POMZA VE GOMALAK İÇEREN SOLVENT BAZLI BOYALAR ÜZERİNE YENİ BİR ARAŞTIRMA

Yıl 2018, Cilt: 23 Sayı: 2, 87 - 96, 31.08.2018

Nil Acaralı

https://doi.org/10.17482/uumfd.297817

Öz

Bu
çalışmada; inşaat ve kimya sektöründe kullanılmak üzere solvent bazlı boyaya
çeşitli katkı maddeleri eklenerek fiziksel özelliklerin geliştirilmesi ve
dekoratif amaçlı olarak kullanılması hedeflenmiştir. Yapılan çalışmada
viskozite, parlaklık, kapatıcılık, hidrofobiklik ve kuruma süresi gibi farklı
fiziksel testler uygulanmıştır. Optimizasyon metodu olarak, Taguchi metodu
kullanılmış ve FT-IR cihazı ile moleküler bağ karakterizasyonu incelenmiştir.
Burada, gomalağın metal yüzeylerde koruma sağladığı ve pomzanın ise yapışma
özelliğini arttırdığı gözlemlenmiştir. Yapılan testler sonucunda kullanılan
katkıların, parlaklık, renk uygunluğu ve kuruma süresine olumsuz bir etkisinin
olmadığı gözlenmiştir. Referans boyaya kıyasla, hazırlanan boyaların
hidrofobikliği ve kapatıcılığı arttırıcı etkisinin olduğu gözlemlenmiştir.
Deneylerin FT-IR spektrumları incelendiğinde ise referans boyayla benzer bağ
karakterizasyonu olduğu gözlemlenmiştir.

Anahtar Kelimeler

Boya, Solvent, Taguchi, FT-IR

A Novel Survey on Solvent Based-Dyes Containing Shellac and Pumice

Öz

This study aimed the dyes as decorative usage
and improving the physical properties by using solvent based-dye with additives
to evaluate in construction and chemical applications. The physical tests as
viscosity, hydrophobicity, drying time, gloss effect, hiding power/transparency
were applied on surfaces. Taguchi Method was used as an optimization method and
characterization of molecular bonds was investigated with FT-IR. Shellac was
used for protection of metallic surfaces and pumice increased the adhesive
effect of dye. The test results showed that the additives did not affect the
glossiness, color availability and drying time as a negative result. When the
prepared dyes compared reference dyes, it was seen that hydrophobicity and
hiding power/transparency effects were increased. FT-IR spectra showed that the
prepared dyes had similar bonds with reference dyes.

