Unique fatty acid composition of coriander seed biodiesel
Year 2024,
Volume: 13 Issue: 3, 114 - 122, 30.09.2024
Suleyman Simsek
,
Esra Koç
,
Ayşegül Öztürk
Abstract
Biodiesel is a renewable and environmentally friendly alternative fuel that can be used in diesel engines without modification. In this study, biodiesel production from coriander seed oil obtained through a two-stage transesterification process using the cold pressing method was carried out in the Konya region. First, the oil's acid value was reduced through acid-catalyzed pretreatment to form coriander seed oil methyl esters, and then biodiesel was produced using standard transesterification with methanol and sodium methoxide catalyst.
Coriander (Coriandrum sativum) contains an unusual fatty acid not previously reported as a major component in biodiesel fuels: petroselinic acid (6Z-octadecenoic acid; 68.5% by weight).
Coriandrum sativum seed oil methyl ester was evaluated to have properties suitable for diesel engines, complying with EN 14214 and ASTM D6751 standards, with a unique fatty acid composition and excellent oxidative stability.
References
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- Uğuz, G., Atabani, AE, Mohammed, MN, Shobana, S., Uğuz, S., Kumar, G., & Ala'a, H., "Fuel stability of biodiesel from waste cooking oil: A comparative evaluation with various antioxidants using FT-IR and DSC techniques", Biocatalysis and Agricultural Biotechnology, 21, 101283, 2019.
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- Kafuku, G., M. Mbarawa, "Biodiesel production from Croton megalocarpus oil and its process optimization", Fuel, 89, 9, 2556-2560, 2010.
- Sayyed, S., Das, R. K., & Kulkarni, K., "Experimental investigation for evaluating the performance and emission characteristics of DICI engine fueled with dual biodiesel-diesel blends of Jatropha, Karanja, Mahua, and Neem", Energy, 238, 121787, 2022.
- Vilas Bôas, R.N., M.F. Mendes, "A review of biodiesel production from non-edible raw materials using the transesterification process with a focus on influence of feedstock composition and free fatty acids", Journal of the Chilean Chemical Society, 67, 1, 5433-5444, 2022.
- Moser, B.R., "Biodiesel production, properties, and feedstocks", In Vitro Cellular & Developmental Biology-Plant, 45, 229-266, 2009.
- Uslu, S., Simsek, S., Simsek, H., "RSM modeling of different amounts of nano-TiO2 supplementation to a diesel engine running with hemp seed oil biodiesel/diesel fuel blends", Energy, 266, 126439, 2023.
- Simsek, S., S. Uslu, Simsek, H., "Assessment of the fuel recovery potential of cattle, sheep, and chicken waste fats in diesel engine. International Journal of Environmental Science and Technology", 19, 11, 11409-11420, 2022.
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- Orege, J. I., Oderinde, O., Kifle, G. A., Ibikunle, A. A., Raheem, S. A., Ejeromedoghene, O., Daramola, M. O., "Recent advances in heterogeneous catalysis for green biodiesel production by transesterification", Energy Conversion and Management, 258, 115406, 2022.
- Mahmudul, H. M., Hagos, F. Y., Mamat, R., Adam, A. A., Ishak, W. F. W., & Alenezi, R., "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines A review", Renewable and Sustainable Energy Reviews, 72, 497-509, 2017.
- Bhatia, S. K., Bhatia, R. K., Jeon, J. M., Pugazhendhi, A., Awasthi, M. K., Kumar, D., Yang, Y. H., ""An overview on advancements in biobased transesterification methods for biodiesel production: Oil resources, extraction, biocatalysts, and process intensification technologies", Fuel, 285, 119117, 2021.
- Cao, H., Zhang, Z., Wu, X., Miao, X., Direct biodiesel production from wet microalgae biomass of Chlorella pyrenoidosa through in situ transesterification", BioMed research international, 2013.
- De Jesus, S. S., Ferreira, G. F., Moreira, L. S., Maciel Filho, R., "Biodiesel production from microalgae by direct transesterification using green solvents", Renewable Energy, 160, 1283-1294, 2020.
- Astm, D., Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels. ASTM International, West Conshohocken, 2012.
