Sodyum-iyon Bataryaların Yapısı ve Elektrokimyasal Mekanizmaları
Yıl 2024,
Cilt: 3 Sayı: 1, 58 - 71, 28.05.2024
Esra Balci
,
Sebahat Altundağ
,
Serdar Altın
Öz
Sürdürülebilir ve yenilenebilir enerji depolama sistemleri içerisinde son zamanlarda üzerinde oldukça fazla çalışılan diğer bir alan ise elektrokimyasal enerji depolama sistemleridir (pil ve kapasitör gibi). Talep edilen enerjiyi sağlayabilmek ve güvenirliği en üst düzeye çıkarmak için farklı enerji depolama sistemlerine ihtiyaç duyulmaktadır. Kullanım amaçlarına göre farklı enerji depolama sistemleri mevcuttur. Elektrokimyasal enerji depolama sistemlerinin başında Sodyum (Na) - iyon ve lityum (Li) - iyon bataryalar gelmektedir ve iki grubunda çalışma mekanizmaları birbirine oldukça benzemektedir. Li-iyon bataryalar günümüzde birçok uygulama sisteminde kullanımı yaygın olduğu halde Na-iyon bataryalarında (SIB) benzer açıdan ticarileştirilmesi ve geliştirilmesi amaçlanmaktadır. Bu nedenle, bu çalışmada SIB'lere ilişkin genel bir anlayış sağlamak amacıyla SIB'lerin katot, anot, elektrolitlerine ilişkin genel olarak yapıları ve elektrokimyasal mekanizmaları incelenmektedir.
Kaynakça
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The Structure and Electrochemical Mechanisms of Sodium-ion Batteries
Yıl 2024,
Cilt: 3 Sayı: 1, 58 - 71, 28.05.2024
Esra Balci
,
Sebahat Altundağ
,
Serdar Altın
Öz
Another area that has been studied a lot lately in sustainable and renewable energy storage systems is electrochemical energy storage systems (such as batteries and capacitors). Different energy storage systems are needed to provide the requested energy and maximize reliability. Different energy storage systems are available depending on their intended use. Sodium (Na) - ion and lithium (Li) - ion batteries are the leading electrochemical energy storage systems, and the working mechanisms of both groups are quite similar to each other. Although Li-ion batteries are widely used in many application systems today, it is aimed to commercialize and develop Na-ion batteries (SIB) in a similar way. Therefore, in this review study, in order to provide a general understanding of SIBs, the general structures and electrochemical mechanisms of the cathode, anode, and electrolytes of SIBs are emphasized.
Kaynakça
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- C. Liu, Z. G. Neale, G. Cao, "Understanding electrochemical potentials of cathode materials in rechargeable batteries,” Materials Today, vol. 19, no.2, pp. 109-123, Mar. 2016.
- K. Holmberg, A. Erdemir, "Influence of tribology on global energy consumption, costs and emissions.,” Friction, vol. 5, pp. 263-284, Sep. 2017.
- X.Arqué, T. Patiño, S. Sánchez, "Correction: Enzyme-powered micro-and nano-motors: key parameters for an application-oriented design,” Chemical Science, vol. 13, no. 33, pp. 9784-9786, Jul. 2022.
- R. Usiskin, et al., "Fundamentals, status and promise of sodium-based batteries,” Nature Reviews Materials, vol. 6, no.11, pp. 1020-1035, Jun. 2021.
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- C. Delmas, C. Fouassier, P. Hagenmuller, "Structural classification and properties of the layered oxides,” Physica B+ c, vol. 99, no. 4, pp. 81-85, Jan. 1980.
- M. Sathiya, Q. Jacquet,M.L. Doublet, O.M. Karakulina, J. Hadermann, and J.m. Tarascon, "A chemical approach to raise cell voltage and suppress phase transition in O3 sodium layered oxide electrodes,” Advanced Energy Materials, vol. 8, no.11, pp. 1702599, Jan. 2018.
- P. F. Wang, et al., "Na+/vacancy disordering promises high-rate Na-ion batteries,” Science advances, Vol. 4, no.3, pp. 6018, Mar. 2018.
- C. Delmas, J. J. Braconnier, C. Fouassier and P. Hagenmuller, "Electrochemical intercalation of sodium in NaxCoO2 bronzes,” Solid State Ionics, vol. 3, no. 4, pp. 165-169, Aug. 1981.
- S. Komaba, C. Takei, T. Nakayama, A. Ogata and N. Yabuuchi, "Electrochemical intercalation activity of layered NaCrO2 vs. LiCrO2,” Electrochemistry Communications, vol. 12, no.3, pp. 355-358, Mar. 2010.
- S. Komaba, et al.,"Electrochemically reversible sodium intercalation of layered NaNi0. 5Mn0. 5O2 and NaCrO2,” Ecs Transactions, vol. 16, no.42, pp.43, Jun. 2009.
- J. P. Parant, R. Olazcuaga, M. Devalette, C. Fouassier and P.Hagenmuller, "Sur quelques nouvelles phases de formule NaxMnO2 (x⩽ 1),” Journal of Solid State Chemistry, vol. 3, no.1, pp. 1-11. Feb. 1971.