Anahtar Kelimeler

Dye, Solvent, Taguchi, FT-IR

Kaynakça

• Altinsoy A.R. and Caliskan, S. (2014) Investigation of thermal and physical properties for construction dyes containing different boron chemicals and shellac, Yildiz Technical University, Istanbul.
• Bayrak, Z. (1996) Applying Taguchi method in the shield of practising quality control, MSc Thesis. Kocaeli University, Kocaeli.
• Byrappa, K. and Suresh Kumar B.V. (2007) Characterization of zeolites by infrared spectroscopy, Asian Journal of Chemistry, 19(6), 4933-4935.
• Canıyılmaz, E. (2001) Taguchi method in quality improvement and an application, MSc Thesis. Gazi University, Ankara.
• Durgun, Z.G. (2010) Çeşitli Kalsiyum Boratların Sentezi Karakterizasyonu ve Alev Geciktirici Etkinliklerinin İncelenmesi, MSc Thesis. Ankara University.
• http://ec.europa.eu/environment/air/pollutants/stationary/paints/paints_legis.htm, Accessed Date: 12.01.2017.
• Kalafatoğlu, İ.E. and Örs, S.N. (2003) 21. yüzyılda bor teknolojileri ve uygulamaları, BAÜ Fen Bilimleri Enstitüsü Dergisi, 5(1), 59-71.
• Kocadagistan, B. and Kocadagistan, E. (2016) Batch and column removal of the dye blue 3R over pumice, Desalination and Water Treatment, 57(58), 28042-28055. doi: 10.1080/19443994.2016.1184186
• Kowalczyk, K., Łuczka, K., Grzmil, B. and Spychaj, T. (2013) Anticorrosive 2K polyurethane paints based on nano and microphosphates with high dispersing additive content, Progress in Organic Coatings, 76, 1088–1094. doi: 10.1016/j.porgcoat.2013.03.003
• Kucuk, M. and Kocakerim, M. (2005) Optimization of dissolution of ulexite in water saturated with sulphur dioxide, Chemical Engineering and Processing, 44(9), 1005-1011. doi: 10.1016/j.cep.2004.11.006
• Kul, A.R., Benek, V., Selçuk, A. and Onursal, N. (2017) Using natural stone pumice in Van region on adsorption of some textile dyes, 4 (2), 525-536. doi: 10.18596/jotcsa.292662
• Kymalainen, H.R. and Sjöberg, A.M. (2008) Flax and hemp fibres as raw materials for thermal insulations, Building and Environment, 43, 1261-1270. doi: 10.1016/j.buildenv.2007.03.006
• Law, C., Pathirana, S.C., Li, X., Anderson, A.Y., Barnes, P.R.F., Listorti, A., Ghaddar, T.H. and O′Regan, B.C. (2010) Water-based electrolytes for dye-sensitized solar cells, Advanced Materials, 22(40), 4505-4509. doi: 10.1002/adma.201001703
• Mergen, A., Demirhan, M.H. and Bilen, M. (2003) Processing of boric acid from borax by a wet chemical method, Advanced Powder Technology, 14, 279-293. doi: 10.1163/15685520360685947
• Moreno, M., Lampard, C., Williams, N., Lago, E., Emmett, S., Goikoetxea, M. and Barandiaran, M.J. (2015) Eco-paints from bio-based fatty acid derivative latexes, Progress in Organic Coatings, 81, 101–106. doi: 10.1016/j.porgcoat.2015.01.001
• Nakajima, A., Hashimoto, K. and Watanabe, T. (2001) Recent studies on super-hydrophobic films, Monatshefte fur Chemie, 132, 31-41.
• Ozturk Akbal, F., Akdemir, N. and Nur Onar, A. (2000) FT-IR spectroscopic detection of pesticide after sorption onto modified pumice, Talanta, 53(1), 131-135.
• Ozturk, A.B. (2015) Investigation of thermal and physical properties for construction dyes containing different boron chemicals and shellac, MSc Thesis. Yildiz Technical University, Istanbul.
• Panyakaew, S. and Fotios, S. (2011) New thermal insulation boards made from coconut husk and bagasse, Energy Buildings, 43, 1732-1739. doi: 10.1016/j.enbuild.2011.03.015
• Pizzi, A. and Mittal, K.L. (2003) Handbook of Adhesive Technology, Second Edition, Revised and Expanded, USA.
• Seclaman, E., Sallo, A., Elenes, F., Crasmareanu, C., Wikete, C., Timofei, S. and Simon, Z. (2002) Hydrophobicity, protolytic equilibrium and chromatographic behaviour of some monoazoic dyes, Dyes and Pigments, 55, 69–77.
• Singaravel, B. and Selvaraj, T. (2016) Application of Taguchi method for optimization of parameters in turning operation, Journal for Manufacturing Science and Production, 16(3), 1-5.
• Stoye, D. and Freitag, W. (1998) Paints, coatings and solvents, Second Edition, Wiley-VCH.
• Vankantia, V.K and Ganta, V.J. (2014) Optimization of Process parameters in drilling of GFRP composite using Taguchi method, Journal of Materials Research and Technology, 3(1), 35-41. doi: 10.1016/j.jmrt.2013.10.007
• Varhegyi, G., Szabo, P., Till, F. and Zelei, B. (1998) TG, TG-MS and FTIR characterization of high-yield biomass charcoals, Energy Fuels, 12, 969-974. doi: 10.1021/ef9800359
• Veliev, E.V., Öztürk, T., Veli, S. and Fatullayev, A.G. (2006) Application of Diffusion Model for Adsorption of Azo Reactive Dye on Pumice, Polish Journal of Environmental Studies, 15 (2), 347-353.
• Woods, W.G. (1994) An introduction to boron: history, sources, uses, and chemistry, Environmental Health Perspectives, 102, 5-11. doi: 10.1289/ehp.94102s75