- Alves, C.T., Peters, M.A., Onwudili, J.A., "Application of thermogravimetric analysis method for the characterisation of products from triglycerides during biodiesel production", Journal of Analytical and Applied Pyrolysis, 168, 105766, 2022.
- Çakmak, A., "Üretilen farklı yakıt katkılarıyla bir dizel motorunun yanma, performans ve emisyon karakteristiklerinin iyileştirilmesinin deneysel incelenmesi", 2021.
- Şanlı, H., Yaşar F., "An Investigation on Fatty Acid Compositions of Three-Generation Biodiesel Fuels", Journal of the Turkish Chemical Society Section B: Chemical Engineering, 5, 2, 195-202, 2022.
- Alpgiray, B., Gürhan R., ""Kanola yağının diesel motorunun performansına ve emisyon karakteristiklerine etkilerinin belirlenmes", Journal of Agricultural Sciences, 13, 03, 231-239, 2007.
- Balo, F., Kurtbaş, İ., Yücel, H.L., "Bitkisel yağlarin dizel yakit özellikleri", Fırat Üniversitesi Doğu Araştırmaları Dergisi, 5, 1, 1-6, 2006.
- Beycar Kafadar, A., "Yağlardan biyodizel eldesine etki eden faktörlerin araştırılması", 2010.
- Knothe, G., "Improving biodiesel fuel properties by modifying fatty ester composition", Energy & Environmental Science, 2, 7, 759-766, 2009.
- Asgarpanah, J., N. Kazemivash, "Phytochemistry, pharmacology and medicinal properties of Coriandrum sativum L.", Afr J Pharm Pharmacol, 6, 31, 2340-2345, 2012.
- Nadeem, M., Muhammad Anjum, F., Issa Khan, M., Tehseen, S., El‐Ghorab, A., & Iqbal Sultan, J., "Nutritional and medicinal aspects of coriander (Coriandrum sativum L.) A review", British Food Journal, 115, 5, 743-755, 2013.
- Momin, A.H., S.S. Acharya, A.V. Gajjar, ""Coriandrum sativum-review of advances in phytopharmacolog", International Journal of Pharmaceutical Sciences and Research, 3, 5, 1233, 2012.
- Ulutaş Deniz, E. L. İ. F., Yeğenoğlu, S., SÖZEN ŞAHNE, B. İ. L. G. E., & Gençler Özkan, A., "Kişniş (Coriandrum sativum L.) üzerine bir derlem", Marmara Pharmaceutical Journal, 22, 1, 2018.
- Bayrak, A., M. Korkut, "Bazı Tohum Yağlarının (Umbelliferae) Yağ Asidi Kompozisyonu ve Özellikle Petroselinik Asit Miktarları Üzerinde Araştırma", II. Standard, 400, 120-126, 1995.
- Mahleyuddin, NN, Moshawih, S., Ming, LC, Zulkifly, HH, Kifli, N., Loy, MJ, ... & Goh, HP, "Coriandrum sativum L.: A review on ethnopharmacology, phytochemistry, and cardiovascular benefits", Molecules, 27, 1, 209, 2021.
- Emamghoreishi, M., M. Khasaki, M.F. Aazam, "Coriandrum sativum: evaluation of its anxiolytic effect in the elevated plus-maze", Journal of ethnopharmacology, 96, 3, 365-370, 2005.
- Laribi, B., Kouki, K., M'Hamdi, M. ve Bettaieb, T., "Coriander (Coriandrum sativum L.) and its bioactive constituents", Fitoterapia, 103, 9-26, 2015.
- Tunçtürk, M., "Kişniş (Coriandrum Sativum L.) bitkisinde farkli tohumluk miktarlarinin verim, verim özellikleri ve uçucu yağ orani üzerine etkisi", Selcuk Journal of Agriculture and Food Sciences, 20, 39, 58-62, 2006.
- Barros, L., Duenas, M., Dias, M. I., Sousa, M. J., Santos-Buelga, C., & Ferreira, I. C., "Phenolic profiles of in vivo and in vitro grown Coriandrum sativum L", Food Chemistry, 132, 2, 841-848, 2012.