- L. Mu, et al.,"Prototype sodium‐ion batteries using an air‐stable and Co/Ni‐free O3‐layered metal oxide cathode,” Advanced Materials, vol. 27, no.43, pp. 6928-6933, Oct. 2015.
- A. Ramesh, A. Tripathi and P. Balaya, "A mini review on cathode materials for sodium‐ion batteries,” International Journal of Applied Ceramic Technology, vol. 19, no. 2, pp. 913- 923, Sep. 2022.
- S. H. Bo, X. Li, A. J. Toumar and G. Ceder, "Layered-to-rock-salt transformation in desodiated Na x CrO2 (x 0.4),” Chemistry of Materials, vol. 28, no. 5, pp. 1419-1429, Feb. 2016.
- M. Kalapsazova, et al.,"P3‐Type layered sodium‐deficient nickel–manganese oxides: a flexible structural matrix for reversible sodium and lithiumintercalation,” ChemPlusChem, vol. 80, no. 11, pp. 1642-1656, Jul. 2015.
- E. J. Kim, et al.,"Oxygen redox activity through a reductive coupling mechanism in the P3-type nickel-doped sodium manganese oxide,” ACS Applied Energy Materials, vol. 3, no.1, pp. 184-191, Dec. 2019.
- J. Liu, et al., "Elucidation of the high-voltage phase in the layered sodium ion battery cathode material P3–Na 0.5 Ni 0.25 Mn 0.75 O2,” Journal of Materials Chemistry A, vol. 8, no. 40, pp. 21151-21162, Sep. 2020.
- Y. H. Jung, A. S. Christiansen, R. E. Johnsen, P. Norby and D.K. Kim, "In situ X‐ray diffraction studies on structural changes of a p2 layered material during electrochemical desodiation/sodiation,” Advanced Functional Materials, vol. 25 no. 21, pp. 3227-3237, Apr. 2015.
- X. Bai, et al.,"Anionic redox activity in a newly Zn‐doped sodium layered oxide P2‐Na2/3Mn1− yZnyO2 (0< y< 0.23),” Advanced Energy Materials C, vol. 8, no. 32, pp. 1802379, Oct. 2018.
- X. Chen, J. Song, J. Li, H. Zhang and H. Tang, "A P2/P3 composite-layered cathode material with low-voltage decay for sodium-ion batteries,” Journal of Applied Electrochemistry, vol. 51, pp. 619-627, Jan. 2021.
- C. Sun, et al.,"Construction of the Na0. 92Li0. 40Ni0. 73Mn0. 24Co0. 12O2 sodium-ion cathode with balanced high-power/energy-densities,” Energy Storage Materials, vol. 27, no. 1, pp. 252-260, May 2020.
- H. Wang, A. Tang and K. Huang, "Oxygen evolution in overcharged LixNi1/3Co1/3Mn1/3O2 electrode and its thermal analysis kinetics,” Chinese Journal of Chemistry, vol. 29, no. 8, pp. 1583-1588, Aug. 2011.
- J. Y. Hwang, S. T. Myung and Y. K. Sun, "Sodium-ion batteries: present and future,” Chemical Society Reviews, vol. 46, no. 12, pp. 3529-3614, Mar. 2017.
- Z. Jian, Y. S. Hu, X. Ji and W. Chen, "Nasicon‐structured materials for energy storage,” Advanced Materials, vol. 29, no. 20, pp. 1601925, Feb. 2017.
- W. Luo, et al., "Low-surface-area hard carbon anode for Na-ion batteries via graphene oxide as a dehydration agent,” ACS applied materials & interfaces, vol. 7, no. 4, pp. 2626--2631, Jan. 2015.
- M. M. Doeff, Y. Ma, S. J. Visco and L. C. De Jonghe, "Electrochemical insertion of sodium into carbon,” Journal of the Electrochemical Society, vol. 140 ,no. 12, pp. L169, Oct. 1993.
- R. Alcántara, J. J. Mateos and J. Tirado, "Negative electrodes for lithium-and sodium-ion batteries obtained by heat-treatment of petroleum cokes below 1000 C,” Journal of the Electrochemical Society, vol. 149, no. 2, pp. A20, Jan. 2002.
- R. Alcántara, G. F. Ortiz, P. Lavela, J. L. Tirado, R. Stoyanova, and E. Zhecheva, "EPR, NMR, and electrochemical studies of surface-modified carbon microbeads,” Chemistry of Materials, vol. 18, no. 9, pp. 2293-2301, Mar. 2006.
- D. Callegari, "New materials for electrochemical energy storage: advanced lithium ion batteries and beyond,” Phd thesis, University of Pavia, Mar. 2021.
- L. Zeng, W. Li, J. Cheng, J. Wang, X. Liu and Y. Yu, " N-doped porous hollow carbon nanofibers fabricated using electrospun polymer templates and their sodium storage properties,” RSC advances, vol. 4, no.33 , pp. 16920-16927, Feb. 2014.
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