Cystoseira (Ocrophyta) sensu lato 'nın Sinop Kıyılarında Biyoçeşitliliğinin Moleküler ve Morfolojik Olarak Tanımlanması ve Biyokütlesinin Atıksu Arıtımında Biyosorbent Olarak Kullanımının Araştırılması

Yıl 2023, Cilt: 19 Sayı: 2, 109 - 124, 01.06.2023

Fatih Gümüş , Dilek Gümüş , Elif Tezel Ersanlı

https://doi.org/10.22392/actaquatr.1211893

Öz

Cystoseira sensu lato (s.l.) türleri kıyısal deniz ekosistemlerinin çok önemli bileşenlerindendir. Ekolojik önemlerine rağmen bu makroalglerin taksonomisi henüz tam olarak çözümlenmiş değildir. Bu çalışmada Sinop kıyılarından toplanan Cystoseira s.l. türlerinin moleküler ve morfolojik teşhisleri yapılmış ve iki tür Gongolaria barbata (Stackhouse) Kuntze ve Ericaria bosphorica (Sauvageau) D.Serio & G.Furnari ile temsil edildiği görülmüştür. Çalışmanın kapsamında alg atıklarının atıksu arıtımında Cr+6 giderim performansı ele alınmış karakterizasyon, biyosorpsiyon kinetiği ve izotermleriyle ilgili çalışmalar gerçekleştirilmiştir. Başlangıç konsantrasyonu, pH, temas süresi gibi temel parametrelerin biyosorpsiyon kapasitesi üzerindeki etkileri incelenmiştir. Biyosorpsiyon verilerinin Freundlich izoterm modeliyle ve yalancı ikinci derece kinetik model ile daha uyumlu olduğu görüldü. Uyumlu olan her iki modelde de korelasyon katsayıları 0.99'un üzerindeydi. Optimum koşullardaki biyosorpsiyon kapasitesi 41,23 mg g-1 olarak bulunmuştur. Çalışmanın sonuçlarına göre atık alg biyokütlesi atıksulardan Cr+6 gideriminde etkin bir biyosorbent olarak değerlendirilebilir.

Anahtar Kelimeler

Karadeniz, Cystoseira, Moleküler, Biyosopsiyon, Ağır metal

Destekleyen Kurum

SİNOP ÜNİVERSİTESİ

Proje Numarası

FEF-1901-18-12, 2020

Teşekkür

FEF-1901-18-12, 2020 proje numaralı çalışmayı destekleyen Sinop Üniversitesi Bilimsel Araştırma Projeleri Koordinasyon Birimine teşekkür ederiz.

Molecular and Morphological Identification of Cystoseira (Ocrophyta) sensu lato Biodiversity in Sinop Coasts and Investigation of Its Use as a Biosorbent in Wastewater Treatment

Öz

Cystoseira sensu lato (s.l.) species are very important components of coastal marine ecosystems. Despite their ecological importance, the taxonomy of these macroalgae has not been fully elucidated. In this study, Cystoseira s.l. collected from the Sinop coast were diagnosed molecularly and morphologically and and found to be represented by two species, Gongolaria barbata (Stackhouse) Kuntze and Ericaria bosphorica (Sauvageau) D.Serio & G. Furnari. In this study, Cr+6 removal performance in wastewater treatment of algal wastes was discussed and characterization, biosorption kinetics, and isotherms studies were performed. The effects of basic parameters such as initial concentration, pH, and contact time on biosorption capacity were studied and evaluated. The biosorption data were found to be in better agreement with the Freundlich isothermal model and the pseudo-second-order kinetic model. The correlation coefficients were above 0.99 for both congruent models, and the biosorption capacity under optimal conditions was found to be 41.23 mg g-1. According to the results of the study, waste algal biomass can be considered as an effective biosorbent for the removal of Cr+6 from wastewater.

Anahtar Kelimeler

Cystoseira, Black Sea, Molecular, Biosorption, Heavy metal

Proje Numarası

FEF-1901-18-12, 2020

Kaynakça

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