- Hu, J., Wu, X., Wu, F., Chen, W., White, JC, Yang, Y., Wang, X., "Potential application of titanium dioxide nanoparticles to improve the nutritional quality of coriander (Coriandrum sativum L.)", Journal of hazardous materials, 389, 121837, 2020.
- Uhl, S.R., Handbook of spices, seasonings and flavorings, CRC Press, 2000.
- Moser, B.R., Vaughn, S.F., "Coriander seed oil methyl esters as biodiesel fuel: unique fatty acid composition and excellent oxidative stability", Biomass and bioenergy, 34, 4, 550-558, 2010.
- Pahl, G., "Biodiesel: growing a new energy economy", Chelsea Green Publishing, 2008.
- Knothe, G., Sharp, C.A. Ryan, T.W., "Exhaust emissions of biodiesel, petrodiesel, neat methyl esters, and alkanes in a new technology engine", Energy & fuels, 20, 1, 403-408, 2006.
Year 2024,
Volume: 13 Issue: 3, 114 - 122, 30.09.2024
Suleyman Simsek
,
Esra Koç
,
Ayşegül Öztürk
References
- Gupta, N., K. Singh, "Experimental Investigation on the Performance of an Engine Operated with Multi Fuel Blends of Biodiesels Made by Animal Fat & Mahua Oil, Ethanol & Diesel", Efflatounia-Multidisciplinary Journal, 5, 1, 2021.
- Atabani, Abdelaziz E, Arridina S Silitonga, Irfan Anjum Badruddin, TMI Mahlia, HHm Masjuki, and Saad Mekhilef, "A comprehensive review on biodiesel as an alternative energy resource and its characteristics", Renewable and sustainable energy reviews, 16, 4, 2070-2093, 2012.
- Janaun, J. and N. Ellis, "Perspectives on biodiesel as a sustainable fuel", Renewable and Sustainable Energy Reviews, 4, 4, 1312-1320, 2010.
- Shahid, E.M., Y. Jamal, "Production of biodiesel: a technical review", Renewable and Sustainable Energy Reviews, 15, 9, 4732-4745, 2011.
- Büyükoğlu, Muhammet, Tuba Hatice Doğan, Orhan Arpa, Hayrunnisa Nadaroğlu, and İlhan Volkan Öner, "Experimental investigation of engine performance and emissions, and characterization, of waste transformer oils and diesel blends with biodiesel produced from olive oil wastes in a CI engine", Journal of Thermal Analysis and Calorimetry, 2024.
- Koç, M., "Biyodizel üretimine uygun Türkiye'de yetişen ve yetişebilecek bitkilerin ve biyodizel teknolojilerinin belirlenmesi", 2011.
- Chidambaram, PK, Dr Amol Lokhande, Dr M Ramachandran, Vimala Saravanan, and Vidhya Prasanth, "A Review on Biodiesel Properties and Fatty acid composites", Rest Journal on Emerging trends in Modelling andManufacturing, 7, 3, 87-93, 2021.
- Atabani, A.E., O.K. Al-Rubaye, "Valorization of spent coffee grounds for biodiesel production: blending with higher alcohols, FT-IR, TGA, DSC, and NMR characterizations", Biomass Conversion and Biorefinery, 12, 3, 577-596, 2022.
- Anand, K., R. Sharma, P. Mehta, "Experimental investigations on combustion, performance, and emissions characteristics of a neat biodiesel-fuelled, turbocharged, direct injection diesel engine", Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering, 224, 5, 661-679, 2010.
- Athar, M., S. Zaidi, "A review of the feedstocks, catalysts, and intensification techniques for sustainable biodiesel production", Journal of Environmental Chemical Engineering, 8, 6, 104523, 2020.
- Dhivya Priya, N., M. Thirumarimurugan, "Biodiesel a review on recent advancements in production", Bioresource Utilization and Bioprocess, 117-129, 2020.
- Uğuz, G., Atabani, AE, Mohammed, MN, Shobana, S., Uğuz, S., Kumar, G., & Ala'a, H., "Fuel stability of biodiesel from waste cooking oil: A comparative evaluation with various antioxidants using FT-IR and DSC techniques", Biocatalysis and Agricultural Biotechnology, 21, 101283, 2019.
