treatment has become very popular for improved antibacterial
activity in recent times. In this study, the effect of argon plasma treatment on cotton fabrics before antibacterial finishing process was
investigated. After antibacterial finish process, they were washed up to ten cycles. The antibacterial activities of the washed and
unwashed samples were evaluated according to the AATCC Test Method 147-1998. The surface morphology was characterized by SEM
and FTIR analysis. From the results, it’s observed that plasma application clearly increased the antibacterial activity of the samples and
the most efficient and washing durable antibacterial agent was non-ionic diphenylalkane based chemical agent. From the SEM images,
it’s seen that after argon plasma treatment, the cotton surface has become rougher and more silver particles have been attached to the
surface. This fact was also confirmed by EDX analysis.

Anahtar Kelimeler

Argon plasma, FT-IR, Surface modification, Antibacterial, Cotton

Kaynakça

• 1. Perez Rivera BM., 2006, “Plasma-Aided Antimicrobial and Insect Repellant Finishing of Cotton”, Master Thesis, North Carolina State University, Raleigh, USA.
• 2. Gao Y, and Cranston R., 2008, “Recent Advances in Antimicrobial Treatments of Textiles”, Textile Research Journal, 78 (1), 60-72.
• 3. Simoncic B, and Tomsic B, 2010, “Structures of Novel Antimicrobial Agents for Textiles–A Review”, Textile Research Journal, 80 (16), 1721-1737.
• 4. Monteiro DR, Gorup LF, Takamiya, AS, Ruvollo-Filho AC, Camargo ER, and Barbosa, DB, 2009, “The growing importance of materials that prevent microbial adhesion: antimicrobial effect of medical devices containing silver”, International Journal of Antimicrobial Agents, 34, 103-110.
• 5. Parikh DV, Fink T, Rajasekharan K, Sachinvala, ND, Sawhney APS, Calamari TA, and Parikh AD, 2005, “Antimicrobial Silver/Sodium Carboxymethyl Cotton Dressings for Burn Wounds”, Textile Research Journal, 75 (2), 134-138.
• 6. Orhan M, Kut D, and Gunesoglu C, 2007, “Use of triclosan as antibacterial agent in textiles”, Indian Journal of Fibre&Textile Research, 32, 114-118.
• 7. Orhan M, Kut D, and Gunesoglu C., 2009, “Improving the Antibacterial Activity of Cotton Fabrics Finished with Triclosan by the Use of 1,2,3,4 Butanetetracarboxylic Acid and Citric Acid”, Journal of Applied Polymer Science, 111, 1344–1352.
• 8. Schnopp C, Ring J, and Mempel M., 2010, “The role of antibacterial therapy in atopic eczema”, Expert Opin. Pharmacother., 11 (6), 929-936.
• 9. Weltmann KD, Woedtke ThV, Branderburg R, and Ehlbeck J., 2008, “Biomedical Applications of Atmospheric Pressure Plasma”, Chem. Listy., 102, 1450-1451.
• 10. Karahan HA, and Ozdogan E., 2008, “Improvements of Surface Functionality of Cotton Fibers by Atmospheric Plasma Treatment”, Fibers and Polymers, 9 (1), 21-26.
• 11. Demir A, Karahan HA, Ozdogan E, Oktem T, and Seventekin N., 2008, “The Synergetic Effects of Alternative Methods in Wool Finishing”, Fibres & Textiles in Eastern Europe, 67, 89-94.
• 12. Guimond S, Hanselmann B, Amberg M, and Hegemann D., 2010, “Plasma processing of textiles-perspectives”, Melliand International, 4, 182.
• 13. Ceria A, and Hauser PJ., 2010, “Atmospheric plasma treatment to improve durability of a water and oil repellent finishing for acrylic fabrics”, Surface and Coatings Technology, 204, 1535-1541.
• 14. Morent R, Geyter ND, Verschuren J, Clerck KD, Kiekens P, and Leys C., 2008, “Non-thermal plasma treatment of textiles”, Surface and Coatings Technology, 202, 3427-3449.
• 15. Luciu I, Mitu B, Satulu V, Matei A, and Dinescu G., 2008, “Low and Atmospheric Pressure Plasma Treatment of Natural Textile Fibers”, XXIII-rd Int. Symp. On Discharges and Electrical Insulation in Vacuum-Bucharest.
• 16. Shenton MJ, and Stevens GC., 2001, “Surface modification of polymer surfaces: atmospheric plasma versus vacuum plasma treatments”, J. Phys. D: Appl. Phys., 34, 2761-2768.
• 17. Yang L, Chen J, and Gao J., 2009, “Low temperature argon plasma sterilization effect on Pseudomonas aeruginosa and its mechanisms”, Journal of Electrostatics, 67, 646-651.
• 18. Shahidi S, Rashidi A, Ghoranneviss M, Anvari A, Rahimi MK, Moghaddam MB, and Wiener J., 2010, “Investigation of metal absorption and antibacterial activity on cotton fabric modified by low temperature plasma”, Cellulose, 17, 627-634.
• 19. Inbakumar S, Morent R, Geyter ND, Desmet T, Anukaliani A, Dubruel P, and Leys C., 2010, “Chemical and physical analysis of cotton fabrics plasmatreated with a low pressure DC glow discharge”, Cellulose, 17, 417-426.