Spectroscopic, Thermal And Electrochemical Properties of 2,2’-Dipyridine Containing Copper(II) Methacrylate Complex

Year 2016, Volume: 6 Issue: 14, 77 - 88, 15.12.2016

Zuhal Yolcu , Saim Topçu Murat Yolcu Ömer Andaç

Abstract

In this work, [Cu(maa)2(H2O)(dipy)] complex has been synthesized by using methacrylate and 2,2’- dipyridine ligands. Magnetic, spectroscopic (IR and UV-Vis.) and thermal (TG, DTG and DTA) properties of the complex have been investigated. Electrochemical behaviours of the complex has been studied by SW and CV in order to determine the catalytic property of the complex. Reversible peaks, were observed in the CVs of the [Cu(maa)2(H2O)(dipy)] complex has indicated that the complex is electroactive.

Keywords

Copper(II) carboxylate, methacrylate complex, 2,2’-dipyridine, square wave voltammetry, cyclic voltammetry

2,2’-Dipiridin Ligandı İçeren Bakır(II) Metakrilat Kompleksinin Spektroskopik, Termal ve Elektrokimyasal Özellikleri

Abstract

Bu çalışmada,
metakrilat (maa) ve 2,2-dipiridin (dipy) ligantları kullanılarak [Cu(maa)₂(H₂O)(dipy)]
kompleksi sentezlendi. Kompleksin manyetik, spektroskopik (UV-Vis. ve IR) ve
termal (TG, DTG ve DTA) özellikleri incelendi. [Cu(maa)₂(H₂O)(dipy)]
kompleksinin katalitik özelliğinin belirlenebilmesi için elektrokimyasal davranışı;
kare dalga (SW) voltametrisi ve dönüşümlü voltametri (CV)
teknikleri kullanılarak araştırıldı. [Cu(maa)₂(H₂O)(dipy)]
kompleksinin CV’ larında gözlenen tersinir piklerden kompleksin elektroaktif
olduğu belirlendi.   

Keywords

Bakır(II) karboksilat, metakrilat kompleks, kare dalga voltametrisi, dönüşümlü voltametri, 2.2’-dipiridin

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