- Ahmad, A. L., Yasin, N. M., Derek, C. J. C., & Lim, J. K., "Microalgae as a sustainable energy source for biodiesel production: a review", Renewable and sustainable energy reviews, 15, 1, 584-593, 2011.
- Kafuku, G., M. Mbarawa, "Biodiesel production from Croton megalocarpus oil and its process optimization", Fuel, 89, 9, 2556-2560, 2010.
- Sayyed, S., Das, R. K., & Kulkarni, K., "Experimental investigation for evaluating the performance and emission characteristics of DICI engine fueled with dual biodiesel-diesel blends of Jatropha, Karanja, Mahua, and Neem", Energy, 238, 121787, 2022.
- Vilas Bôas, R.N., M.F. Mendes, "A review of biodiesel production from non-edible raw materials using the transesterification process with a focus on influence of feedstock composition and free fatty acids", Journal of the Chilean Chemical Society, 67, 1, 5433-5444, 2022.
- Moser, B.R., "Biodiesel production, properties, and feedstocks", In Vitro Cellular & Developmental Biology-Plant, 45, 229-266, 2009.
- Uslu, S., Simsek, S., Simsek, H., "RSM modeling of different amounts of nano-TiO2 supplementation to a diesel engine running with hemp seed oil biodiesel/diesel fuel blends", Energy, 266, 126439, 2023.
- Simsek, S., S. Uslu, Simsek, H., "Assessment of the fuel recovery potential of cattle, sheep, and chicken waste fats in diesel engine. International Journal of Environmental Science and Technology", 19, 11, 11409-11420, 2022.
- Rezania, S., Oryani, B., Park, J., Hashemi, B., Yadav, K. K., Kwon, E. E., Cho, J., "Review on transesterification of non-edible sources for biodiesel production with a focus on economic aspects, fuel properties and by-product applications", Energy Conversion and Management, 201, 112155, 2019.
- Orege, J. I., Oderinde, O., Kifle, G. A., Ibikunle, A. A., Raheem, S. A., Ejeromedoghene, O., Daramola, M. O., "Recent advances in heterogeneous catalysis for green biodiesel production by transesterification", Energy Conversion and Management, 258, 115406, 2022.
- Mahmudul, H. M., Hagos, F. Y., Mamat, R., Adam, A. A., Ishak, W. F. W., & Alenezi, R., "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines A review", Renewable and Sustainable Energy Reviews, 72, 497-509, 2017.
- Bhatia, S. K., Bhatia, R. K., Jeon, J. M., Pugazhendhi, A., Awasthi, M. K., Kumar, D., Yang, Y. H., ""An overview on advancements in biobased transesterification methods for biodiesel production: Oil resources, extraction, biocatalysts, and process intensification technologies", Fuel, 285, 119117, 2021.
- Cao, H., Zhang, Z., Wu, X., Miao, X., Direct biodiesel production from wet microalgae biomass of Chlorella pyrenoidosa through in situ transesterification", BioMed research international, 2013.
- De Jesus, S. S., Ferreira, G. F., Moreira, L. S., Maciel Filho, R., "Biodiesel production from microalgae by direct transesterification using green solvents", Renewable Energy, 160, 1283-1294, 2020.
- Astm, D., Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels. ASTM International, West Conshohocken, 2012.
- Alves, C.T., Peters, M.A., Onwudili, J.A., "Application of thermogravimetric analysis method for the characterisation of products from triglycerides during biodiesel production", Journal of Analytical and Applied Pyrolysis, 168, 105766, 2022.
- Çakmak, A., "Üretilen farklı yakıt katkılarıyla bir dizel motorunun yanma, performans ve emisyon karakteristiklerinin iyileştirilmesinin deneysel incelenmesi", 2021.
- Şanlı, H., Yaşar F., "An Investigation on Fatty Acid Compositions of Three-Generation Biodiesel Fuels", Journal of the Turkish Chemical Society Section B: Chemical Engineering, 5, 2, 195-202, 2022.
- Alpgiray, B., Gürhan R., ""Kanola yağının diesel motorunun performansına ve emisyon karakteristiklerine etkilerinin belirlenmes", Journal of Agricultural Sciences, 13, 03, 231-239, 2007.
