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Origin, Geochemistry and Sulfur Isotope Ratios of Pb-Zn-Cu Mineralization between Karadoru and Karaköy (Biga Peninsula, Çanakkale)

Year 2024, Volume: 67 Issue: 3, 361 - 388, 31.08.2024

Didem Kıray , Mustafa Kuşcu , Oya Cengiz

https://doi.org/10.25288/tjb.1369277

Abstract

This study aims to investigate the geochemistry and sulfur isotope ratios, as well as the origin of Pb-Zn-Cu mineralization, between Karadoru (Biga, Çanakkale) and Karaköy (Yenice, Çanakkale) in the Biga Peninsula (NW Turkey). Mineralization was observed at four locations: Karadoru, Peynirderesi, Madençeşme (Biga, Çanakkale) and Karaköy (Yenice, Çanakkale). The lowest tectonostratigraphic unit in the region is the Karakaya Complex. The Nilüfer unit, which is part of the Karakaya Complex and mainly consists of metabasic rocks, is overlain by the Hodul unit. The Hodul unit comprises limestones, spilitic basalt, diabase, and arkosic sandstones. The Karadoru, Sarıçayır, and Soğucak granitoids, which are Oligocene-Miocene in age, cut through units of the Karakaya Complex. Skarn zones developed in locations where many plutonic masses intersect with the units of the Karakaya Complex (Nilüfer and Hodul). The Çan volcanics, which date back to the Miocene era, are found on top of the Karadoru, Sarıçayır, and Soğucak granitoid rocks. The Pb-Zn-Cu mineralizations were deposited as veins in the Nilüfer unit (epimetamorphics) in the Karadoru and Madençeşme locations within the Karakaya Complex, and in the Hodul unit (metadiabase and crystallized limestone) in the Peynirderesi and Karaköy (Arapuçandere) locations. The paragenesis includes galena, chalcopyrite, sphalerite, pyrite, limonite, hematite, malachite, manganese, quartz, calcite, and chlorite. The δ34S values of galena and pyrite samples taken from the ore zones in the study area are as follows: Karadoru -3.4‰ and -3.9‰, Karaköy -1.7‰ and -1.6‰, and Peynirderesi -1.7‰ and -4.0‰. The examined Pb-Zn-Cu mineralizations had Sb/Bi ratio in galena ranging from 0.06-0.34 ppm, and Co/Ni ratio in pyrites ranging from 1-10 ppm. The sulfur isotope ratios are negative, indicating that the mineralization has magmatic hydrothermal origin and is due to I-type magmatic activity. The mineralization contains vein-shaped epigenetic deposits of Pb-Zn-Cu mineralization, high trace element contents (Pb, Zn, Cu, Bi, Sb, Ag, Au, W, As), and silicification, sericitization, argillization, and limonitization are observed. These characteristics support the view that the mineralization has hydrothermal origin.

Keywords

Biga Peninsula Karakaya Complex Karadoru-Karaköy Pb-Zn-Cu mineralization S34/32 isotope ratios origin.

Project Number

1745-YL-08

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Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları

Year 2024, Volume: 67 Issue: 3, 361 - 388, 31.08.2024

Didem Kıray , Mustafa Kuşcu , Oya Cengiz

https://doi.org/10.25288/tjb.1369277

Abstract

Bu çalışma Biga Yarımadası (KB Türkiye)’nda yer alan Karadoru (Biga, Çanakkale) ve Karaköy (Yenice, Çanakkale) arasındaki Pb-Zn-Cu cevherleşmelerinin jeokimyasını ve kükürt izotop oranlarıile kökenini ortaya koymaya yöneliktir. İncelenen cevherleşmeler, Karadoru, Peynirderesi, Madençeşme (Biga, Çanakkale) ve Karaköy (Yenice, Çanakkale) olmak üzere toplam 4 lokasyonda gözlenmektedir. Bölgenin en alt tektonostratigrafik birimini Karakaya Kompleksi oluşturmaktadır. Karakaya Kompleksinin birimi olan ve başlıca metabazik kayaçları içeren Nilüfer birimi onun üzerinde de kireçtaşları, spilitik bazalt, diyabaz ve arkozik kumtaşlarını kapsayan Hodul birimi yer alır. Karakaya Kompleksine ait birimlerini Oligosen-Miyosen yaşlı Karadoru, Sarıçayır ve Soğucak granitoyidleri kesmektedir. Bölgede yüzlek veren birçok plütonik kütlelerin Karakaya Kompleksi (Nilüfer ve Hodul)’ne ait birimleri kestiği lokasyonlarda skarn zonları gelişmiştir. Karadoru, Sarıçayır ve Soğucak granitoyid kayaçları üzerine Miyosen yaştaki Çan volkanitleri gelir. İncelenen Pb-Zn-Cu cevherleşmeleri Karakaya Kompleksi içerisindeki Karadoru ve Madençeşme lokasyonlarında Nilüfer biriminde (epimetamorfikler), Peynirderesi ve Karaköy (Arapuçandere) mevkiilerinde Hodul birimi (metadiyabazve kristalize kireçtaşı) içerisinde damar şeklinde yataklanmaktadır. Cevherleşmenin mineral parajenezini galen, kalkopirit, sfalerit cevher mineralleri ile pirit, limonit, hematit, malakit, manganoksit, kuvars, kalsit ve klorit oluşturmaktadır. Çalışma alanındaki cevherli zonlardan alınan galen ve pirit numunelerinin δ34S değerleri sırasıyla Karadoru ‰ -3,4 ve ‰-3,9, Karaköy ‰-1,7 ve ‰ -1,6, Peynirderesi ‰ -1,7 ve ‰ -4,0 şeklindedir. İncelenen Pb-Zn-Cu cevherleşmelerinde galenlerde Sb/Bi oranının 0,06-0,34 ppm, piritlerde Co/Ni oranı 1-10 ppm arasında olması, kükürt izotop oranlarının negatif değerlerde olması, cevherleşmenin magmatik hidrotermal kökenli ve I-tipi bir magmatik aktiviteye bağlı olduğunaişaret etmektedir. Buna ek olarak, Pb-Zn-Cu cevherleşmelerinin damar şeklinde epijenetik yataklanması, iz element içeriklerinin (Pb, Zn, Cu, Bi, Sb, Ag, Au, W, As) yüksekliği ve silisleşme, serizitleşme, killeşme ve limonitleşme alterasyonlarının gözlenmesi de cevherleşmenin hidrotermal kökenli olduğunu destekler niteliktedir.

Keywords

Biga Yarımadası Karakaya Kompleksi Karadoru-Karaköy Pb-Zn-Cu cevherleşmesi S34/32 izotop oranları köken.

Supporting Institution

Süleyman Demirel Üniversitesi Bilimsel Araştırma Proje Ofisi

Project Number

1745-YL-08

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There are 125 citations in total.

Details

Primary Language Turkish
Subjects Geological Sciences and Engineering (Other), Isotope Geochemistry
Journal Section Makaleler - Articles
Authors

Didem Kıray 0000-0002-4187-7285

Mustafa Kuşcu 0000-0001-6955-7470

Oya Cengiz 0000-0003-1363-4638

Project Number 1745-YL-08
Early Pub Date April 26, 2024
Publication Date August 31, 2024
Submission Date September 30, 2023
Acceptance Date March 4, 2024
Published in Issue Year 2024 Volume: 67 Issue: 3

Cite

APA Kıray, D., Kuşcu, M., & Cengiz, O. (2024). Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları. Türkiye Jeoloji Bülteni, 67(3), 361-388. https://doi.org/10.25288/tjb.1369277
AMA Kıray D, Kuşcu M, Cengiz O. Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları. Geol. Bull. Turkey. August 2024;67(3):361-388. doi:10.25288/tjb.1369277
Chicago Kıray, Didem, Mustafa Kuşcu, and Oya Cengiz. “Karadoru Ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası Ve Kükürt İzotop Oranları”. Türkiye Jeoloji Bülteni 67, no. 3 (August 2024): 361-88. https://doi.org/10.25288/tjb.1369277.
EndNote Kıray D, Kuşcu M, Cengiz O (August 1, 2024) Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları. Türkiye Jeoloji Bülteni 67 3 361–388.
IEEE D. Kıray, M. Kuşcu, and O. Cengiz, “Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları”, Geol. Bull. Turkey, vol. 67, no. 3, pp. 361–388, 2024, doi: 10.25288/tjb.1369277.
ISNAD Kıray, Didem et al. “Karadoru Ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası Ve Kükürt İzotop Oranları”. Türkiye Jeoloji Bülteni 67/3 (August 2024), 361-388. https://doi.org/10.25288/tjb.1369277.
JAMA Kıray D, Kuşcu M, Cengiz O. Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları. Geol. Bull. Turkey. 2024;67:361–388.
MLA Kıray, Didem et al. “Karadoru Ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası Ve Kükürt İzotop Oranları”. Türkiye Jeoloji Bülteni, vol. 67, no. 3, 2024, pp. 361-88, doi:10.25288/tjb.1369277.
Vancouver Kıray D, Kuşcu M, Cengiz O. Karadoru ve Karaköy (Biga Yarımadası, Çanakkale) Arasındaki Pb-Zn-Cu Cevherleşmelerinin Kökeni, Jeokimyası ve Kükürt İzotop Oranları. Geol. Bull. Turkey. 2024;67(3):361-88.
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