- Balo, F., Kurtbaş, İ., Yücel, H.L., "Bitkisel yağlarin dizel yakit özellikleri", Fırat Üniversitesi Doğu Araştırmaları Dergisi, 5, 1, 1-6, 2006.
- Beycar Kafadar, A., "Yağlardan biyodizel eldesine etki eden faktörlerin araştırılması", 2010.
- Knothe, G., "Improving biodiesel fuel properties by modifying fatty ester composition", Energy & Environmental Science, 2, 7, 759-766, 2009.
- Asgarpanah, J., N. Kazemivash, "Phytochemistry, pharmacology and medicinal properties of Coriandrum sativum L.", Afr J Pharm Pharmacol, 6, 31, 2340-2345, 2012.
- Nadeem, M., Muhammad Anjum, F., Issa Khan, M., Tehseen, S., El‐Ghorab, A., & Iqbal Sultan, J., "Nutritional and medicinal aspects of coriander (Coriandrum sativum L.) A review", British Food Journal, 115, 5, 743-755, 2013.
- Momin, A.H., S.S. Acharya, A.V. Gajjar, ""Coriandrum sativum-review of advances in phytopharmacolog", International Journal of Pharmaceutical Sciences and Research, 3, 5, 1233, 2012.
- Ulutaş Deniz, E. L. İ. F., Yeğenoğlu, S., SÖZEN ŞAHNE, B. İ. L. G. E., & Gençler Özkan, A., "Kişniş (Coriandrum sativum L.) üzerine bir derlem", Marmara Pharmaceutical Journal, 22, 1, 2018.
- Bayrak, A., M. Korkut, "Bazı Tohum Yağlarının (Umbelliferae) Yağ Asidi Kompozisyonu ve Özellikle Petroselinik Asit Miktarları Üzerinde Araştırma", II. Standard, 400, 120-126, 1995.
- Mahleyuddin, NN, Moshawih, S., Ming, LC, Zulkifly, HH, Kifli, N., Loy, MJ, ... & Goh, HP, "Coriandrum sativum L.: A review on ethnopharmacology, phytochemistry, and cardiovascular benefits", Molecules, 27, 1, 209, 2021.
- Emamghoreishi, M., M. Khasaki, M.F. Aazam, "Coriandrum sativum: evaluation of its anxiolytic effect in the elevated plus-maze", Journal of ethnopharmacology, 96, 3, 365-370, 2005.
- Laribi, B., Kouki, K., M'Hamdi, M. ve Bettaieb, T., "Coriander (Coriandrum sativum L.) and its bioactive constituents", Fitoterapia, 103, 9-26, 2015.
- Tunçtürk, M., "Kişniş (Coriandrum Sativum L.) bitkisinde farkli tohumluk miktarlarinin verim, verim özellikleri ve uçucu yağ orani üzerine etkisi", Selcuk Journal of Agriculture and Food Sciences, 20, 39, 58-62, 2006.
- Barros, L., Duenas, M., Dias, M. I., Sousa, M. J., Santos-Buelga, C., & Ferreira, I. C., "Phenolic profiles of in vivo and in vitro grown Coriandrum sativum L", Food Chemistry, 132, 2, 841-848, 2012.
- Hu, J., Wu, X., Wu, F., Chen, W., White, JC, Yang, Y., Wang, X., "Potential application of titanium dioxide nanoparticles to improve the nutritional quality of coriander (Coriandrum sativum L.)", Journal of hazardous materials, 389, 121837, 2020.
- Uhl, S.R., Handbook of spices, seasonings and flavorings, CRC Press, 2000.
- Moser, B.R., Vaughn, S.F., "Coriander seed oil methyl esters as biodiesel fuel: unique fatty acid composition and excellent oxidative stability", Biomass and bioenergy, 34, 4, 550-558, 2010.
- Pahl, G., "Biodiesel: growing a new energy economy", Chelsea Green Publishing, 2008.
- Knothe, G., Sharp, C.A. Ryan, T.W., "Exhaust emissions of biodiesel, petrodiesel, neat methyl esters, and alkanes in a new technology engine", Energy & fuels, 20, 1, 403-408, 2006.